Atomic carbon emission produced through photodissociative excitation of CO

Atomic carbon fluorescence at C i 1561, 1657, and 1931 A has been produced through photodissociative excitation of CO. Absolute partial fluorescence cross sections have been measured from threshold to ∼400 A (31 eV) by using a line emisson source. The fluorescence excitation functions show that the observed peaks correlate with the asymptotes of C(3D0, 3P0, and 1P0)+O(3P, 1D, and 1S). The maximum yield for producing the presently measured C i lines and the O i (1304 A), from earlier work, photodissociative excitation of the CO molecule is found to be ∼3% at a primary photon wavelength of 572 A.

[1]  D. Judge,et al.  Lyman‐α fluorescence from hydrogen photofragments of CH4 and H2O , 1981 .

[2]  D. Judge,et al.  The atomic oxygen 1304 Å emission produced through photodissociation of CO and CO2 , 1979 .

[3]  L. C. Lee,et al.  Atomic carbon emission from photodissociation of CO2 , 1978 .

[4]  L. C. Lee,et al.  Dispersed fluorescence observations of the CO(A 1Π→X 1Σ+) transitions from photodissociation of CO2 , 1977 .

[5]  P. Feldman,et al.  Carbon production in comet West 1975n. , 1976 .

[6]  C. E. Brion,et al.  Dipole excitation, ionization and fragmentation of N2 and CO in the 10-60 eV region , 1976 .

[7]  R. Carlson,et al.  Photoabsorption cross sections of CO from λλ520 730 Å , 1975 .

[8]  R. Carlson,et al.  Vacuum ultraviolet fluorescence from photodissociation fragments of CO and CO2 , 1974 .

[9]  K. Codling,et al.  Photoelectron Spectrum and Rydberg Transitions of CO , 1974 .

[10]  D. K. Prinz,et al.  Comet Kohoutek: Ultraviolet Images and Spectrograms , 1974, Science.

[11]  P. Takacs,et al.  Rocket Ultraviolet Spectrophotometry of Comet Kohoutek (1973f) , 1974, Science.

[12]  M. Belton,et al.  Ultraviolet Observations of Venus from Mariner 10: Preliminary Results , 1974, Science.

[13]  A. W. Potts,et al.  The absorption spectrum of carbon monoxide near 550 Å , 1974 .

[14]  G. Rottman,et al.  The ultraviolet /1200-1900 Angstrom/ spectrum of Venus , 1973 .

[15]  L. C. Lee,et al.  Cross sections for the production of CO(a′ 3Σ+, d 3Δi, and e 3Σ− ↠ a 3P) fluorescence through photodissociation of CO2 , 1973 .

[16]  J. Ajello Emission Cross Sections of CO by Electron Impact in the Interval 1260–5000 Å. I , 1971 .

[17]  G. Anderson,et al.  Mariner 6 and 7 Ultraviolet Spectrometer Experiment: Upper atmosphere data , 1971 .

[18]  James A. R. Samson,et al.  Total Absorption Cross Sections of CO and CO 2 in the Region 550–200 Å* , 1966 .

[19]  W. C. Walker,et al.  Photoelectric Yields in the Vacuum Ultraviolet , 1955 .

[20]  G. Herzberg,et al.  Spectra of diatomic molecules , 1950 .