论文信息 - A Novel 3D Porous Cu(II)-Based Metal−Organic Framework Built from H4hbpdc Ligand: Synthesis, Structure, and Magnetic Characterization (H4hbpdc = 3,3′-Dihydroxy-2,2′-bipyridine-6,6′-dicarboxylic)

A Novel 3D Porous Cu(II)-Based Metal−Organic Framework Built from H4hbpdc Ligand: Synthesis, Structure, and Magnetic Characterization (H4hbpdc = 3,3′-Dihydroxy-2,2′-bipyridine-6,6′-dicarboxylic)

The coordination polymer {[Cu3(hbpdc)(OH)2(H2O)]·2H2O}n (1, hbpdc = 3,3′-dihydroxy-2,2′-bipyridine-6,6′-dicarboxylic anion) was prepared under hydrothermal conditions. Single-crystal X-ray diffraction revealed that complex 1 features a highly ordered 3D nanoporous structure encapsulating a zigzag water chain. Variable-temperature magnetic studies indicated the presence of strong antiferromagnetic coupling.