Review of recent developments to improve storage and transportation stability of bio-oil

The technology of fast pyrolysis is regarded as a promising route to convert lignocellulose biomass into liquid oil (bio-oil) which can be upgraded to transportable fuels and intermediate chemicals. However, the bio-oil is a complex mixture of organic compounds that are obtained in a non-equilibrium state. Therefore, the physical properties of bio-oil such as density, acidity, viscosity and chemical compositions change during storage and transportation, which is one of the most challenging problems in using bio-oil for any applications including as transportation fuels. This paper summarizes phenomena that lead to unstable properties of bio-oil and reviews recent developments in techniques used to improve the bio-oil properties for making bio-oil a stable intermediate product that can be easily handled and processed.

[1]  D. Meier,et al.  State of the art of applied fast pyrolysis of lignocellulosic materials - a review , 1999 .

[2]  A. Siriwardhana Aging and Stabilization of Pyrolitic Bio-Oils and Model Compounds , 2013 .

[3]  Hongwei Wu,et al.  Simultaneous catalytic esterification of carboxylic acids and acetalisation of aldehydes in a fast pyrolysis bio-oil from mallee biomass , 2011 .

[4]  Dinesh Mohan,et al.  Characterization of Bio-oils Produced from Fast Pyrolysis of Corn Stalks in an Auger Reactor , 2012 .

[5]  Jie Chang,et al.  Hydrogenation of Furfural as Model Reaction of Bio-Oil Stabilization under Mild Conditions Using Multiwalled Carbon Nanotube (MWNT)-Supported Pt Catalysts , 2014 .

[6]  Anja Oasmaa,et al.  Fuel oil quality of biomass pyrolysis oils-state of the art for the end users , 1999 .

[7]  Douglas C. Elliott,et al.  Catalytic Upgrading of Biomass Pyrolysis Oils , 1988 .

[8]  D. Resasco,et al.  Condensation/Hydrogenation of Biomass-Derived Oxygenates in Water/Oil Emulsions Stabilized by Nanohybrid Catalysts , 2012, Topics in Catalysis.

[9]  Joan Salvadó,et al.  Analytical methods for determining functional groups in various technical lignins , 2007 .

[10]  J. Bilbao,et al.  Transformation of Oxygenate Components of Biomass Pyrolysis Oil on a HZSM-5 Zeolite. II. Aldehydes, Ketones, and Acids , 2004 .

[11]  James P. Diebold,et al.  Additives To Lower and Stabilize the Viscosity of Pyrolysis Oils during Storage , 1997 .

[12]  J. P. Diebold,et al.  A review of the chemical and physical mechanisms of the storage stability of fast pyrolysis bio-oils , 1999 .

[13]  Ronghou Liu,et al.  Effect of hot vapor filtration on the characterization of bio-oil from rice husks with fast pyrolysis in a fluidized-bed reactor. , 2011, Bioresource technology.

[14]  A. Bridgwater,et al.  Overview of Applications of Biomass Fast Pyrolysis Oil , 2004 .

[15]  A. Dufour,et al.  Gas-phase hydrodeoxygenation of guaiacol over Fe/SiO2 catalyst , 2012 .

[16]  Charles A. Mullen,et al.  Maximizing the Stability of Pyrolysis Oil/Diesel Fuel Emulsions , 2014 .

[17]  Yu-Ting Cheng,et al.  Production of green aromatics and olefins by catalytic fast pyrolysis of wood sawdust , 2011 .

[18]  A. Oasmaa,et al.  Fast Pyrolysis of Forestry Residue. 3. Storage Stability of Liquid Fuel , 2003 .

[19]  A. Bridgwater Review of fast pyrolysis of biomass and product upgrading , 2012 .

[20]  Ronghou Liu,et al.  State of art of biomass fast pyrolysis for bio-oil in China: a review , 2008 .

[21]  Christian Roy,et al.  Bio-oils obtained by vacuum pyrolysis of softwood bark as a liquid fuel for gas turbines. Part II: Stability and ageing of bio-oil and its blends with methanol and a pyrolytic aqueous phase , 2000 .

[22]  Wei Fan,et al.  Production of renewable aromatic compounds by catalytic fast pyrolysis of lignocellulosic biomass with bifunctional Ga/ZSM-5 catalysts. , 2012, Angewandte Chemie.

