Chemical Methods in Archaeology

Chemistry plays an important role in the study of archaeological materials. For instance, chemistry has developed methods for dating archaeological material. It has also allowed for inferring trade routes by studying ancient artifacts and for shedding light on the technology used to make them. In addition, the diets and customs of ancient peoples have also been discovered by applying chemical methods. Furthermore, chemistry assists in gaining understanding of the mechanisms that cause archaeological material to degrade. The modern analytical methods available today have been used to study a wide range of archaeological inorganic, organic, and biological materials. A short overview of some of the most relevant achievements reached by applying chemical methods to archaeology is reported here. Keywords: Analytical methods; Archaeology; Conservation science

[1]  A. Pollard,et al.  Here today, gone tomorrow? integrated experimentation and geochemical modeling in studies of archaeological diagenetic change. , 2002, Accounts of chemical research.

[2]  M. Collins,et al.  The Removal of Protein from Mineral Surfaces: Implications for Residue Analysis of Archaeological Materials , 2002 .

[3]  Andrew R. Millard,et al.  The survival of organic matter in bone: a review , 2002 .

[4]  J. Boon,et al.  Molecular archaeology: Analysis of charred (food) remains from prehistoric pottery by pyrolysis—gas chromatography/mass spectrometry , 1991 .

[5]  S. Pääbo,et al.  Mitochondrial genome variation and the origin of modern humans , 2000, Nature.

[6]  Mike Baxter,et al.  Exploratory Multivariate Analysis in Archaeology , 1994 .

[7]  R. Evershed,et al.  Organic geochemical studies of soils from the Rothamsted Classical Experiments - I. Total lipid extracts, solvent insoluble residues and humic acids from Broadbalk Wilderness , 1997 .

[8]  T. Lindahl Recovery of antediluvian DNA , 1993, Nature.

[9]  M. Glascock,et al.  An Assessment of the Acid-Extraction Approach to Compositional Characterization of Archaeological Ceramics , 1996, American Antiquity.

[10]  R. Bishop,et al.  Instrumental neutron activation analysis of archaeological ceramics: scale and interpretation. , 2002, Accounts of chemical research.

[11]  R. Evershed,et al.  δ13C Analysis of Cholesterol Preserved in Archaeological Bones and Teeth , 1996 .

[12]  Evershed,et al.  Direct demonstration of milk as an element of archaeological economies , 1998, Science.

[13]  P. Crown,et al.  Sensitivity, Precision, and Accuracy: Their Roles in Ceramic Compositional Data Bases , 1990, American Antiquity.

[14]  K. Spindler,et al.  THE MAN IN THE ICE: THE PRESERVED BODY OF A NEOLITHIC MAN REVEALS THE SECRETS OF THE STONE AGE , 1994 .

[15]  R. Evershed,et al.  Muck ‘n’ molecules: organic geochemical methods for detecting ancient manuring , 1999, Antiquity.

[16]  P. McGovern,et al.  Neolithic resinated wine , 1996, Nature.

[17]  G. Poinar,et al.  Amber: the organic gemstone. , 2002, Accounts of chemical research.

[18]  Colin Renfrew,et al.  Obsidian and Early Cultural Contact in the Near East , 1966, Proceedings of the Prehistoric Society.

[19]  M. Tite,et al.  The beginnings of vitreous materials in the Near East and Egypt. , 2002, Accounts of chemical research.

[20]  I. T. Platzner,et al.  Modern Isotope Ratio Mass Spectrometry , 1997 .

[21]  S. Pääbo Molecular cloning of Ancient Egyptian mummy DNA , 1985, Nature.

[22]  E. Sayre,et al.  Compositional Categories of Ancient Glass , 1961, Science.

[23]  C. Salter,et al.  Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) for spatially resolved trace analysis of early-medieval archaeological iron finds , 2000, Fresenius' journal of analytical chemistry.

[24]  M. Pearson,et al.  Archaeology: Detecting milk proteins in ancient pots , 2000, Nature.

[25]  C. W. Beck Spectroscopic Investigations of Amber , 1986 .

[26]  T. S. Wheeler,et al.  How the Iron Age Began , 1977 .

[27]  R. Evershed,et al.  Chemistry of archaeological animal fats. , 2002, Accounts of chemical research.

[28]  M. Glascock Obsidian provenance research in the Americas. , 2002, Accounts of chemical research.

[29]  J B Lambert,et al.  Carbon Functionalities in Amber , 1982, Science.

