Bis{N-[5-(4-methoxyphenyl)-1,3,4-oxadiazol-2-yl]ethanimidamidato}copper(II)

The title compound, [Cu(C11H11N4O2)2], was prepared by solvothermal synthesis using 2-amino-5-(4-methoxyphenyl)-1,3,4-oxadiazole and copper sulfate pentahydrate in an acetonitrile solution. The CuII atom lies on an inversion center and is four-coordinated in a slightly distorted square-planar geometry by four N atoms of the ligands obtained from the formation of a bond between the amine N atom of the oxadiazole molecule and the nitrile C atom of the solvent. In the crystal structure an intermolecular N—H⋯N hydrogen bond links inversion-related molecules.

[1]  Bang-Hong Cai,et al.  Bis[4-bromo-2-(cyclopentyliminomethyl)phenolato]copper(II) , 2009, Acta crystallographica. Section E, Structure reports online.

[2]  M. Zareef,et al.  Ethyl 2-(5-phenyl-1,3,4-oxadiazol-2-ylsulfanyl)acetate , 2008, Acta crystallographica. Section E, Structure reports online.

[3]  A. Kadi,et al.  Synthesis, antimicrobial, and anti-inflammatory activities of novel 2-(1-adamantyl)-5-substituted-1,3,4-oxadiazoles and 2-(1-adamantylamino)-5-substituted-1,3,4-thiadiazoles. , 2007, European journal of medicinal chemistry.

[4]  M. Zareef,et al.  Synthesis, Anti–HIV, and Antifungal Activity of New Benzensulfonamides Bearing the 2,5-Disubstituted-1,3,4-Oxadiazole Moiety , 2007 .

[5]  C. Supuran,et al.  Carbonic anhydrase inhibitors. Inhibition of human tumor-associated isozymes IX and cytosolic isozymes I and II with some 1,3,4-oxadiazole-thiols , 2006, Journal of enzyme inhibition and medicinal chemistry.

[6]  X. Qian,et al.  Syntheses and insecticidal activity of new 2-(5-(trifluoromethyl)pyridyloxymethyl)-1,3,4-oxadiazoles , 2002 .

[7]  Jack Y. Lu,et al.  A Novel Nanostructured Open-Channel Coordination Polymer with an Included Fused-Polyiodide Ring , 2002 .

[8]  Louis J. Farrugia,et al.  WinGX suite for small-molecule single-crystal crystallography , 1999 .

[9]  Maria Cristina Burla,et al.  EXPO: a program for full powder pattern decomposition and crystal structure solution , 1999 .

[10]  Louis J. Farrugia,et al.  ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[11]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.