Feedstocks for biodiesel production

Abstract: Globally dominating feedstocks for biodiesel production nowadays are mainly rapeseed, soybean, sunflower and palm oils; animal fats (tallow) and recycled frying oils are minor contributors. This chapter describes the main characteristics of the major and minor first-generation foodstocks for biodiesel production and the short- to medium-term prospects of second-generation, non-edible feedstocks (in particular Jatropha and algae) and various highly acidic, low-quality oils for the same purpose. Biodiesel outlooks are differing geographically as a result of the prevailing agronomic and climatic conditions. Important developments can be observed in various parts of the world.

[1]  Y. Chisti.  Biodiesel from microalgae. , 2007, Biotechnology advances.

[2]  A. Hamama,et al.  Oil, erucic acid, and glucosinolate contents in winter hardy rapeseed germplasms. , 2000 .

[3]  G. Rowland.  An EMS-induced low-linolenic-acid mutant in McGregor flax (Linum usitatissimum L.) , 1991 .

[4]  D. Murphy.  Designer oil crops: breeding, processing and biotechnology. , 1994 .

[5]  W. H. Wu,et al.  Optimizing production of ethyl esters of grease using 95% ethanol by response surface methodology , 1999 .

[6]  T. Foglia,et al.  Lipase-catalyzed production of biodiesel , 1996 .

[7]  Jan Hazebroek,et al.  New sunflower and soybean cultivars for novel vegetable oil types , 1998 .

[8]  W. Friedt,et al.  Genetic modification of saturated fatty acids in oilseed rape (Brassica napus) , 2005 .

[9]  D. West,et al.  Low-palmitic, low-linolenic soybean development , 2003 .

[10]  J. Myers,et al.  On the heterotrophic growth of Chlorella pyrenoidosa. , 1958, Journal of general microbiology.

[11]  K. Terry,et al.  System design for the autotrophic production of microalgae , 1985 .

[12]  D. Knauft,et al.  Fatty Acid Genotypes of Five Virginia-Type Peanut Cultivars , 1996 .

[13]  M. Martínez,et al.  PILOT PLANT STUDIES OF BIODIESEL PRODUCTION USING BRASSICA CARINATA AS RAW MATERIAL , 2005 .

[14]  M Mittelbach,et al.  Conversion of sewage sludge into lipids by Lipomyces starkeyi for biodiesel production. , 2008, Bioresource technology.

[15]  A. Green,et al.  Linola™ 989 low linolenic flax , 1996 .

[16]  C. Möllers,et al.  Toward increasing erucic acid content in oilseed rape (Brassica napus L.) through the combination with genes for high oleic acid , 2005 .

[17]  Transesterification of heated rapeseed oil for extending diesel fuel , 1999 .

[18]  K. Hamasaki,et al.  Utilization of waste vegetable oil methyl ester for diesel fuel , 2001 .

[19]  Voelker,et al.  Lysophosphatidic acid acyltransferase from coconut endosperm mediates the insertion of laurate at the sn-2 position of triacylglycerols in lauric rapeseed oil and can increase total laurate levels , 1999, Plant physiology.

[20]  F. Shahidi,et al.  Marine Mammal Oils , 2005, Bailey's Industrial Oil and Fat Products.

[21]  Jeff Shrager,et al.  Alternative photosynthetic electron flow to oxygen in marine Synechococcus. , 2008, Biochimica et biophysica acta.

[22]  Michele Aresta,et al.  Production of biodiesel from macroalgae by supercritical CO2 extraction and thermochemical liquefaction , 2005 .

[23]  D. A. Knauft,et al.  Variability in oil quality among peanut genotypes in the Florida breeding program , 1987 .

[24]  E. Booth,et al.  Agricultural aspects of rape and other Brassica products , 2001 .

[25]  T. Voelker,et al.  Genetic engineering of a quantitative trait: metabolic and genetic parameters influencing the accumulation of laurate in rapeseed , 1996 .

[26]  Robert O. Dunn,et al.  Low-temperature properties of alkyl esters of tallow and grease , 1997 .

[27]  José M. Encinar,et al.  Preparation and Properties of Biodiesel from Cynara cardunculus L. Oil , 1999 .