[30]  Demetrios Anglos,et al.  Laser-Induced Breakdown Spectroscopy in Art and Archaeology , 2001 .

[31]  Pamela B. Vandiver,et al.  Materials Issues in Art and Archaeology , 1991 .

[32]  A. von Haeseler,et al.  Independent origins of New Zealand moas and kiwis. , 1992, Proceedings of the National Academy of Sciences of the United States of America.

[33]  H. Poinar The genetic secrets some fossils hold. , 2002, Accounts of chemical research.

[34]  S. Junk Ancient artefacts and modern analytical techniques - Usefulness of laser ablation ICP-MS demonstrated with ancient gold coins , 2001 .

[35]  Paul T. Craddock,et al.  The trace element composition of polished flint axes as an indicator of source , 1983 .

[36]  R. Evershed,et al.  Proteinaceous material from potsherds and associated soils , 1996 .

[37]  J L Bada,et al.  Marine Sediments: Dating by the Racemization of Amino Acids , 1970, Science.

[38]  Michael Schall,et al.  New strategies for characterizing ancient proteins using matrix-assisted laser desorption ionization mass spectrometry , 2000 .

[39]  M. Rehkämper,et al.  Applications of Multiple Collector-ICPMS to Cosmochemistry, Geochemistry, and Paleoceanography , 1998 .

[40]  M. Stoneking,et al.  Neandertal DNA Sequences and the Origin of Modern Humans , 1997, Cell.

[41]  T. Hirata Lead isotopic analyses of NIST Standard Reference Materials using multiple collector inductively coupled plasma mass spectrometry coupled with a modified external correction method for mass discrimination effect , 1996 .

[42]  Practical Organic Mass Spectrometry: A Guide for Chemical and Biochemical Analysis , 1993 .

[43]  R. Evershed,et al.  Preliminary results for the analysis of lipids in ancient bone , 1995 .

[44]  A. M. Pollard,et al.  Handbook of archaeological sciences , 2001 .

[45]  E. Caley Early history and literature of archaeological chemistry , 1951 .

[46]  Richard P. Evershed,et al.  Organic chemistry of embalming agents in Pharaonic and Graeco-Roman mummies , 2001, Nature.

[47]  J. Bada,et al.  New Evidence for the Antiquity of Man in North America Deduced from Aspartic Acid Racemization , 1974, Science.

[48]  C Rowe,et al.  One Signal or Two? , 1999, Science.

[49]  P. Healy,et al.  Analysis of Obsidian from Moho Cay, Belize: New Evidence on Classic Maya Trade Routes , 1984, Science.

[50]  Giuseppe Spoto,et al.  Secondary ion mass spectrometry in art and archaeology , 2000 .

[51]  Julian Henderson,et al.  The science and archaeology of materials , 2000 .

[52]  K. Mullis,et al.  Primer-directed enzymatic amplification of DNA with a thermostable DNA polymerase. , 1988, Science.

[53]  S. Pääbo,et al.  Genetic analyses from ancient DNA. , 2004, Annual review of genetics.

[54]  M. Aitken,et al.  Science-Based Dating in Archaeology , 1990 .

[55]  G. Miller,et al.  ARCHAEOLOGICAL APPLICATIONS OF AMINO ACID RACEMIZATION , 1997 .

[56]  J. Nandris,et al.  The distribution and provenance of archaeological obsidian in central and eastern Europe , 1984 .

[57]  G. Poupeau,et al.  Determination of minor and trace elements in obsidian rock samples and archaeological artifacts by laser ablation inductively coupled plasma mass spectrometry using synthetic obsidian standards , 2001 .

[58]  P. McGovern,et al.  A funerary feast fit for King Midas , 1999, Nature.

[59]  R. Evershed,et al.  Complex organic chemical balms of Pharaonic animal mummies , 2004, Nature.

[60]  Manfred Schreiner,et al.  X-ray analysis of objects of art and archaeology , 2001 .

[61]  G. Hung Archaeological chemistry, advances in chemistry series no. 138: Edited by Curt W. Beck. American Chemical Society, Washington, D. C., 1974. ix + 254 pp. $22.50 , 1976 .

[62]  E. Caley The early history of chemistry in the service of archaeology , 1967 .

[63]  G. Auden,et al.  The Preservation of Antiquities, a Handbook for Curators , 2012, Nature.

[64]  I. L. Barnes,et al.  STATISTICAL EVALUATION OF THE PRESENTLY ACCUMULATED LEAD ISOTOPE DATA FROM ANATOLIA AND SURROUNDING REGIONS , 1992 .

