论文信息 - Course of oxidation of 1, 1‐disubstituted ethylenes by chromic acid

Course of oxidation of 1, 1‐disubstituted ethylenes by chromic acid

The oxidation of 1,1-diphenylethylene by chromic acid gives a fair yield of diphenylacetic acid. 1,1-Di-(p-chlorophenyl)ethylene and 2-phenylprop-1-ene are similarly oxidised to acids which have the same number of carbon atoms as the original olefins. 2-Phenyl-3,3-dimethylbut-1-ene and 1,1-di-(p-tolyl)ethylene give abnormal fission products on chromic acid oxidation. The significcane of these results is discussed.

G. Moussa | N. Eweiss

[1] R. Davis. Heat Transfer in the Goldfish, Carassius auratus , 1955 .

[2] E. I. Becker,et al. 1,1-Di-(p-chlorophenyl)-ethane , 1945 .

[3] F. Whitmore,et al. Polymerization of Olefins. VII.1 The Isolation and Oxidation of 1,1-Dineopentylethylene , 1941 .

[4] F. Whitmore,et al. The Structure of the Acids Obtained by the Oxidation of Triisobutylene. II.1 The Alpha Acid of Conant and Wheland2 , 1934 .

[5] G. W. Wheland,et al. The Structure of the Acids Obtained by the Oxidation of Tri-isobutylene , 1933 .

[6] J. Messinger. Titrimetrische Bestimmung von Aceton in Methylalkohol , 1888 .

[7] D. Peters,et al. Reactions of unsaturated compounds. Part XII. The course of oxidation of olefins by chromic acid , 1955 .

[8] W. J. Hickinbottom,et al. 361. The reactions of unsaturated compounds. Part IX. The oxidation of as-dineopentylethylene by chromic oxide , 1951 .