A simple evaluation of microstructure and transport parameters of ion-exchange membranes from conductivity measurements

Ion-exchange membranes (IEMs) have received considerable attentions due to their wide application in cleaning production and environmental protection. In this background, modeling the ion-exchange membrane processes and correlating the parameters become necessary and important. This paper reported a simple procedure to simultaneously evaluate the transport and structural parameters on the basis of conductivity measurements together with the data of the conventional ion-exchange capacity and water uptake. Most of the commercial membranes and a series of lab-made membranes were used for the modeling, and the characteristic parameters for the ion-exchange membrane microstructure were correlated.

[1]  S. Moon,et al.  Heterogeneity of Ion-Exchange Membranes: The Effects of Membrane Heterogeneity on Transport Properties. , 2001, Journal of colloid and interface science.

[2]  R. F. Hill,et al.  Development of a space‐charge transport model for ion‐exchange membranes , 1990 .

[3]  Victor Nikonenko,et al.  A simplified procedure for ion-exchange membrane characterisation , 2004 .

[4]  Jae-Hwan Choi,et al.  Pore size characterization of cation-exchange membranes by chronopotentiometry using homologous amine ions , 2001 .

[5]  I. G. Wenten,et al.  Performance of a novel electrodeionization technique during citric acid recovery , 2004 .

[6]  Seung-Hyeon Moon,et al.  Electrochemical characterization of sulfonated poly(arylene ether sulfone) (S-PES) cation-exchange membranes , 2003 .

[7]  S. Koter,et al.  Electromembrane Processes in Environment Protection , 2000 .

[8]  N. Kononenko,et al.  Physicochemical principles of testing ion-exchange membranes , 1996 .

[9]  Marie-Laure Lameloise,et al.  Complete Decalcification of Saline Effluent by Associating a Carboxylic Resin with a Chelating Resin , 2006 .

[10]  S. Moon,et al.  Electrodialytic separation characteristics of large molecular organic acid in highly water-swollen cation-exchange membranes , 2003 .

[11]  C. Gardner,et al.  Comparison of the transport properties of normal and expanded forms of a cation-exchange membrane by use of an irreversible thermodynamic approach. Part I. Membranes in the sodium form in 0·1M-sodium chloride , 1971 .

[12]  O. Kedem,et al.  Description of the transport of solvent and ions through membranes in terms of differential coefficients. Part 1.—Phenomenological characterization of flows , 1961 .

[13]  Victor Nikonenko,et al.  Effect of structural membrane inhomogeneity on transport properties , 1993 .

[14]  Victor Nikonenko,et al.  Correlation between transport parameters of ion-exchange membranes , 2002 .

[15]  T. Xu,et al.  Application of electrodialysis to the production of organic acids: State-of-the-art and recent developments , 2007 .

[16]  Inamuddin,et al.  Applications of Hg(II) sensitive polyaniline Sn(IV) phosphate composite cation-exchange material in determination of Hg2+ from aqueous solutions and in making ion-selective membrane electrode , 2006 .

[17]  Liang Wu,et al.  Fundamental studies of a new series of anion exchange membranes: Membranes prepared through chloroacetylation of poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) followed by quaternary amination , 2006 .

[18]  N. Berezina,et al.  Water electrotransport in membrane systems. Experiment and model description , 1994 .

[19]  Chuanhui Huang,et al.  Electrodialysis with bipolar membranes for sustainable development. , 2006, Environmental science & technology.

[20]  R K Nagarale,et al.  Recent developments on ion-exchange membranes and electro-membrane processes. , 2006, Advances in colloid and interface science.

[21]  T. Xu Ion exchange membranes: State of their development and perspective , 2005 .

[22]  A. Katchalsky,et al.  Permeability of composite membranes. Part 1.—Electric current, volume flow and flow of solute through membranes , 1963 .

[23]  S. Koter,et al.  Ions and water transport across charged nafion membranes. Irreversible thermodynamics approach , 1984 .

[24]  N. Kononenko,et al.  Transport structural parameters to characterize ion exchange membranes , 2004 .

[25]  S. Koter Transport number of counterions in ion-exchange membranes , 2001 .

[26]  C. Innocent,et al.  Electrodialysis with ion exchange membranes in organic media , 2005 .

[27]  Adrian Oehmen,et al.  Removal of heavy metals from drinking water supplies through the ion exchange membrane bioreactor , 2006 .

[28]  Yang Weihua,et al.  Ionic conductivity threshold in sulfonated poly (phenylene oxide) matrices: a combination of three-phase model and percolation theory , 2001 .

[29]  S. Koter Transport of simple electrolyte solutions through ion-exchange membranes—the capillary model , 2002 .

[30]  S. Sridhar,et al.  Electrodialysis in a non-aqueous medium: production of sodium methoxide , 1996 .

[31]  O. Kedem The role of volume flow in electrodialysis , 2002 .

[32]  T. Xu,et al.  Fundamental studies of a new series of anion exchange membranes: membrane preparation and characterization , 2001 .