Transformations of functional groups attached to cyclopentadienyl or related ligands in group 4 metal complexes

[1]  A. Zukal,et al.  Homogeneous and heterogeneous cyclopentadienyl-arene titanium catalysts for selective ethylene trimerization to 1-hexene , 2015 .

[2]  D. Stephan,et al.  1,1-Olefin-bridged bis-(2-indenyl) metallocenes of titanium and zirconium. , 2014, Dalton transactions.

[3]  T. Marks,et al.  Very large cooperative effects in heterobimetallic titanium-chromium catalysts for ethylene polymerization/copolymerization. , 2014, Journal of the American Chemical Society.

[4]  P. Chirik,et al.  Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification. , 2014, Angewandte Chemie.

[5]  M. Alexandru,et al.  Siloxane-bridged [n]troticenophanes: Syntheses, structures and ring-opening reactions , 2014 .

[6]  J. Sýkora,et al.  Reactivity of a Titanocene Pendant Si–H Group toward Alcohols. Unexpected Formation of Siloxanes from the Reaction of Hydrosilanes and Ph3COH Catalyzed by B(C6F5)3 , 2013 .

[7]  T. Marks,et al.  Synthesis, characterization, and heterobimetallic cooperation in a titanium-chromium catalyst for highly branched polyethylenes. , 2013, Journal of the American Chemical Society.

[8]  I. Císařová,et al.  Synthetic transformations of a pendant nitrile moiety in group 4 metallocene complexes. , 2013, Dalton transactions.

[9]  S. Losio,et al.  New tethered ansa-bridged zirconium catalysts: Insights into the “self-immobilization” mechanism , 2013 .

[10]  C. Daniliuc,et al.  Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C–P and C–Si Bridges , 2012 .

[11]  J. Khinast,et al.  Tethered ansa-bridged titanium complexes immobilized on 3-mercaptopropyl-functionalized silica gel and their application for the hydrosilylation of imines. , 2012, Dalton transactions.

[12]  J. Sýkora,et al.  Carbosilane Metallodendrimers with Titanocene Dichloride End Groups , 2012 .

[13]  C. Redshaw,et al.  Tridentate ligands and beyond in group IV metal α-olefin homo-/co-polymerization catalysis. , 2012, Chemical Society reviews.

[14]  C. Daniliuc,et al.  Synthesis, Reactivity and Ring‐Opening Polymerization of a Tin‐Bridged ansa‐Cycloheptatrienyl‐Cyclopentadienyl Titanium Sandwich Complex , 2012 .

[15]  J. Friedrich,et al.  Radical 4-exo cyclizations via template catalysis. , 2012, Chemistry.

[16]  C. Daniliuc,et al.  Preparation and characterization of Cp-functionalized cycloheptatrienyl–cyclopentadienyl titanium sandwich complexes (troticenes) , 2012 .

[17]  Brian C. Peoples,et al.  Synthesis and Structure of Bifunctional Zirconocene/Borane Complexes and Their Activation for Ethylene Polymerization , 2011 .

[18]  N. Metzler‐Nolte,et al.  Towards peptide-substituted titanocene anticancer drugs , 2011 .

[19]  M. Horáček,et al.  Intramolecular activation of pendant alkenyl group as a tool for modification of the zirconocene framework , 2011 .

[20]  M. Horáček,et al.  Group 4 metallocene complexes with pendant nitrile groups , 2011 .

[21]  M. Horáček,et al.  Ethene Elimination during Thermolysis of Bis(3-butenyltetramethylcyclopentadienyl)dimethyltitanium , 2011 .

[22]  D. Stephan,et al.  Titanium "constrained geometry" complexes with pendant arene groups. , 2011, Dalton transactions.

[23]  I. Císařová,et al.  Dehydrocoupling of SiMe2H substituents in permethylated zirconocene complexes , 2011 .

[24]  G. Erker Bio-Organometallic Chemistry, ansa-Metallocenes, and Frustrated Lewis Pairs: Functional Group Chemistry at the Group 4 Bent Metallocenes , 2011 .

[25]  H. Cramail,et al.  Polymer support of “single-site” catalysts for heterogeneous olefin polymerization , 2011 .

