Carbon nanotube based composite membranes for water desalination by membrane distillation

New technologies are required to improve desalination efficiency and increase water treatment capacities. One promising low energy technique to produce potable water from either sea or sewage water is membrane distillation (MD). However, to be competitive with other desalination processes, membranes need to be designed specifically for the MD process requirements. Here we report on the design of carbon nanotube (CNT) based composite material membranes for direct contact membrane distillation (DCMD). The membranes were characterized and tested in a DCMD setup under different feed temperatures and test conditions. The composite CNT structures showed significantly improved performance compared to their pure self-supporting CNT counterparts. The best composite CNT membranes gave permeabilities as high as 3.3 x 10-12 kg/(m x s x Pa) with an average salt rejection of 95% and lifespan of up to 39 h of continuous testing, making them highly promising candidates for DCMD.

[1]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[2]  Marek Gryta,et al.  Wastewater treatment by membrane distillation , 2006 .

[3]  M. Meyyappan,et al.  Gas Permeability of a Buckypaper Membrane , 2003 .

[4]  Mohamed Khayet,et al.  A framework for better understanding membrane distillation separation process , 2006 .

[5]  K. Smolders,et al.  Terminology for Membrane Distillation , 1989 .

[6]  Ákos Kukovecz,et al.  Structure and gas permeability of multi-wall carbon nanotube buckypapers , 2007 .

[7]  Anthony G. Fane,et al.  Factors affecting flux in membrane distillation , 1990 .

[8]  Asa H. Barber,et al.  Direct measurement of multiwall nanotube surface tension , 2005 .

[9]  Zhongyi Jiang,et al.  Novel ploy(vinyl alcohol)/carbon nanotube hybrid membranes for pervaporation separation of benzene/cyclohexane mixtures , 2007 .

[10]  D. R. Lloyd,et al.  Membrane distillation. II. Direct contact MD , 1996 .

[11]  Niall Finn,et al.  Characterization and evaluation of carbon nanotube Bucky-Paper membranes for direct contact membrane distillation , 2010 .

[12]  S. Hawkins,et al.  Understanding the synthesis of directly spinnable carbon nanotube forests , 2010 .

[13]  M. Vahdati,et al.  Direct Contact Membrane Distillation , 2000 .

[14]  Hyung Gyu Park,et al.  Ion exclusion by sub-2-nm carbon nanotube pores , 2008, Proceedings of the National Academy of Sciences.

[15]  Joseph Wang,et al.  Carbon nanotube-modified glassy carbon electrode for adsorptive stripping voltammetric detection of ultratrace levels of 2,4,6-trinitrotoluene , 2004 .

[16]  A. Rinzler,et al.  Engineered macroporosity in single-wall carbon nanotube films. , 2009, Nano letters.

[17]  P. Ajayan,et al.  Carbon nanotube filters , 2004, Nature materials.

[18]  Rodney Andrews,et al.  Aligned Multiwalled Carbon Nanotube Membranes , 2004, Science.