[23]  R. French,et al.  Mild Hydrotreating of Bio-Oil: Effect of Reaction Severity and Fate of Oxygenated Species , 2011 .

[24]  K. Das,et al.  DSC studies to evaluate the impact of bio-oil on cold flow properties and oxidation stability of bio-diesel. , 2010, Bioresource technology.

[25]  Naoko Ellis,et al.  Upgrading Bio-oil through Emulsification with Biodiesel: Thermal Stability , 2010 .

[26]  Charles A. Mullen,et al.  Catalytic pyrolysis-GC/MS of lignin from several sources , 2010 .

[27]  Richard J. French,et al.  Mild hydrotreating of biomass pyrolysis oils to produce a suitable refinery feedstock , 2010 .

[28]  D. Meier,et al.  Norms and Standards for Pyrolysis Liquids. End-User Requirements and Specifications , 2005 .

[29]  A. Chaala,et al.  Colloidal Properties of Bio-Oils Obtained by Vacuum Pyrolysis of Softwood Bark. Storage Stability , 2004 .

[30]  Eid Alsbou,et al.  Accelerated Aging of Bio-oil from Fast Pyrolysis of Hardwood , 2014 .

[31]  G. Huber,et al.  Removal of char particles from fast pyrolysis bio-oil by microfiltration , 2010 .

[32]  Manuel Garcia-Perez,et al.  Vacuum pyrolysis of sugarcane bagasse , 2002 .

[33]  Naoko Ellis,et al.  Upgrading Bio-oil through Emulsification with Biodiesel: Mixture Production , 2010 .

[34]  B. D. Batts,et al.  A literature review on fuel stability studies with particular emphasis on diesel oil , 1991 .

[35]  Kwang Ho Kim,et al.  The effect of storage duration on bio-oil properties , 2012 .

[36]  Ronghou Liu,et al.  Upgrading of bio-oil from biomass fast pyrolysis in China: A review , 2013 .

[37]  M. Balat,et al.  An Overview of the Properties and Applications of Biomass Pyrolysis Oils , 2011 .

[38]  Tahereh Kaghazchi,et al.  Application of membrane separation processes in petrochemical industry: a review , 2009 .

[39]  Robert M. Baldwin,et al.  Bio-oil Stabilization and Upgrading by Hot Gas Filtration , 2013 .

[40]  Ji-Lu Zheng,et al.  Improving the quality of fast pyrolysis bio-oil by reduced pressure distillation , 2011 .

[41]  A. Demirbas,et al.  Chemical Valorization of Wood for Bio-fuels and Bio-chemicals , 2009 .

[42]  Akwasi A. Boateng,et al.  Characterization of Various Fast-Pyrolysis Bio-Oils by NMR Spectroscopy† , 2009 .

[43]  A. V. Bridgewater,et al.  Biomass fast pyrolysis , 2004 .

[44]  P. Paquin Technological properties of high pressure homogenizers: the effect of fat globules, milk proteins, and polysaccharides , 1999 .

[45]  Dietrich Meier,et al.  Characterization of the water-insoluble fraction from pyrolysis oil (pyrolytic lignin). Part I. PY–GC/MS, FTIR, and functional groups , 2001 .

[46]  Chun-Zhu Li,et al.  Acid-catalysed reactions between methanol and the bio-oil from the fast pyrolysis of mallee bark , 2012 .

[47]  Abolghasem Shahbazi,et al.  Bio-oil production and upgrading research: A review , 2012 .

[48]  Anja Oasmaa,et al.  Fast Pyrolysis of Forestry Residue and Pine. 4. Improvement of the Product Quality by Solvent Addition , 2004 .

[49]  U. Sedran,et al.  Fuels from bio-oils: Bio-oil production from different residual sources, characterization and thermal conditioning , 2012 .

[50]  A. Oasmaa,et al.  An Approach for Stability Measurement of Wood-Based Fast Pyrolysis Bio-Oils , 2011 .

[51]  N. Ellis,et al.  Aging and Thermal Stability of the Mixed Product of the Ether‐Soluble Fraction of Bio‐Oil and Bio‐Diesel , 2011 .

[52]  M. J. Groeneveld,et al.  Fast Pyrolysis of Biomass in a Fluidized Bed Reactor: In Situ Filtering of the Vapors , 2009 .

