Multivariate analysis of the spatial patterns of 8 trace elements using the French soil monitoring network data.

Geostatistical and spatially constrained multivariate analysis methods (MULTISPATI-PCA) have been applied at the scale of France to differentiate the influence of natural background from the pollution due to human activities on the content of 8 trace elements in the topsoil. The results of MULTISPATI-PCA evidence strong spatial structures attributed to different natural and artificial processes. The first axis can be interpreted as an axis of global richness in trace elements. Axis 2 reflects geochemical anomalies in Tl and Pb. Axis 3 exhibits on one hand natural pedogeogenic anomalies and on the other hand, it shows high values attributable to anthropogenic contamination. Finally, axis 4 is driven by anthropogenic copper contamination. At the French territory scale, we show that the main factors controlling trace elements distribution in the topsoil are soil texture, variations in parent material geology and weathering, and various anthropogenic sources.

[1]  R. Webster,et al.  Coregionalization of trace metals in the soil in the Swiss Jura , 1994 .

[2]  A. Facchinelli,et al.  Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. , 2001, Environmental pollution.

[3]  J. Halamić Geochemical Atlas of Europe , 2006 .

[4]  D. Arrouays,et al.  Geostatistical assessment of Pb in soil around Paris, France. , 2006, The Science of the total environment.

[5]  Olle Selinus,et al.  Discrimination between natural background and anthropogenic pollution in environmental geochemistry — exemplified in an area of south-eastern Sweden , 1999 .

[6]  R. Reese Geostatistics for Environmental Scientists , 2001 .

[7]  Dominique King,et al.  Scale of spatial dependence between chemical properties of topsoil and subsoil over a geologically contrasted area (Massif central, France) , 2003 .

[8]  Dominique Arrouays,et al.  The carbon content of topsoil and its geographical distribution in France , 2001 .

[9]  D. Cox,et al.  An Analysis of Transformations , 1964 .

[10]  M. L. Pignata,et al.  Identification of atmospheric trace-element sources by passive biomonitoring employing PCA and variogram analysis , 2008 .

[11]  T. Sterckeman,et al.  Of the necessity of knowledge of the natural pedo-geochemical background content in the evaluation of the contamination of soils by trace elements. , 2001, The Science of the total environment.

[12]  T. Sterckeman,et al.  Trace element distributions in soils developed in loess deposits from northern France , 2006 .

[13]  Daniel Wartenberg,et al.  Multivariate Spatial Correlation: A Method for Exploratory Geographical Analysis , 2010 .

[14]  B. Minasny,et al.  The Matérn function as a general model for soil variograms , 2005 .

[15]  W. Shi,et al.  Metal contamination in urban, suburban, and country park soils of Hong Kong: a study based on GIS and multivariate statistics. , 2006, The Science of the total environment.

[16]  R. M. Lark,et al.  Modelling complex soil properties as contaminated regionalized variables , 2002 .

[17]  M. Bidovec,et al.  Geochemical Atlas of Europe, Part 1, Background Information, Methodology and Maps , 2005 .

[18]  Jean Thioulouse,et al.  The ade4 package - I : One-table methods , 2004 .

[19]  N. Basta,et al.  Path analysis of heavy metal adsorption by soil , 1993 .

[20]  A. Journel,et al.  Geostatistics for natural resources characterization , 1984 .

[21]  S. McGrath,et al.  Estimates of ambient background concentrations of trace metals in soils for risk assessment. , 2007, Environmental pollution.

[22]  Stéphane Dray,et al.  Spatial ordination of vegetation data using a generalization of Wartenberg's multivariate spatial correlation , 2008 .

[23]  R. Jones,et al.  Soil monitoring in Europe: a review of existing systems and requirements for harmonisation. , 2008, The Science of the total environment.

[24]  I. Thornton,et al.  Application of factorial kriging analysis to the FOREGS European topsoil geochemistry database. , 2008, The Science of the total environment.

[25]  Chaosheng Zhang,et al.  Geostatistical analyses and hazard assessment on soil lead in Silvermines area, Ireland. , 2004, Environmental pollution.

[26]  R. M. Lark,et al.  A comparison of some robust estimators of the variogram for use in soil survey , 2000 .

[27]  Peter A. Dowd,et al.  The Variogram and Kriging: Robust and Resistant Estimators , 1984 .

[28]  Jean Thioulouse,et al.  CO‐INERTIA ANALYSIS AND THE LINKING OF ECOLOGICAL DATA TABLES , 2003 .

[29]  A. Johnston,et al.  Isotopic Character of Lead Deposited from the Atmosphere at a Grassland Site in the United Kingdom Since 1860 , 1996 .

[30]  D. Arrouays,et al.  A new projection in France: a multi-institutional soil quality monitoring network , 2002 .

[31]  M. Mench,et al.  Thallium in French agrosystems--I. Thallium contents in arable soils. , 1997, Environmental pollution.

[32]  R. Webster,et al.  Geostatistical analysis of soil contamination in the Swiss Jura. , 1994, Environmental pollution.

[33]  I. Thornton,et al.  LEAD POLLUTION IN AGRICULTURAL SOILS , 1978 .

[34]  Y. Erel,et al.  Tracing the transport of anthropogenic lead in the atmosphere and in soils using isotopic ratios , 1997 .

[35]  J. Thioulouse,et al.  The ade 4 package-I : One-table methods by , 2004 .

[36]  P. Goovaerts Factorial kriging analysis: a useful tool for exploring the structure of multivariate spatial soil information , 1992 .

[37]  R. Lark,et al.  Geostatistics for Environmental Scientists , 2001 .

[38]  T. R. Lister,et al.  The influence of parent material on topsoil geochemistry in eastern England , 2003 .

[39]  Stefano Bocchi,et al.  Application of factorial kriging for mapping soil variation at field scale. , 2000 .

[40]  A. Korre Statistical and spatial assessment of soil heavy metal contamination in areas of poorly recorded, complex sources of pollution , 1999 .

[41]  P. D. Reffye,et al.  La théorie des variables régionalisées, ses applications possibles dans le domaine épidémiologique aux recherches agronomiques en particulier sur le palmier à huile et le cocotier , 1986 .

[42]  Jean Thioulouse,et al.  Multivariate analysis of spatial patterns: a unified approach to local and global structures , 1995, Environmental and Ecological Statistics.