Hydrothermal Carbonization of Peat Moss and Herbaceous Biomass (Miscanthus): A Potential Route for Bioenergy

Peat moss and miscanthus were hydrothermally carbonized (HTC) either individually or co-processed in a different ratio to produce hydrochar. The hydrochar and pelletized hydrochar were then characterized to determine if hydrochar can be used as an alternative to coal to produce bioenergy from existing coal-fired power plants in Ontario that have already been shut down. The properties of carbonized biomass (either hydrochar or pellets) reveal that fuel grade hydrochar can be produced from peat moss or from the blend of peat moss and miscanthus (agricultural biomass/energy crops). Hydrochar either produced from peat moss or from the blend of peat moss and miscanthus was observed to be hydrophobic and porous compared to raw peat moss or raw miscanthus. The combustion indices of carbonized biomass confirmed that it can be combusted or co-combusted to produce bioenergy and can avoid slagging, fouling, and agglomeration problems of the bioenergy industry. The results of this study revealed that HTC is a promising option for producing solid biofuel from undervalued biomass, especially from high moisture biomass. Co-processing of peat moss with rural biomass, a relatively novel idea which can be a potential solution to heat and power for the rural communities/agri-industry that are not connected with national grids and alleviate their waste management problems. In addition, the hydrochar can also be used to run some of the existing coal-fired power plants that have already been shut down in Ontario without interrupting investment and employment.

[1]  Victor R. Vasquez,et al.  Pelletization of biochar from hydrothermally carbonized wood , 2012 .

[2]  A. Ross,et al.  Phosphate and ammonium sorption capacity of biochar and hydrochar from different wastes. , 2016, Chemosphere.

[3]  J. Chen,et al.  Maintaining the role of Canada’s forests and peatlands in climate regulation , 2010 .

[4]  D. Choi,et al.  Effect of binders on the durability of wood pellets fabricated from Larix kaemferi C. and Liriodendron tulipifera L. sawdust , 2014 .

[5]  P. Rudz Carbon and Nutrient Dynamics of Downed Woody Debris in a Northern Hardwood Forest , 2013 .

[6]  Animesh Dutta,et al.  Strength, storage, and combustion characteristics of densified lignocellulosic biomass produced via torrefaction and hydrothermal carbonization , 2014 .

[7]  T. Moore Growth and net production of Sphagnum at five fen sites, subarctic eastern Canada , 1989 .

[8]  K. Yoshikawa,et al.  Development of an ultra-small biomass gasification and power generation system: Part 1. A novel carbonization process and optimization of pelletization of carbonized wood char , 2017 .

[9]  Robin J. White,et al.  Black perspectives for a green future: hydrothermal carbons for environment protection and energy storage , 2012 .

[10]  Pusker Regmi,et al.  Removal of copper and cadmium from aqueous solution using switchgrass biochar produced via hydrothermal carbonization process. , 2012, Journal of environmental management.

[11]  U. Henriksen,et al.  Fuel pellets from biomass: The importance of the pelletizing pressure and its dependency on the processing conditions , 2011 .

[12]  N. Bolan,et al.  Biochar : Production, Characterization, and Applications , 2015 .

[13]  Shahab Sokhansanj,et al.  Pelletization of torrefied sawdust and properties of torrefied pellets , 2012 .

[14]  Animesh Dutta,et al.  Impact of agronomic treatments on fuel characteristics of herbaceous biomass for combustion , 2013 .

[15]  Andrew Rowe,et al.  A techno-economic analysis of using mobile distributed pyrolysis facilities to deliver a forest residue resource. , 2013, Bioresource technology.

[16]  G. Zeng,et al.  Co-pelletization of sewage sludge and biomass: the density and hardness of pellet. , 2014, Bioresource technology.

[17]  W. Cong,et al.  Ultrasonic vibration-assisted pelleting for cellulosic biofuels manufacturing: A study on in-pellet temperatures , 2015 .

[18]  M. Reza,et al.  Hydrothermal carbonization: Fate of inorganics , 2013 .

[19]  Despina Vamvuka,et al.  Predicting the behaviour of ash from agricultural wastes during combustion , 2004 .

[20]  S. P. Mathur,et al.  Relationship between acid phosphatase activities and decomposition rates of twenty‐two virgin peat materials , 1980 .

[21]  L. R. Belyea Separating the effects of litter quality and microenvironment on decomposition rates in a patterned peatland , 1996 .

[22]  R. .. Morey,et al.  Factors affecting strength and durability of densified biomass products. , 2009 .

[23]  A. Funke,et al.  Hydrothermal carbonization of biomass: A summary and discussion of chemical mechanisms for process engineering , 2010 .

