Chemistry of corrosion inhibitors

In the last quarter century, it has become feasible to extend the life of reinforced concrete structures by inhibiting chloride-induced corrosion of steel. Chemical interactions can occur between the concrete system and the inhibitor-steel-chloride system. The chemical reactions of the corrosion process in concrete and of the most commonly used inhibitors are discussed, with special attention to test procedures and practical issues arising from use of inhibitors.

[1]  Michael M Sprinkel,et al.  PERFORMANCE OF EPOXY-COATED REINFORCING STEEL , 2000 .

[2]  B D Prowell,et al.  IMPREGNATION OF CONCRETE WITH CORROSION INHIBITORS , 1992 .

[3]  David G. Manning,et al.  CORROSION PERFORMANCE OF EPOXY-COATED REINFORCING STEEL: NORTH AMERICAN EXPERIENCE , 1996 .

[4]  F. P. Glasser,et al.  Friedel’s salt, Ca2Al(OH)6(Cl,OH)·2H2O: its solid solutions and their role in chloride binding , 1998 .

[5]  Neal S. Berke,et al.  Protection Against Chloride-Induced Corrosion , 1988 .

[6]  A. Jeknavorian,et al.  Determination of a Nitrite-Based Corrosion Inhibitor in Plastic and Hardened Concrete , 1995 .

[7]  M. Pourbaix Atlas of Electrochemical Equilibria in Aqueous Solutions , 1974 .

[8]  A. Bentur Steel corrosion in concrete , 1997 .

[9]  Matthew A. Miltenberger,et al.  PREDICTING THE SERVICE LIFE OF CONCRETE MARINE STRUCTURES: AN ENVIRONMENTAL METHODOLOGY , 1998 .

[10]  M. Grunze,et al.  Interactions of N,N′-dimethylaminoethanol with steel surfaces in alkaline and chlorine containing solutions , 1997 .

[11]  H. Justnes CALCIUM NITRATE AS CORROSION INHIBITOR FOR REINFORCED CONCRETE , 2002 .

[12]  Jm Gaidis,et al.  The inhibition of chloride-induced corrosion in reinforced concrete by calcium nitrite , 1987 .

[13]  J. S. McHattie,et al.  FACTORS AFFECTING CATHODIC DISBONDMENT OF EPOXY COATINGS FOR STEEL REINFORCING BARS , 1996 .

[14]  V. M. Malhotra,et al.  Advances in concrete technology , 1992 .

[15]  R. Powers,et al.  TIME TO CORROSION OF REINFORCING STEEL IN CONCRETE CONTAINING CALCIUM NITRITE , 1999 .

[16]  Ns Berke,et al.  Comparison of the Polarization Resistance Technique to the Macrocell Corrosion Technique , 1990 .

[17]  George J. Verbeck Mechanisms of Corrosion of Steel in Concrete , 1975 .

[18]  Dubravka Bjegović,et al.  Migrating Corrosion Inhibitor Protection of Concrete , 1999 .

[19]  Susan Budavari,et al.  The Merck index , 1998 .

[20]  P. Aitcin High Performance Concrete , 1998 .

[21]  Morris Cohen Inhibition of Steel Corrosion by Sodium Nitrite in Water , 1948 .

[22]  Charles K. Nmai,et al.  Organic-Based Corrosion-Inhibiting Admixture For Reinforced Concrete , 1992 .

[23]  Victor Chaker,et al.  Corrosion Rates of Steel in Concrete , 1990 .

[24]  Noel P. Mailvaganam Repair and Protection of Concrete Structures , 1991 .

[25]  D L Edwards HPC ON BRIDGES: THE FLORIDA EXPERIENCE , 2000 .

[26]  Jan Skalny,et al.  Materials science of concrete , 1989 .

[27]  A M Rosenberg,et al.  METHODS OF DETERMINING CORROSION SUSCEPTIBILITY OF STEEL IN CONCRETE , 1978 .

[28]  R. Foley,et al.  The Influence of Chloride and Sulfate Ions on the Corrosion of Iron in Sulfuric Acid , 1971 .

[29]  Michael D. A. Thomas,et al.  Modelling chloride diffusion in concrete: Effect of fly ash and slag , 1999 .