[28]  J. Encinar,et al.  Biodiesel from Used Frying Oil. Variables Affecting the Yields and Characteristics of the Biodiesel , 2005 .

[29]  J. Morton.  The horseradish tree,Moringa pterygosperma (Moringaceae)—A boon to Arid Lands? , 1991, Economic Botany.

[30]  O. Njoku,et al.  Production of biodiesel using rubber [Hevea brasiliensis (Kunth. Muell.)] seed oil , 2000 .

[31]  Neal A. Bringe,et al.  Soybean Oil Composition for Biodiesel , 2005 .

[32]  David L. Parry,et al.  The gross chemical composition and fatty acid composition of 18 species of tropical Australian microalgae for possible use in mariculture , 1999 .

[33]  H. Portugal,et al.  Effects of salmon oil and corn oil on plasma lipid level and hepato-biliary cholesterol metabolism in rats. , 1990, Biochimica et biophysica acta.

[34]  A. Carvalho,et al.  Microalgal Reactors: A Review of Enclosed System Designs and Performances , 2006, Biotechnology progress.

[35]  B. Butler,et al.  Calculating the lodine value for marine oils from fatty acid profiles , 1998 .

[36]  M. J. Nye,et al.  Conversion of used frying oil to diesel fuel by transesterification: Preliminary tests , 1983 .

[37]  T. Foglia,et al.  Production of alkyl esters from tallow and grease using lipase immobilized in a phyllosilicate sol-gel , 2001 .

[38]  H. Raheman,et al.  Biodiesel production from mahua (Madhuca indica) oil having high free fatty acids , 2005 .

[39]  M. Lagarde,et al.  Effect of dietary argan oil on fatty acid composition, proliferation, and phospholipase D activity of rat thymocytes. , 2006, Nutrition.

[40]  A. Grossman,et al.  Trophic Conversion of an Obligate Photoautotrophic Organism Through Metabolic Engineering , 2001, Science.

[41]  D. Parry,et al.  Effect of light intensity on the proximate biochemical and fatty acid composition of Isochrysis sp. and Nannochloropsis oculata for use in tropical aquaculture , 1991, Journal of Applied Phycology.

[42]  Ján Cvengroš,et al.  Used frying oils and fats and their utilization in the production of methyl esters of higher fatty acids , 2004 .

[43]  A. Kinney,et al.  Modifying soybean oil for enhanced performance in biodiesel blends , 2005 .

[44]  M. Haas.  Improving the economics of biodiesel production through the use of low value lipids as feedstocks: vegetable oil soapstock , 2005 .

[45]  H. Raheman,et al.  Process optimization for biodiesel production from mahua (Madhuca indica) oil using response surface methodology. , 2006, Bioresource technology.

[46]  Milford A. Hanna,et al.  Preparation and properties of methyl esters of beef tallow , 1996 .

[47]  Rudolph Diesel,et al.  THE DIESEL OIL ENGINE. , 1912 .

[48]  W. Jacoby,et al.  Conversion of the Rosin Acid Fraction of Crude Tall Oil into Fuels and Chemicals , 2001 .

[49]  Nick Nagle,et al.  Production of methyl ester fuel from microalgae , 1990 .

[50]  J. F. González,et al.  Biodiesel Fuels from Vegetable Oils: Transesterification of Cynara cardunculus L. Oils with Ethanol , 2002 .

[51]  N. Vedaraman,et al.  Mahua oil (Madhuca Indica seed oil) methyl ester as biodiesel-preparation and emission characterstics , 2005 .

[52]  Michael Wink,et al.  Studies on nutritive potential and toxic constituents of different provenances of Jatropha curcas , 1997 .

[53]  Ram Prasad,et al.  TRIGLYCERIDES-BASED DIESEL FUELS , 2000 .

[54]  D. Auld,et al.  Rapeseed Mutants with Reduced Levels of Polyunsaturated Fatty Acids and Increased Levels of Oleic Acid , 1992 .

[55]  Dere A. Okiy,et al.  Recovery of oil via acid-catalyzed transesterification , 2003 .

