Paraffin wax mixtures as phase change materials

Abstract Melting of the binary mixture system of tetradecane and hexadecane in Differential Scanning Calorimetry (DSC) cell has been investigated experimentally and numerically. Different concentrations of tetradecane–hexadecane paraffin mixture were studied. It is found that the phase change process of the binary mixture takes place over a temperature range and the temperature range depends on both the heating rate and the mixture composition. The proposed study shows also that for the same concentration of tetradecane and using various heating rates, we will be able to predict the solidus and liquidus temperature of the binary mixture from DSC curves.

[1]  He Bo,et al.  Tetradecane and hexadecane binary mixtures as phase change materials (PCMs) for cool storage in district cooling systems , 1999 .

[2]  J. Selman,et al.  A novel thermal management system for electric vehicle batteries using phase-change material , 2000 .

[3]  Tarik Kousksou,et al.  Numerical simulation of fluid flow and heat transfer in a phase change thermal energy storage , 2008 .

[4]  W. M. Mazee Thermal analysis of normal alkanes , 1957 .

[5]  Yajuan Zhong,et al.  Heat transfer enhancement of paraffin wax using graphite foam for thermal energy storage , 2010 .

[6]  Young I. Cho,et al.  Thermal analysis of the mixture of laboratory and commercial grades hexadecane and tetradecane , 1992 .

[7]  T. Kousksou,et al.  Thermal analysis of phase change emulsion , 2009 .

[8]  Kamil Kaygusuz,et al.  Thermal Energy Storage System Using a Technical Grade Paraffin Wax as Latent Heat Energy Storage Material , 2005 .

[9]  Jerzy Banaszek,et al.  Numerical analysis of the paraffin wax-air spiral thermal energy storage unit , 2000 .

[10]  X. Py,et al.  Highly conductive composites made of phase change materials and graphite for thermal storage , 2008 .

[11]  Tarik Kousksou,et al.  DSC study and computer modelling of the melting process in ice slurry , 2006 .

[12]  Luisa F. Cabeza,et al.  Review on thermal energy storage with phase change: materials, heat transfer analysis and applications , 2003 .

[13]  L. Drzal,et al.  High latent heat storage and high thermal conductive phase change materials using exfoliated graphite nanoplatelets , 2009 .

[14]  A. Sharma,et al.  Review on thermal energy storage with phase change materials and applications , 2009 .

[15]  Fredrik Setterwall,et al.  Liquid–solid phase equilibrium study of tetradecane and hexadecane binary mixtures as phase change materials (PCMs) for comfort cooling storage , 2003 .

[16]  I. Paunovic,et al.  Liquid–solid phase transformation of C16H34, C28H58 and C41H84 and their binary and ternary mixtures , 2000 .

[17]  J. Timmermans The physico-chemical constants of binary systems in concentrated solutions , 1959 .

[18]  Tarik Kousksou,et al.  Dynamic modelling of the storage of an encapsulated ice tank , 2005 .

[19]  A. Sari,et al.  Preparation, thermal properties and thermal reliability of palmitic acid/expanded graphite composite as form-stable PCM for thermal energy storage , 2009 .

[20]  Amar M. Khudhair,et al.  A review on phase change energy storage: materials and applications , 2004 .

[21]  X. Py,et al.  Paraffin/porous-graphite-matrix composite as a high and constant power thermal storage material , 2001 .

[22]  A. Hammami,et al.  Liquid-solid-solid thermal behaviour of n-C44H90 + n-C50H102 and n-C25H52 + n-C28H58 paraffinic binary mixtures , 1995 .

[23]  T. Kousksou,et al.  Equilibrium liquidus temperatures of binary mixtures from differential scanning calorimetry , 2007 .

[24]  A. Bejan,et al.  Thermal Energy Storage: Systems and Applications , 2002 .

[25]  S. H. Choi,et al.  Thermal characteristics of paraffin in a spherical capsule during freezing and melting processes , 2000 .

[26]  Fredrik Setterwall,et al.  Phase transition temperature ranges and storage density of paraffin wax phase change materials , 2004 .

[27]  D. A. Neeper,et al.  Thermal dynamics of wallboard with latent heat storage , 2000 .