Instructional Misconceptions in Acid-Base Equilibria: An Analysis from a History and Philosophy of Science Perspective

The implications of history and philosophy of chemistry are explored in the context of chemical models. Models and modeling provide the context through which epistemological aspects of chemistry can be promoted. In this work, the development of ideas and models about acids and bases (with emphasis on the Arrhenius, the Brønsted–Lowry, and the Lewis models) are presented. In addition, misconceptions (alternative and instructional ones) on acid-base (ionic) equilibria are examined from the history and philosophy of science perspective. The relation between the development of the models and students’ misconceptions are investigated. Finally, the hypothesis that history and philosophy could help educators anticipate students’ misconceptions is examined.

[1]  Michael P. Clough,et al.  The Nature of Science in Science Education: An Introduction , 1998 .

[2]  G. Kauffman History in the chemistry curriculum , 1989 .

[3]  Teaching chemistry by the Socratic method , 1990 .

[4]  Aaron J. Ihde,et al.  The development of modern chemistry , 1964 .

[5]  J. Dudley Herron Place of history in the teaching of chemistry (Fourth Biennial Conference) , 1977 .

[6]  J. Schummer The Philosophy of Chemistry , 2003 .

[7]  Rosária Justi,et al.  A cause of ahistorical science teaching: Use of hybrid models , 1999 .

[8]  James H. Wandersee,et al.  Can the history of science help science educators anticipate students' misconceptions? , 1986 .

[9]  S. Pickering The Theory of Dissociation into Ions , 1897, Nature.

[10]  Ernest Nagel,et al.  The Structure of Science , 1962 .

[11]  T. Lowry The uniqueness of hydrogen , 1923 .

[12]  W. Jensen Logic, History, and the Chemistry Textbook: II. Can We Unmuddle the Chemistry Textbook? , 1998 .

[13]  Pamela J. Garnett,et al.  Students' Alternative Conceptions in Chemistry: A Review of Research and Implications for Teaching and Learning , 1995 .

[14]  B. Jaffe The history of chemistry and its place in the teaching of high-school chemistry , 1938 .

[15]  Reinders Duit,et al.  Conceptual Change Approaches in Science Education , 1999 .

[16]  T. Kuhn,et al.  The Structure of Scientific Revolutions. , 1964 .

[17]  M. R. Matthews,et al.  In defense of modest goals when teaching about the nature of science , 1998 .

[18]  S. Erduran Emergence and application of philosophy of chemistry in chemistry education , 2000 .

[19]  J. N. Brönsted Some Remarks on the Concept of Acids and Bases , 1968 .

[20]  P. Koumaras,et al.  The Contribution of the History of Physics in Physics Education: A Review , 2001 .

[21]  A. Benseghir Transition électrostatique-électrocinétique : point de vue historique et analyse des difficultés des élèves , 1989 .

[22]  Thomas L. Hankins,et al.  Science and the Enlightenment , 1970 .

[23]  H. Armstrong Osmotic Pressure and Ionic Dissociation , 1896, Nature.

[24]  Eric R. Scerri THE NEW PHILOSOPHY OF CHEMISTRY AND ITS RELEVANCE TO CHEMICAL EDUCATION , 2001 .

[25]  Eric R. Scerri Prediction of the nature of hafnium from chemistry, Bohr's theory and quantum theory , 1994 .

[26]  M. C. Whiting,et al.  Chemistry through models by Colin J. Suckling, Keith E. Suckling and Charles W. Suckling. Pp. 321. Cambridge University Press, Cambridge U.K. and New York. 1978. £15.00 , 1979 .

[27]  Arnold B. Arons,et al.  A Guide to Introductory Physics Teaching , 1990 .

[28]  J. C. Smart,et al.  Higher Education: Handbook of Theory and Research , 2001, Higher Education: Handbook of Theory and Research.

[29]  W. H. Brock,et al.  The Fontana History of Chemistry , 1992 .

[30]  David F. Treagust,et al.  A multidimensional framework for interpreting conceptual change events in the classroom , 1997 .

[31]  Bruce K. Britton,et al.  Analogical Reasoning and Problem Solving in Science Textbooks , 1989 .

[32]  Eric R. Scerri The Failure of Reduction and How to Resist Disunity of the Sciences in the Context of Chemical Education , 2000 .

[33]  M. Carr Model confusion in chemistry , 1984 .

[34]  S. Arrhenius Über die Dissociation der in Wasser gelösten Stoffe , 1887 .

[35]  Colin A. Russell Recent developments in the history of chemistry , 1985 .

[36]  Rosenfeld,et al.  Of Minds and Molecules , 2000 .

[37]  The Development of the Theory of Electrolytic Dissociation: A Case Study of a Scientific Controversy and the Changing Nature of Chemistry. , 2003 .

[38]  Michael A. Rodriguez,et al.  How in Spite of the Rhetoric, History of Chemistry has Been Ignored in Presenting Atomic Structure in Textbooks , 2002 .

[39]  Hans-Jürgen Schmidt,et al.  A Label as a Hidden Persuader: Chemists' Neutralization Concept. , 1991 .

[40]  Thomas W. Shiland The atheoretical nature of the national science education standards , 1998 .

[41]  E. F. Herroun The Theory of Dissociation into Ions , 1896, Nature.

[42]  M. Linn,et al.  Heat energy and temperature concepts of adolescents, adults, and experts: Implications for curricular improvements , 1994 .

[43]  Canan Nakiboğlu,et al.  INSTRUCTIONAL MISCONCEPTIONS OF TURKISH PROSPECTIVE CHEMISTRY TEACHERS ABOUT ATOMIC ORBITALS AND HYBRIDIZATION , 2003 .

[44]  Arthur Stinner,et al.  Science textbooks and science teaching: From logic to evidence , 1992 .

[45]  Laurinda Leite,et al.  Alternative conceptions and history of science in physics teacher education , 1991 .

[46]  Eric R. Scerri Chemistry, spectroscopy, and the question of reduction , 1991 .

[47]  R. Duit,et al.  Students' conceptions of the second law of thermodynamics—an interpretive study , 1993 .

[48]  H. Siegel Kuhn and Schwab on Science Texts and the Goals of Science Education , 1978 .

[49]  Sibel Erduran,et al.  Philosophy of Chemistry: An Emerging Field with Implications for Chemistry Education , 2001 .

[50]  Mansoor Niaz,et al.  DO WE HAVE TO INTRODUCE HISTORY AND PHILOSOPHY OF SCIENCE OR IS IT ALREADY ‘INSIDE’ CHEMISTRY? , 2001 .

[51]  G. F. Fitzgerald Helmholtz Memorial Lecture , 1896 .

[52]  Carol L. Smith,et al.  Understanding models and their use in science: Conceptions of middle and high school students and experts , 1991 .

[53]  Derek Hodson,et al.  Toward a philosophically more valid science curriculum , 1988 .

[54]  Relating students' reasoning to the history of science: The case of chemical equilibrium , 1998 .

[55]  Jacopo Tomasi Models and modeling in theoretical chemistry , 1988 .

[56]  Eric R. Scerri,et al.  THE CASE FOR THE PHILOSOPHY OF CHEMISTRY , 1997, Synthese.

[57]  Mansoor Niaz,et al.  TEACHING CHEMISTRY AS RHETORIC OF CONCLUSIONS OR HEURISTIC PRINCIPLES - A HISTORY AND PHILOSOPHY OF SCIENCE PERSPECTIVE , 2000 .