[56]  J. T. Barminas,et al.  A preliminary investigation into the biofuel characteristics of tigernut (Cyperus esculentus) oil. , 2001, Bioresource technology.

[57]  Yoshio Tominaga,et al.  Enzymatic conversion of waste edible oil to biodiesel fuel in a fixed-bed bioreactor , 2001 .

[58]  M. I. Wahbeh.  Amino acid and fatty acid profiles of four species of macroalgae from Aqaba and their suitability for use in fish diets , 1997 .

[59]  M. Zong,et al.  Efficient lipid production with Trichosporon fermentans and its use for biodiesel preparation. , 2008, Bioresource technology.

[60]  J. H. Van Gerpen,et al.  A pilot plant to produce biodiesel from high free fatty acid feedstocks. , 2003 .

[61]  H. Gunnlaugsdottir,et al.  Process parameters influencing ethanolysis of cod liver oil in supercritical carbon dioxide , 1998 .

[62]  F. Gunstone.  Oilseed Crops with Modified Fatty Acid Composition , 2001 .

[63]  Ayhan Demirbas,et al.  Oily Products from Mosses and Algae via Pyrolysis , 2006 .

[64]  Recovery of corn oil from ethanol extracts of ground corn using membrane technology , 2005 .

[65]  Norbert Martini,et al.  Plant Oils as Fuels , 1998 .

[66]  Qingyu Wu,et al.  High-density fermentation of microalga Chlorella protothecoides in bioreactor for microbio-diesel production , 2008, Applied Microbiology and Biotechnology.

[67]  Enoch Y. Park,et al.  Potential application of waste activated bleaching earth on the production of fatty acid alkyl esters using Candida cylindracea lipase in organic solvent system , 2004 .

[68]  N. Dunford,et al.  New hihg-oleic peanut cultivars grown in the Southwestern United States , 2005 .

[69]  Sanjib Kumar Karmee,et al.  Preparation of biodiesel from crude oil of Pongamia pinnata. , 2005, Bioresource technology.

[70]  M. Ghirardi,et al.  Microalgae: a green source of renewable H(2). , 2000, Trends in biotechnology.

[71]  Yusuf Chisti,et al.  Biotechnology-a sustainable alternative for chemical industry. , 2005, Biotechnology advances.

[72]  E. Tarantino,et al.  Changes in seed yield and oil fatty acid composition of high oleic sunflower (Helianthus annuus L.) hybrids in relation to the sowing date and the water regime , 2002 .

[73]  F. Orthoefer.  Rice Bran Oil , 2005, Bailey's Industrial Oil and Fat Products.

[74]  W. Keller,et al.  Utility of the Arabidopsis FAE1 and yeast SLC1-1 genes for improvements in erucic acid and oil content in rapeseed. , 2000, Biochemical Society transactions.

[75]  F. R. Voort,et al.  Determination of free fatty acids in crude palm oil and refined-bleached-deodorized palm olein using fourier transform infrared spectroscopy , 1999 .

[76]  C. Chu,et al.  A preliminary study on the introduction and cultivation of Crambe abyssinica in China, an oil plant for industrial uses. , 2000 .

[77]  A. K. Vasishtha,et al.  Changes in the characteristics and composition of oils during deep-fat frying , 1996 .

[78]  X. Miao,et al.  Biodiesel production from heterotrophic microalgal oil. , 2006, Bioresource technology.

[79]  S. Bhathena,et al.  The effect of dietary menhaden, olive, and coconut oil fed with three levels of vitamin E on plasma and liver lipids and plasma fatty acid composition in rats. , 2002, The Journal of nutritional biochemistry.

[80]  Mano Misra,et al.  Spent coffee grounds as a versatile source of green energy. , 2008, Journal of agricultural and food chemistry.

[81]  K. Pramanik.  Properties and use of jatropha curcas oil and diesel fuel blends in compression ignition engine , 2003 .

[82]  M. H. Chakrabarti,et al.  Trans esterification studies on castor oil as a first step towards its use in bio diesel production. , 2008 .

[83]  M. J. T. Reaney,et al.  Vegetable Oils as Biodiesel , 2005 .

