Polymerization and Copolymerization of a New N‐Propargylamide Monomer Having a Pendant Galactose Residue to Produce Sugar‐Carrying Poly(N‐propargylamide)s

Rh‐catalyzed polymerization of a new N‐propargylamide monomer having a galactose residue was investigated. The polymerization proceeded in a mixed solvent of THF and water to produce the galactose‐carrying poly(N‐propargylamide) consisting of cis‐isomer. The copolymerization of the monomer with the N‐propargylamide having the alkyl chain was also carried out.

[1]  Y. Kaneko,et al.  Synthesis of rodlike polysiloxane containing polyol moieties derived from glucose with regularly controlled higher-ordered structure , 2005 .

[2]  J. Kadokawa,et al.  Synthesis of Glucose‐Containing Polyaniline by the Oxidative Polymerization of N‐Glucosylaniline , 2005 .

[3]  J. Tabei,et al.  Variation of helical pitches driven by the composition of N-propargylamide copolymers , 2004 .

[4]  J. Tabei,et al.  Conformational transition between random coil and helix of poly(N-propargylamides) , 2004 .

[5]  S. Armes,et al.  Synthesis and aqueous solution properties of novel sugar methacrylate-based homopolymers and block copolymers. , 2003, Biomacromolecules.

[6]  T. Masuda,et al.  Synthesis and Properties of Amino Acid-Based Polyacetylenes , 2003 .

[7]  James N. Wilson,et al.  Synthesis and mesoscopic order of a sugar-coated poly(p-phenyleneethynylene) , 2002 .

[8]  E. Yashima,et al.  Switching of a macromolecular helicity for visual distinction of molecular recognition events. , 2001, Journal of the American Chemical Society.

[9]  M. Okada.  Molecular design and syntheses of glycopolymers , 2001 .

[10]  R C Stevens,et al.  Design and synthesis of novel glycopolythiophene assemblies for colorimetric detection of influenza virus and E. coli. , 2000, Bioconjugate chemistry.

[11]  Kazukiyo Kobayashi,et al.  Rigid Helical Poly(glycosyl phenyl isocyanide)s: Synthesis, Conformational Analysis, and Recognition by Lectins , 1999 .

[12]  Yoshikazu Sadahiro,et al.  Precise synthesis of monosubstituted polyacetylenes using Rh complex catalysts. Control of solid structure and π-conjugation length , 1999 .

[13]  K. Matsuura,et al.  Helical Stereoregular Artificial Glycoconjugate Polymers Based on Poly (phenylacetylene) Backbone : Synthesis and Molecular Recognition with Lectin , 1998 .

[14]  J. Stenger-Smith.  Intrinsically electrically conducting polymers. Synthesis, characterization, and their applications , 1998 .

[15]  L. Kiessling,et al.  Strength in numbers: non-natural polyvalent carbohydrate derivatives. , 1996, Chemistry & biology.

[16]  T. Akaike,et al.  Culturing hepatocytes on lactose-carrying polystyrene layer via asialoglycoprotein receptor-mediated interactions. , 1994, Methods in enzymology.

[17]  R. Schrock,et al.  .pi.-Bonded complexes of the tetraphenylborate ion with rhodium(I) and iridium(I) , 1970 .