[24]  Animesh Dutta,et al.  A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications , 2015 .

[25]  A. Lyngfelt,et al.  Ash behaviour in a CFB boiler during combustion of coal, peat or wood , 1998 .

[26]  Nicolin Plank THE NATURE OF CELLULOSE IN SPHAGNUM , 1946 .

[27]  Steve Frolking,et al.  Peatlands and Their Role in the Global Carbon Cycle , 2011 .

[28]  P. Jansens,et al.  Biomass combustion in fluidized bed boilers: Potential problems and remedies , 2009 .

[29]  U. Henriksen,et al.  Validation of a Multiparameter Model To Investigate Torrefied Biomass Pelletization Behavior , 2017 .

[30]  T. Murugesan,et al.  Degradation of Alizarin Yellow R using UV/H2O2 advanced oxidation process , 2014 .

[31]  N. H. Ravindranath,et al.  Jatropha cultivation in southern India: assessing farmers' experiences , 2012 .

[32]  Shouyu Zhang,et al.  High-strength charcoal briquette preparation from hydrothermal pretreated biomass wastes. , 2018 .

[33]  A. Pantaleo,et al.  Influence of process parameters and biomass characteristics on the durability of pellets from the pruning residues of Olea europaea L. , 2011 .

[34]  Naoto Shimizu,et al.  Effect of Temperature Distribution on the Quality of Parboiled Rice Produced by Traditional Parboiling Process , 2004 .

[35]  Julian Cleary,et al.  Greenhouse Gas Emissions from Canadian Peat Extraction, 1990–2000: A Life-cycle Analysis , 2005 .

[36]  Robert Samuelsson,et al.  Effects of moisture content, torrefaction temperature, and die temperature in pilot scale pelletizing of torrefied Norway spruce , 2013 .

[37]  V. Farmer,et al.  Lignin in sphagnum and phragmites and in peats derived from these plants , 1964 .

[38]  A. Corma,et al.  The hydrothermal carbonization (HTC) plant as a decentral biorefinery for wet biomass , 2015 .

[39]  R. B. Williams,et al.  Release of Inorganic Constituents from Leached Biomass during Thermal Conversion , 1999 .

[40]  Y. Ok,et al.  Minireview of potential applications of hydrochar derived from hydrothermal carbonization of biomass , 2018 .

[41]  E. Vakkilainen,et al.  Hydrothermal carbonization of coniferous biomass: Effect of process parameters on mass and energy yields , 2015 .

[42]  Danchen Zhu,et al.  The densification of bio-char: Effect of pyrolysis temperature on the qualities of pellets. , 2016, Bioresource technology.

[43]  Animesh Dutta,et al.  An investigation of raw and torrefied lignocellulosic biomasses with CaO during combustion , 2017, Journal of the Energy Institute.

[44]  A. Buttler,et al.  Plant Litter Decomposition and Nutrient Release in Peatlands , 2013 .

[45]  R. Davis Peat respiration and decomposition in Antarctic terrestrial moss communities , 1980 .

[46]  M. Reza,et al.  Engineered pellets from dry torrefied and HTC biochar blends , 2014 .

[47]  R. .. Morey,et al.  Natural binders and solid bridge type binding mechanisms in briquettes and pellets made from corn stover and switchgrass. , 2010, Bioresource technology.

[48]  E. Tuittila,et al.  Peatlands in the Earth's 21st century climate system , 2011 .

[49]  Timothy M. Weis,et al.  Renewable is Doable: Affordable and flexible options for Ontario's long term energy plan , 2013 .

[50]  M.J.A. van den Oever,et al.  Process for production of high density/high performance binderless boards from whole coconut husk: Part 1: Lignin as intrinsic thermosetting binder resin , 2004 .

[51]  Animesh Dutta,et al.  Comparative evaluation of torrefaction and hydrothermal carbonization of lignocellulosic biomass for the production of solid biofuel , 2015 .

[52]  S. Frolking,et al.  Modeling Northern Peatland Decomposition and Peat Accumulation , 2001, Ecosystems.

[53]  P. Parker,et al.  Dehydration of Flocs by Freezing , 1999 .

[54]  W. E. Farthing,et al.  Hydrothermal carbonization (HTC) of loblolly pine using a continuous, reactive twin-screw extruder , 2017 .

[55]  Victor R. Vasquez,et al.  Thermal pretreatment of lignocellulosic biomass , 2009 .

[56]  G. Zeng,et al.  Complementary effects of torrefaction and co-pelletization: Energy consumption and characteristics of pellets. , 2015, Bioresource technology.