[84]  A. Azeem,et al.  Biotechnological production of oil: Fatty acid composition of microbial oil , 1999, Plant foods for human nutrition.

[85]  Z. Cohen,et al.  Microbial and algal oils: Do they have a future for biodiesel or as commodity oils? , 2008 .

[86]  R. Przybylski,et al.  Flax Oil and High Linolenic Oils , 2005 .

[87]  Yung-Sheng Huang,et al.  In Vitro hydrolysis of fungal oils: Distribution of arachidonic acid-containing triacylglycerol molecular species , 1998 .

[88]  C. Sims,et al.  Flavor stability of high-oleic peanuts stored at low humidity , 1998 .

[89]  Lu Nan,et al.  Yellow nut-sedge (Cyperus esculentus L.) tuber oil as a fuel☆ , 1996 .

[90]  J. U. Obibuzor,et al.  Lipase-catalysed production of biodiesel fuel from some Nigerian lauric oils. , 2000, Biochemical Society transactions.

[91]  M. Hanna,et al.  Biodiesel : Current perspectives and future , 2005 .

[92]  Martin Mittelbach,et al.  Novel 12-deoxy-16-hydroxyphorbol diesters isolated from the seed oil of Jatropha curcas. , 2002, Journal of natural products.

[93]  H. Raheman,et al.  Diesel engine emissions and performance from blends of karanja methyl ester and diesel , 2004 .

[94]  Tracey Holloway,et al.  A global comparison of national biodiesel production potentials. , 2007, Environmental science & technology.

[95]  Evripidis Lois,et al.  Tobacco seed oil as an alternative diesel fuel: physical and chemical properties , 2002 .

[96]  Sevil Özgül-Yücel,et al.  FA monoalkylesters from rice bran oil by in situ esterification , 2003 .

[97]  M. P. Dorado,et al.  KINETIC PARAMETERS AFFECTING THE ALKALI-CATALYZED TRANSESTERIFICATION PROCESS OF USED OLIVE OIL , 2004 .

[98]  M. A. Simeh.  Comparative Advantage of the European Rapeseed Industry vis-à-vis Other Oils and Fats Producers , 2004 .

[99]  W. Prinyawiwatkul,et al.  FA composition of the oil extracted from farmed atlantic salmon (Salmo salar L.) viscera , 2006 .

[100]  M. Johansson,et al.  A study of the drying of linseed oils with different fatty acid patterns using RTIR-spectroscopy and chemiluminescence (CL) , 2005 .

[101]  Débora Oliveira,et al.  Optimization of enzymatic production of biodiesel from castor oil in organic solvent medium , 2004, Applied biochemistry and biotechnology.

[102]  C. Ratledge,et al.  The biochemistry and molecular biology of lipid accumulation in oleaginous microorganisms. , 2002, Advances in applied microbiology.

[103]  Lewis M. Brown,et al.  Genetic Engineering Approaches for Enhanced Production of Biodiesel Fuel from Microalgae , 1994 .

[104]  Mustafa Canakci,et al.  The potential of restaurant waste lipids as biodiesel feedstocks. , 2007, Bioresource technology.

[105]  Shweta Shah,et al.  Biodiesel Preparation by Lipase-Catalyzed Transesterification of Jatropha Oil , 2004 .

[106]  F. Gunstone.  Production and consumption of rapeseed oil on a global scale , 2001 .

[107]  J.T.P. Derksen,et al.  Seed oils rich in linolenic acid as renewable feedstock for environment-friendly crosslinkers in powder coatings , 1999 .

[108]  J. Gressel.  Transgenics are imperative for biofuel crops , 2008 .

[109]  A. M. Calderón de la Barca,et al.  Seasonal variation in the fatty acid composition and quality of sardine oil from sardinops sagax caeruleus of the gulf of California , 1999, Lipids.

[110]  C. Peterson,et al.  Potential Production of Biodiesel , 2005 .

[111]  M. G. Kulkarni,et al.  WASTE COOKING OIL – AN ECONOMICAL SOURCE FOR BIODIESEL: A REVIEW , 2006 .