[53]  Matthew W. Liberatore,et al.  Physical and chemical characteristics of aging pyrolysis oils produced from hardwood and softwood feedstocks , 2011 .

[54]  Zhou Weiqi,et al.  Influence of methanol additive on bio-oil stability. , 2014 .

[55]  Theodore Dickerson,et al.  Catalytic Fast Pyrolysis: A Review , 2013 .

[56]  Ed Hogan,et al.  Emulsification of pyrolysis derived bio-oil in diesel fuel , 2003 .

[57]  G. Huber,et al.  Hydrodeoxygenation of the aqueous fraction of bio-oil with Ru/C and Pt/C catalysts , 2015 .

[58]  D. Meier,et al.  Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin) , 2001 .

[59]  Akwasi A. Boateng,et al.  Characterizing Biomass Fast Pyrolysis Oils by 13C NMR and Chemometric Analysis , 2011 .

[60]  Akwasi A. Boateng,et al.  Bench-Scale Fluidized-Bed Pyrolysis of Switchgrass for Bio-Oil Production† , 2007 .

[61]  Dennis J. Miller,et al.  A mild approach for bio-oil stabilization and upgrading: electrocatalytic hydrogenation using ruthenium supported on activated carbon cloth , 2014 .

[62]  Robert J. Farrauto,et al.  Conversion of Residual Biomass into Liquid Transportation Fuel: An Energy Analysis , 2011 .

[63]  Piyarat Weerachanchai,et al.  Effect of reaction conditions on the catalytic esterification of bio-oil , 2011, Korean Journal of Chemical Engineering.

[64]  B. Shanks,et al.  Bifunctional mesoporous organic–inorganic hybrid silica for combined one-step hydrogenation/esterification , 2010 .

[65]  S. Adhikari,et al.  Production of hydrocarbon fuels from biomass using catalytic pyrolysis under helium and hydrogen environments. , 2011, Bioresource technology.

[66]  M. Liberatore,et al.  Real-Time Viscosity Measurements during the Accelerated Aging of Biomass Pyrolysis Oil , 2011 .

[67]  A. Bridgwater,et al.  Results of the IEA round robin on viscosity and stability of fast pyrolysis bio-oils , 2012 .

[68]  R. Kandiyoti,et al.  Yields and ageing of the liquids obtained by slow pyrolysis of sorghum, switchgrass and corn stalks , 2013 .

[69]  Brent H. Shanks,et al.  Upgrading of bio-oil: Effect of light aldehydes on acetic acid removal via esterification , 2009 .

[70]  Sharon Mitchell,et al.  Prospectives for bio-oil upgrading via esterification over zeolite catalysts , 2014 .

[71]  Anja Oasmaa,et al.  State-of-the-Art of Fast Pyrolysis in IEA Bioenergy Member Countries , 2013 .

[72]  A. Bridgwater,et al.  An overview of fast pyrolysis of biomass , 1999 .

[73]  Stephen S. Kelley,et al.  Toward Understanding of Bio-Oil Aging: Accelerated Aging of Bio-Oil Fractions , 2014 .

[74]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[75]  Adisak Pattiya,et al.  Influence of a glass wool hot vapour filter on yields and properties of bio-oil derived from rapid pyrolysis of paddy residues. , 2012, Bioresource technology.

[76]  Q. Guo,et al.  Catalytic Hydrocracking of Pyrolytic Lignin to Liquid Fuel in Supercritical Ethanol , 2010 .

[77]  Peter Arendt Jensen,et al.  A review of catalytic upgrading of bio-oil to engine fuels , 2011 .

[78]  Ying Xu,et al.  Upgrading of liquid fuel from the vacuum pyrolysis of biomass over the Mo–Ni/γ-Al2O3 catalysts , 2009 .

[79]  Thermal stability of sewage sludge pyrolysis oil , 2011 .

[80]  Lin Wei,et al.  An Exploration of Improving the Properties of Heavy Bio-oil , 2013 .

[81]  D. Mohan,et al.  Pyrolysis of Wood/Biomass for Bio-oil: A Critical Review , 2006 .

[82]  Yong Wang,et al.  Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds , 2013 .

