Service-life limitations in vacuum glazing: A transient pressure balance model

Abstract Windows constitute a weak link in the building envelope and hence contribute significantly to the heating energy demand. By evacuating the glazing cavity, heat transfer rates two to five times lower than those of gas-filled conventional glazing units are predicted in theory and have been practically confirmed in a few cases. Of central importance to any practical realization of vacuum glazing is the edge-sealing problem because the technology used defines many secondary and tertiary parameters and strongly influences service life. This work establishes a correlation between the sealing method and its effect on the products service life. A cavity pressure balance model is presented, which takes into account four possible sources to the total pressure increase. Using this model a set of critical parameters is defined and the range of tolerable values for each parameter can be extracted. These findings underline the importance of choosing a sealing process, which is carried out in a high-vacuum environment. A possible source of pressure increase not considered in detail so far is the photofragmentation of long-chain organic adsorbate contaminants on the inner glazing surfaces. It was shown that a surface treatment via UV/ozone cleaning reduces the surface concentration of a model surface contaminant sodium dodecyl sulfate (SDS) by approximately 3 orders of magnitude.

[1]  Richard Edward Collins,et al.  Current status of the science and technology of vacuum glazing , 1998 .

[2]  R. Collins,et al.  Photodesorption of gases in vacuum glazing , 2003 .

[3]  Philip C. Eames,et al.  Fabrication of evacuated glazing at low temperature , 1998 .

[4]  H. Manz,et al.  On minimizing heat transport in architectural glazing , 2008 .

[5]  M. Liehr,et al.  Vapor phase hydrocarbon removal for Si processing , 1990 .

[6]  E. Taglauer Surface cleaning using sputtering , 1990 .

[7]  R. Collins,et al.  Evacuation and outgassing of vacuum glazing , 2000 .

[8]  Study of annealed Co thin films deposited by ion beam sputtering , 2006 .

[9]  J. Hobson Measurements with a Modulated Bayard–Alpert Gauge in Aluminosilicate Glass at Pressures below 10−12 Torr , 1964 .

[10]  B. J. Todd Outgassing of Glass , 1955 .

[11]  G. M. Turner,et al.  Thermal outgassing of vacuum glazing , 1999 .

[12]  R. Collins,et al.  Thermal and optical evolution of gas in vacuum glazing , 2005 .

[13]  Volker Wittwer,et al.  Optical materials technology for energy efficiency and solar energy conversion XIII : 18-22 April 1994, Freiburg, FRG , 1994 .

[14]  D. Lichtman Adsorption–Desorption of Residual Gases in High Vacuum , 1965 .

[15]  M. Bilek,et al.  Analysis of the internal glass surfaces of vacuum glazing , 2007 .

[16]  V. O. Altemose Helium Diffusion through Glass , 1961 .

[17]  Ruth Shinar,et al.  Glucose biosensors based on organic light-emitting devices structurally integrated with a luminescent sensing element , 2004 .

[18]  P. Pigram,et al.  X‐ray photoelectron spectroscopic study of the surface chemistry of soda‐lime glass in vacuum , 2006 .

[19]  W. Zachariasen,et al.  THE ATOMIC ARRANGEMENT IN GLASS , 1932 .

[20]  M. Seah,et al.  Ultrathin SiO2 on Si. I. Quantifying and removing carbonaceous contamination , 2003 .