[65]  Robert E. M. Hedges,et al.  Bone diagenesis: an overview of processes , 2002 .

[66]  T. Calligaro,et al.  An external milli-beam for archaeometric applications on the AGLAE IBA facility of the Louvre museum , 1998 .

[67]  G. Spoto Detecting past attempts to restore two important works of art. , 2002, Accounts of chemical research.

[68]  H. J. Plenderleith A history of conservation , 1998 .

[69]  B. Gratuze Obsidian Characterization by Laser Ablation ICP-MS and its Application to Prehistoric Trade in the Mediterranean and the Near East: Sources and Distribution of Obsidian within the Aegean and Anatolia , 1999 .

[70]  Henry Hodges,et al.  Artifacts: An introduction to early materials and technology , 1981 .

[71]  J. Csapó,et al.  Use of amino acids and their racemisation for age determination in archaeometry , 1998 .

[72]  B. X. Mayer,et al.  Investigation of the triacylglycerol composition of iceman's mummified tissue by high-temperature gas chromatography. , 1997, Journal of Chromatography B: Biomedical Sciences and Applications.

[73]  R. Evershed,et al.  Detection of nucleotide bases in ancient seeds using gas chromatography/mass spectrometry and gas chromatography/mass spectrometry/mass spectrometry , 1994 .

[74]  R. B. Mason,et al.  Lead glazes in antiquity - Methods of production and reasons for use , 1998 .

[75]  J. Bada Aspartic Acid Racemization Ages of California Paleoindian Skeletons , 1985, American Antiquity.

[76]  R. Evershed Biomolecular archaeology and lipids. , 1993, World archaeology.

[77]  R. Evershed,et al.  Organic geochemical studies of soils from the Rothamsted classical experiments-IV. Preliminary results from a study of the effect of soil pH on organic matter decay , 1998 .

[78]  A. Aspinall,et al.  NEUTRON ACTIVATION ANALYSIS OF PREHISTORIC FLINT MINE PRODUCTS. , 1972 .

[79]  M. Collins,et al.  An improved method for the immunological detection of mineral bound protein using hydrofluoric acid and direct capture. , 2000, Journal of immunological methods.

[80]  J. E. Dixon,et al.  Obsidian in the Aegean , 1965, The Annual of the British School at Athens.

[81]  M. Tite Pottery Production, Distribution, and Consumption—The Contribution of the Physical Sciences , 1999 .

[82]  L. Mayer SURFACE AREA CONTROL OF ORGANIC CARBON ACCUMULATION IN CONTINENTAL SHELF SEDIMENTS , 1994 .

[83]  J. Henderson ELECTRON PROBE MICROANALYSIS OF MIXED‐ALKALI GLASSES , 1988 .

[84]  E. Ciliberto,et al.  Modern analytical methods in art and archaeology , 2000 .

[85]  N. Gale,et al.  COMMENTS ON P. BUDD, D. GALE, A. M. POLLARD, R. G. THOMAS AND P. A. WILLIAMS,‘EVALUATING LEAD ISOTOPE DATA: FURTHER OBSERVATIONS’, ARCHAEOMETRY, 35 (2) (1993), AND REPLY , 1993 .

[86]  Sungmin Hong,et al.  Greenland Ice Evidence of Hemispheric Lead Pollution Two Millennia Ago by Greek and Roman Civilizations , 1994, Science.

[87]  R. Tykot Chemical fingerprinting and source tracing of obsidian: the central Mediterranean trade in black gold. , 2002, Accounts of chemical research.

[88]  M. Faerman,et al.  Sequence analysis reveals a β–thalassaemia mutation in the DNA of skeletal remains from the archaeological site of Akhziv, Israel , 1995, Nature Genetics.

[89]  C. Bakels,et al.  THE USE OF NON-DESTRUCTIVE ACTIVATION ANALYSIS AND PATTERN RECOGNITION IN THE STUDY OF FLINT ARTEFACTS , 1972 .

[90]  W. Goodwin,et al.  Molecular analysis of Neanderthal DNA from the northern Caucasus , 2000, Nature.

[91]  P. Bahn The making of a mummy , 1992, Nature.

[92]  J. Svoboda,et al.  The Origins of Ceramic Technology at Dolni Věstonice, Czechoslovakia , 1989, Science.

[93]  M. Oddone,et al.  Provenance studies of obsidian artifacts: Trace elements analysis and data reduction , 1986 .