ZnO nanorods on ZnO seed layer derived by sol–gel process

Well-aligned ZnO nanorods are obtained by a liquid phase epitaxial growth on the indium-doped tin oxide glass deposited with a ZnO thin film as the seed layer, which is prepared by combining a sol–gel process and a spin coating technique. The effects of water content in the sol and heat treatment temperature on the properties of the ZnO thin film are investigated. Relationship among the seed layer, the growing time, the growing temperature, the concentration of Zn2+ in the solution, the anions in the solution and the resulting ZnO nanorods are discussed in detail. X-ray diffraction analysis and scanning electronic microscopy are employed to characterize the structural and morphological properties of the resulting ZnO nanorods. Results indicate that the ZnO nanorods with a preferred orientation show a single crystal with a wurtzite structure in the direction of [0001], the diameter of the ZnO nanorods seems to depend on the size of the seed grain, while the length of the ZnO nanorods is determined by the growing time and the growing temperature.

[1]  Hongen Shen,et al.  ZnO Schottky ultraviolet photodetectors , 2001 .

[2]  Daniel Lincot,et al.  Heteroepitaxial electrodeposition of zinc oxide films on gallium nitride , 1999 .

[3]  G. Meng,et al.  Ordered semiconductor ZnO nanowire arrays and their photoluminescence properties , 2000 .

[4]  Robert N. Lamb,et al.  The influence of film crystallinity on the coupling efficiency of ZnO optical modulator waveguides , 1995 .

[5]  Takashi Sekiguchi,et al.  Low‐Temperature Fabrication of Light‐Emitting Zinc Oxide Micropatterns Using Self‐Assembled Monolayers , 2002 .

[6]  G. Hu,et al.  Epitaxy of Vertical ZnO Nanorod Arrays on Highly (001)-Oriented ZnO Seed Monolayer by a Hydrothermal Route , 2008 .

[7]  Yiying Wu,et al.  Room-Temperature Ultraviolet Nanowire Nanolasers , 2001, Science.

[8]  Toshinobu Yoko,et al.  Sol-gel preparation of ZnO films with extremely preferred orientation along (002) plane from zinc acetate solution , 1997 .

[9]  A. Hagfeldt,et al.  Purpose-Built Anisotropic Metal Oxide Material: 3D Highly Oriented Microrod Array of ZnO , 2001 .

[10]  Sigurd Wagner,et al.  Thin film semiconductor deposition on free-standing ZnO columns , 2000 .

[11]  S. Studenikin,et al.  Sensor Photoresponse of Thin‐Film Oxides of Zinc and Titanium to Oxygen Gas , 2000 .

[12]  A. Ballman,et al.  HYDROTHERMAL SYNTHESIS OF ZINC OXIDE AND ZINC SULFIDE1 , 1960 .

[13]  Zhifeng Liu,et al.  Growth and morphology of ZnO nanorods prepared from Zn(NO3)2/NaOH solutions , 2006 .

[14]  E. D. Kolb,et al.  The solubility of zincite in basic hydrothermal solvents , 1963 .

[15]  Peidong Yang,et al.  Nanowire dye-sensitized solar cells , 2005, Nature materials.

[16]  Gyu-Chul Yi,et al.  Metalorganic vapor-phase epitaxial growth of vertically well-aligned ZnO nanorods , 2002 .

[17]  M. Izaki,et al.  Transparent zinc oxide films prepared by electrochemical reaction , 1996 .

[18]  Weizhuo Zhong,et al.  Growth mechanism and growth habit of oxide crystals , 1999 .