[112]  C. Ratledge,et al.  Single cell oils--have they a biotechnological future? , 1993, Trends in biotechnology.

[113]  Michimasa Kishimoto,et al.  Oil production from algal cells of Dunaliella tertiolecta by direct thermochemical liquefaction , 1995 .

[114]  J. Fernández-martínez,et al.  Mutant Sunflowers with High Concentration of Saturated Fatty Acids in the Oil , 1995 .

[115]  Vittorio Rocco,et al.  Brassica carinata as an alternative oil crop for the production of biodiesel in Italy: agronomic evaluation, fuel production by transesterification and characterization , 2003 .

[116]  E. G. Perkins,et al.  Frying performance of low-linolenic acid soybean oil , 2000 .

[117]  Naveen Kumar,et al.  Jatropha curcus ─ A sustainable source for production of biodiesel , 2005 .

[118]  L. Canoira,et al.  Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow , 2000 .

[119]  A rapid and simple approach to identify different sunflower oil types by means of near-infrared reflectance spectroscopy , 1998 .

[120]  S. Meneghetti,et al.  Ethanolysis of castor and cottonseed oil: A systematic study using classical catalysts , 2006 .

[121]  A. Demirbas,et al.  Fatty and Resin Acids Recovered from Spruce Wood by Supercritical Acetone Extraction , 1991 .

[122]  J. V. Gerpen,et al.  BIODIESEL PRODUCTION FROM OILS AND FATS WITH HIGH FREE FATTY ACIDS , 2001 .

[123]  Adrian O'Connell,et al.  Camelina oil as a fuel for diesel transport engines , 2003 .

[124]  Simone Bastianoni,et al.  Biofuel potential production from the Orbetello lagoon macroalgae : A comparison with sunflower feedstock , 2008 .

[125]  E. Belarbi,et al.  A process for high yield and scaleable recovery of high purity eicosapentaenoic acid esters from microalgae and fish oil. , 2000, Enzyme and microbial technology.

[126]  J. Tsaknis,et al.  Characterization of Moringa oleifera seed oil variety Periyakulam 1 , 2002 .

[127]  S. Schönwiese,et al.  Alkali-catalyzed alcoholysis of crambe oil and camelina oil for the preparation of long-chain esters , 2000 .

[128]  J. Leahy,et al.  Winterisation of waste cooking oil methyl ester to improve cold temperature fuel properties , 2002 .

[129]  Ghassan Tashtoush,et al.  Utilization of ethyl ester of waste vegetable oils as fuel in diesel engines , 2002 .

[130]  M. J. Diamond,et al.  High-oleic safflower oil. Stability and chemical modification , 1967, Journal of the American Oil Chemists' Society.

[131]  G. Röbbelen,et al.  Impact of low linolenic acid content on seed yield of winter oilseed rape (Brassica napus L.) , 1996 .

[132]  D. Taylor,et al.  Inheritance of elevated palmitic acid in flax and its relationship to the low linolenic acid , 1995 .

[133]  V. Knauf,et al.  Modification of Brassica seed oil by antisense expression of a stearoyl-acyl carrier protein desaturase gene. , 1992, Proceedings of the National Academy of Sciences of the United States of America.

[134]  W. Friedt,et al.  RECENT DEVELOPMENTS AND PERSPECTIVES OF INDUSTRIAL RAPESEED BREEDING , 1998 .

[135]  A. J. Yuste,et al.  A Neural Network Approach to Simulate Biodiesel Production from Waste Olive Oil , 2006 .

[136]  A. Saydut,et al.  Transesterified sesame (Sesamum indicum L.) seed oil as a biodiesel fuel. , 2008, Bioresource technology.

[137]  A. Green.  A MUTANT GENOTYPE OF FLAX (Linum usitatissimum L.) CONTAINING VERY LOW LEVELS OF LINOLENIC ACID IN ITS SEED OIL , 1986 .

[138]  T. Lebeau,et al.  Diatom cultivation and biotechnologically relevant products. Part II: Current and putative products , 2003, Applied Microbiology and Biotechnology.

[139]  Peter Tritthart,et al.  Diesel fuel derived from vegetable oils, III. Emission tests using methyl esters of used frying oil , 1988 .

