High-quality bulk a-plane GaN sliced from boules in comparison to heteroepitaxially grown thick films on r-plane sapphire

Thick GaN bars with [1120] orientation have been sliced from GaN boules grown on freestanding films by hydride vapor phase epitaxy (HVPE) in the [0001] direction. High-resolution x-ray diffraction and transmission electron microscopy have been used to study the structural quality and defect distribution in the material in comparison to heteroepitaxially grown thick HVPE-GaN films grown in the [1120] direction on (1102)-plane sapphire. It is demonstrated that while the heteroepitaxial material possesses a high density of stacking faults and partial dislocations, leading to anisotropic structural characteristics, the (1120)-plane bulk GaN, sliced from boules, exhibits low dislocation density and narrow rocking curves with isotropic in-plane character.

[1]  U. Pietsch X-ray Scattering from Semiconductors, 2nd Edition, By Paul F. Fewster. Pp. 299. London: Imperial College Press. Price 56 GBP. ISBN 1-86094-360-8. , 2005 .

[2]  D. K. Bowen,et al.  High Resolution X-Ray Diffractometry And Topography , 1998 .

[3]  Robert F. Davis,et al.  Structural TEM study of nonpolar a-plane gallium nitride grown on (112_0) 4H-SiC by organometallic vapor phase epitaxy , 2005 .

[4]  Zheng Gong,et al.  Anisotropic structural characteristics of (112̄0) GaN templates and coalesced epitaxial lateral overgrown films deposited on (101̄2) sapphire , 2004 .

[5]  N. Andrew,et al.  Interpretation of the diffraction profile resulting from strain relaxation in epilayers , 1995 .

[6]  James S. Speck,et al.  Structural and morphological characteristics of planar (112̄0) a-plane gallium nitride grown by hydride vapor phase epitaxy , 2003 .

[7]  R. Köhler,et al.  X-ray diffraction peaks due to misfit dislocations in heteroepitaxial structures , 1997 .

[8]  James S. Speck,et al.  Characterization of Planar Semipolar Gallium Nitride Films on Spinel Substrates , 2005 .

[9]  Detlef Hommel,et al.  Emission properties of a-plane GaN grown by metal-organic chemical-vapor deposition , 2005 .

[10]  P. Fewster EQUIPMENT FOR MEASURING DIFFRACTION PATTERNS , 2000 .

[11]  B. Arnaudov,et al.  Properties of nonpolar a-plane GaN films grown by HVPE with AlN buffers , 2005 .

[12]  James S. Speck,et al.  Polarity determination of a-plane GaN on r-plane sapphire and its effects on lateral overgrowth and heteroepitaxy , 2003 .

[13]  J. Harris,et al.  Optically controlled electroabsorption modulators for unconstrained wavelength conversion , 2004 .

[14]  James S. Speck,et al.  Defect reduction in (112̄0) a-plane gallium nitride via lateral epitaxial overgrowth by hydride vapor-phase epitaxy , 2003 .

[15]  Paul F. Fewster,et al.  X Ray Scattering From Semiconductors , 2000 .