Life cycle assessment of a new graphene-based electrodeposition process on copper components

Abstract This report studies the electrodeposition process of an innovative alternative to silver plating: graphene-copper composite coatings on copper substrates. This new technology provides a potential solution to the environmental problems that typically affect traditional silvering processes, which rely on using and disposing of highly toxic cyanide baths that incur negative economic impacts. Silver plating applications include electronics, connectors and semi-conductors, bearings, musical instruments, and luxury goods. This study consists of two main steps. First, experimental tests investigated the overall process and its coating performance. The tests also focused on understanding the basic mechanisms involved in the coating process and the effects of the operational parameters. Second, an LCA analysis was developed to verify the effectiveness of the proposed technology in terms of environmental impact, energy consumption and cost. The results demonstrate that this new technology is suitable for industrial applications, providing an effective and environmentally friendly solution with a positive economic impact.

[1]  S. Berger,et al.  Novel and innovative non-cyanide silver process: A report on commercial plating experiences , 2005 .

[2]  A. Balandin Thermal properties of graphene and nanostructured carbon materials. , 2011, Nature materials.

[3]  T. Maloney,et al.  General overview of graphene: Production, properties and application in polymer composites , 2017 .

[4]  M. Chhowalla,et al.  A review of chemical vapour deposition of graphene on copper , 2011 .

[5]  Mark A. J. Huijbregts,et al.  A bright future for addressing chemical emissions in life cycle assessment , 2011 .

[6]  Ivan Tengbjerg Herrmann,et al.  Does it matter which Life Cycle Assessment (LCA) tool you choose? – a comparative assessment of SimaPro and GaBi , 2015 .

[7]  SUPARNA DUTTASINHA,et al.  Graphene: Status and Prospects , 2009, Science.

[8]  Pål Börjesson,et al.  Life cycle assessment in green chemistry , 2006 .

[9]  Llorenç Milà i Canals,et al.  Method for assessing impacts on life support functions (LSF) related to the use of ‘fertile land’ in Life Cycle Assessment (LCA) , 2007 .

[10]  D. A. Tolle,et al.  Life cycle assessment of chemical agent resistant coatings , 1998 .

[11]  Jean-Louis Bantignies,et al.  Life cycle assessment of nanocomposites made of thermally conductive graphite nanoplatelets , 2014, The International Journal of Life Cycle Assessment.

[12]  Andréa Moura Bernardes,et al.  Closing the loop in the electroplating industry by electrodialysis , 2017 .

[13]  F. Ren,et al.  Cyanide-free silver electroplating process in thiosulfate bath and microstructure analysis of Ag coatings , 2013 .

[14]  Electro-deposition of graphene on aluminium open cell metal foams , 2015 .

[15]  R. Ruoff,et al.  Graphene and Graphene Oxide: Synthesis, Properties, and Applications , 2010, Advanced materials.

[16]  Matthew W. Losey,et al.  1.10 – Electrodeposition , 2008 .

[17]  K. Rhee,et al.  Silver-coated graphene electrode produced by electrolytic deposition for electrochemical behaviors , 2014 .

[18]  V. Tagliaferri,et al.  Improvement of the mechanical and thermal characteristics of open cell aluminum foams by the electrodeposition of Cu , 2014 .

[19]  Anthony J. Kinloch,et al.  The science of adhesion , 1980 .

[20]  E. Chainet,et al.  Electrochemical deposition of silver from a low cyanide concentration bath , 1996 .

[21]  V. Tagliaferri,et al.  Thermal behavior of open cell aluminum foams in forced air: Experimental analysis , 2015 .

[22]  M. Lemme,et al.  Contact resistance study of various metal electrodes with CVD graphene , 2016, 2211.12415.

[23]  I. González,et al.  Electrochemical deposition of silver and gold from cyanide leaching solutions , 2002 .

[24]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.

[25]  B. Raj,et al.  Measurement of thermal diffusivity of solids using infrared thermography , 2008 .

[26]  Eiichiro Watanabe,et al.  Low contact resistance metals for graphene based devices , 2012 .

[27]  C. N. Lau,et al.  Superior thermal conductivity of single-layer graphene. , 2008, Nano letters.