[140]  M. Droop.  Heterotrophy of carbon , 1974 .

[141]  Alfred R. Braun.  Re-use and fixation of CO2 in chemistry, algal biomass and fuel substitutions in the traffic sector , 1996 .

[142]  P. Spolaore,et al.  Commercial applications of microalgae. , 2006, Journal of bioscience and bioengineering.

[143]  W. Prinyawiwatkul,et al.  Oil production from catfish viscera , 2003 .

[144]  N. Dale,et al.  Camelina sativa, A Montana Omega-3 and Fuel Crop * , 2007 .

[145]  M. Espe,et al.  Chemical composition and theoretical nutritional evaluation of the produced fractions from enzymic hydrolysis of salmon frames with Protamex , 2003 .

[146]  H. Aksoy,et al.  Evaluation of Turkish sulphur olive oil as an alternative diesel fuel , 1988 .

[147]  W. Friedt,et al.  Development of linseed for industrial purposes via pedigree-selection and haploid-technique , 1998 .

[148]  Eric E. Jarvis,et al.  Manipulation of microalgal lipid production using genetic engineering , 1996 .

[149]  A. H. Zakri,et al.  Assessment of Genetic Diversity in Oil Palm (Elaeis guineensis Jacq.) using Restriction Fragment Length Polymorphism (RFLP) , 2006, Genetic Resources and Crop Evolution.

[150]  A. Darus,et al.  Improvement of palm oil through breeding and biotechnology , 1997 .

[151]  C. Ratledge,et al.  Oils from Microorganisms , 2005, Bailey's Industrial Oil and Fat Products.

[152]  L. Kleingartner.  NuSun Sunflower Oil: Redirection of an Industry , 2002 .

[153]  R. Howard-Hildige,et al.  The effect of steam treating waste cooking oil on the yield of methyl ester , 2002 .

[154]  D. Taylor,et al.  Improving Erucic Acid Content in Rapeseed through Biotechnology: What Can the Arabidopsis FAE1 and the Yeast SLC1‐1 Genes Contribute?1,2 , 2001 .

[155]  L. C. Meher,et al.  Methanolysis of Pongamia pinnata (karanja) oil for production of biodiesel , 2004 .

[156]  A. Green,et al.  Isolation of induced mutants in linseed (Linum usitatissimum) having reduced linolenic acid content , 1984, Euphytica.

[157]  E. Heinz,et al.  Spatial and temporal regulation of three different microsomal oleate desaturase genes (FAD2) from normal-type and high-oleic varieties of sunflower (Helianthus annuus L.) , 2001, Molecular Breeding.

[158]  A. Kinney,et al.  Reducing Polyunsaturation in Oils of Transgenic Canola and Soybean , 1995 .

[159]  Yuan-Kun Lee,et al.  Commercial production of microalgae in the Asia-Pacific rim , 1997, Journal of Applied Phycology.

[160]  A. S. Ramadhas,et al.  Biodiesel production from high FFA rubber seed oil , 2005 .

[161]  X. Miao,et al.  High quality biodiesel production from a microalga Chlorella protothecoides by heterotrophic growth in fermenters. , 2006, Journal of biotechnology.

[162]  M. P. Dorado,et al.  AN ALKALI–CATALYZED TRANSESTERIFICATION PROCESS FOR HIGH FREE FATTY ACID WASTE OILS , 2002 .

[163]  Ki-Teak Lee,et al.  Production of alkyl ester as biodiesel from fractionated lard and restaurant grease , 2002 .

[164]  Y. Dote,et al.  CO2 fixation and oil production through microalga , 1995 .

[165]  Pedro Felizardo,et al.  Production of biodiesel from waste frying oils. , 2006, Waste management.

[166]  A. Tomašević,et al.  Methanolysis of used frying oil , 2003 .

[167]  H. A. Aksoy,et al.  Methyl ester from safflower seed oil of Turkish origin as a biofuel for diesel engines , 1994 .

[168]  Satya Narayan Naik,et al.  Conversion of Non-edible Oil into Biodiesel , 2003 .