[83]  Young-Kwon Park,et al.  Fast pyrolysis of radiata pine in a bench scale plant with a fluidized bed: Influence of a char separation system and reaction conditions on the production of bio-oil , 2006 .

[84]  Anja Oasmaa,et al.  A guide to physical property characterisation of biomass-derived fast pyrolysis liquids. , 2001 .

[85]  Wolter Prins,et al.  Fast pyrolysis technology development , 2010 .

[86]  K. Das,et al.  Comparative Evaluation of Thermochemical Liquefaction and Pyrolysis for Bio-Oil Production from Microalgae , 2011 .

[87]  Ronghou Liu,et al.  Influence of acetone addition on the physicochemical properties of bio-oils , 2014 .

[88]  Anthony V. Bridgwater,et al.  Upgrading biomass fast pyrolysis liquids , 2012 .

[89]  Zhenyu Liu,et al.  Understanding the stability of pyrolysis tars from biomass in a view point of free radicals. , 2014, Bioresource technology.

[90]  A. Tudos,et al.  Possibilities and pitfalls in analyzing (upgraded) pyrolysis oil by size exclusion chromatography (SEC) , 2011 .

[91]  B. Shanks,et al.  One-Step Hydrogenation/Esterification Activity Enhancement Over Bifunctional Mesoporous Organic–Inorganic Hybrid Silicas , 2013, Topics in Catalysis.

[92]  K. Iisa,et al.  Production of Hydrocarbon Fuels from Biomass by Catalytic Fast Pyrolysis , 2012 .

[93]  Douglas C. Elliott,et al.  Historical Developments in Hydroprocessing Bio-oils , 2007 .

[94]  A. Bridgwater,et al.  In situ catalytic upgrading of bio-oil using supported molybdenum carbide , 2013 .

[95]  Stefan Czernik,et al.  Stability of wood fast pyrolysis oil , 1994 .

[96]  C. Feik,et al.  Removal of Residual Char Fines from Pyrolysis Vapors by Hot Gas Filtration , 1997 .

[97]  Young Jin Lee,et al.  Petroleomic Characterization of Bio-Oil Aging using Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry , 2014 .

[98]  Z. Qi,et al.  Review of biomass pyrolysis oil properties and upgrading research , 2007 .

[99]  G. Tompsett,et al.  Renewable high-octane gasoline by aqueous-phase hydrodeoxygenation of C₅ and C₆ carbohydrates over Pt/Zirconium phosphate catalysts. , 2010, ChemSusChem.

[100]  S. Czernik,et al.  Catalytic pyrolysis of biomass for biofuels production , 2010 .

[101]  Chun-Zhu Li,et al.  Polymerization on heating up of bio‐oil: A model compound study , 2013 .

[102]  F. Agblevor,et al.  Storage stability of biocrude oils from fast pyrolysis of poultry litter. , 2012, Waste management.

[103]  George W. Huber,et al.  Aqueous-phase hydrodeoxygenation of sorbitol with Pt/SiO2―Al2O3: Identification of reaction intermediates , 2010 .

[104]  Baosheng Jin,et al.  Influence of reaction conditions and red brick on fast pyrolysis of rice residue (husk and straw) in a spout-fluid bed , 2012 .

[105]  Qing-Xiang Guo,et al.  Esterification of Organic Acid in Bio-Oil using Acidic Ionic Liquid Catalysts , 2009 .

[106]  Douglas C. Elliott,et al.  Catalytic Hydroprocessing of Chemical Models for Bio-oil , 2009 .

[107]  D. Elliott,et al.  Development of the Basis for an Analytical Protocol for Feeds and Products of Bio-oil Hydrotreatment , 2012 .

[108]  G. H. Schenk Organic Functional Group Analysis: Theory and Development , 1968 .

[109]  Burton C. English,et al.  Effects of high-pressure homogenization on physicochemical properties and storage stability of switchgrass bio-oil , 2009 .

[110]  Keshav C. Das,et al.  Comparison of three accelerated aging procedures to assess bio-oil stability , 2010 .

[111]  Manuel Garcia-Perez,et al.  Production and fuel properties of pine chip bio-oil/biodiesel blends , 2007 .

[112]  S. Kelley,et al.  Identification of free radicals in pyrolysis oil and their impact on bio-oil stability , 2014 .