A superconcentrated ether electrolyte for fast-charging Li-ion batteries.

We have found ultrafast Li(+) intercalation into graphite in a superconcentrated ether electrolyte, even exceeding that in a currently used commercial electrolyte. This discovery is an important breakthrough toward fast-charging Li-ion batteries far beyond present technologies.

[1]  Daniel M. Seo,et al.  Electrolyte Solvation and Ionic Association II. Acetonitrile-Lithium Salt Mixtures: Highly Dissociated Salts , 2012 .

[2]  H. Sakaebe,et al.  Fast cycling of Li/LiCoO2 cell with low-viscosity ionic liquids based on bis(fluorosulfonyl)imide [FSI]− , 2006 .

[3]  Yuki Yamada,et al.  Electrochemical Lithium Intercalation into Graphite in Dimethyl Sulfoxide-Based Electrolytes: Effect of Solvation Structure of Lithium Ion , 2010 .

[4]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[5]  M. Ishikawa,et al.  Charge-Discharge Characteristics of a LiNi1/3Mn1/3Co1/3O2 Cathode in FSI-based Ionic Liquids , 2012 .

[6]  T. Abe,et al.  Correlation Between Cointercalation of Solvents and Electrochemical Intercalation of Lithium into Graphite in Propylene Carbonate Solution , 2003 .

[7]  J. Besenhard The electrochemical preparation and properties of ionic alkali metal-and NR4-graphite intercalation compounds in organic electrolytes , 1976 .

[8]  T. Abe,et al.  Lithium-Ion Transfer at the Interface Between Lithium-Ion Conductive Ceramic Electrolyte and Liquid Electrolyte-A Key to Enhancing the Rate Capability of Lithium-Ion Batteries , 2005 .

[9]  K. Amine,et al.  Change of Conductivity with Salt Content, Solvent Composition, and Temperature for Electrolytes of LiPF6 in Ethylene Carbonate-Ethyl Methyl Carbonate , 2001 .

[10]  W. Henderson,et al.  Glyme-lithium salt phase behavior. , 2006, The journal of physical chemistry. B.

[11]  M. Ishikawa,et al.  High-performance graphite negative electrode in a bis(fluorosulfonyl)imide-based ionic liquid , 2013 .

[12]  D. Wilkinson,et al.  Conductivity of electrolytes for rechargeable lithium batteries , 1991 .

[13]  T. Abe,et al.  Electrochemical intercalation of lithium ion within graphite from propylene carbonate solutions , 2003 .

[14]  M. Ishikawa,et al.  Pure ionic liquid electrolytes compatible with a graphitized carbon negative electrode in rechargeable lithium-ion batteries , 2006 .

[15]  G. Nazri,et al.  Raman Spectra and Transport Properties of Lithium Perchlorate in Ethylene Carbonate Based Binary Solvent Systems for Lithium Batteries , 1998 .

[16]  D. Macfarlane,et al.  Fast Charge/Discharge of Li Metal Batteries Using an Ionic Liquid Electrolyte , 2013 .

[17]  A. Dey,et al.  The Electrochemical Decomposition of Propylene Carbonate on Graphite , 1970 .

[18]  S. Seki,et al.  Intermolecular interactions in Li+-glyme and Li+-glyme-TFSA- complexes: relationship with physicochemical properties of [Li(glyme)][TFSA] ionic liquids. , 2013, Chemphyschem : a European journal of chemical physics and physical chemistry.

[19]  Hiroatsu Matsuura,et al.  Density Functional Study of the Conformations and Vibrations of 1,2-Dimethoxyethane , 1998 .

[20]  Yuki Yamada,et al.  Kinetics of lithium ion transfer at the interface between graphite and liquid electrolytes: effects of solvent and surface film. , 2009, Langmuir : the ACS journal of surfaces and colloids.

[21]  T. Jow,et al.  Solvation sheath of Li+ in nonaqueous electrolytes and its implication of graphite/ electrolyte interface chemistry , 2007 .

[22]  M. Ratner,et al.  Vibrational Spectroscopic Determination of Structure and Ion Pairing in Complexes of Poly(ethylene oxide) with Lithium Salts , 1982 .

[23]  D. Aurbach,et al.  Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems , 1997 .