[26]  J. Quail,et al.  ansa-Zirconocenes with Aluminum or Gallium in Bridging Positions , 2010 .

[27]  T. Kupfer,et al.  Synthesis and reactivity of boron-, silicon-, and tin-bridged ansa-cyclopentadienyl-cycloheptatrienyl titanium complexes (troticenophanes). , 2010, Chemistry.

[28]  R. Fröhlich,et al.  Exploring the limits of frustrated Lewis pair chemistry with alkynes: detection of a system that favors 1,1-carboboration over cooperative 1,2-P/B-addition. , 2010, Chemistry, an Asian journal.

[29]  M. Bochmann The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts† , 2010 .

[30]  G. Schnakenburg,et al.  Synthesis of Stable Functional Titanocene Enolates , 2010 .

[31]  G. Erker,et al.  Dynamic Topochemical Reaction Control−A Principle and Its Application in ansa-Metallocene Synthesis† , 2010 .

[32]  E. Chen,et al.  Silylium–metallocenium dications derived from hydrosilyl-bridged metallocenes and roles in polymerization of polar and nonpolar vinyl monomers , 2010 .

[33]  J. Matta,et al.  Synthesis and cytotoxicity studies of steroid-functionalized titanocenes as potential anticancer drugs: sex steroids as potential vectors for titanocenes , 2010, JBIC Journal of Biological Inorganic Chemistry.

[34]  M. Cokoja,et al.  η5,η1-Coordinated cyclopentadienyl transition metal complexes featuring σ-metal-carbon ansa bridges , 2010 .

[35]  Tülay Aslı Tumay,et al.  Metal-Free Frustrated Lewis Pair Catalyzed 1,4-Hydrogenation of Conjugated Metallocene Dienamines , 2010 .

[36]  G. Erker,et al.  Functional Group Chemistry at the Group 4 Bent Metallocene Framework: [2+2] Cycloaddition of the Parent Bis(vinyl-Cp/vinyl-Ind)ZrCl2 Systems , 2010 .

[37]  A. Rheingold,et al.  Synthesis, Structure and Biological Activity of Amide-Functionalized Titanocenyls: Improving their Cytotoxic Properties. , 2009, Journal of organometallic chemistry.

[38]  G. Schnakenburg,et al.  4-exo cyclizations by template catalysis. , 2009, Angewandte Chemie.

[39]  C. Daniliuc,et al.  Selective lithiation and phosphane-functionalization of [(eta(7)-C7H7)Ti(eta(5)-C5H5)] (troticene) and its use for the preparation of early-late heterobimetallic complexes. , 2009, Journal of the American Chemical Society.

[40]  W. Kaminsky,et al.  New application for metallocene catalysts in olefin polymerization. , 2009, Dalton transactions.

[41]  Tülay Aslı Tumay,et al.  Ring-closing metathesis of sterically congested functionalized zirconocenes-ethene polymerization catalysts derived from related bridged and open metallocenes. , 2009, Dalton Transactions.

[42]  V. Busico Metal-catalysed olefin polymerisation into the new millennium: a perspective outlook. , 2009, Dalton transactions.

[43]  D. P. Krut’ko Zirconium and titanium complexes with side-chain functionalized cyclopentadienyl ligands , 2009 .

[44]  G. Erker,et al.  Facile cyclometalation reactions of Cp-zirconium complexes with weakly Lewis acidic pendent boron functionalities. , 2009, Chemistry.

[45]  R. Fröhlich,et al.  Functional Group Chemistry at the Group 4 Bent Metallocene Frameworks: Formation and “Metal-Free” Catalytic Hydrogenation of Bis(imino-Cp)zirconium Complexes , 2009 .

[46]  Tülay Aslı Tumay,et al.  Synthesis of an Amino-Functionalized ansa-Zirconocene by Intramolecular Photochemical Enamine [2+2]Cycloaddition , 2009 .

[47]  A. N. Ryabov,et al.  Palladium-Catalyzed Cross-Coupling Reactions of Bromo-Substituted Group 4 Metallocenes , 2009 .

[48]  I. Besu,et al.  Anticancer drugs based on alkenyl and boryl substituted titanocene complexes , 2009 .

[49]  A. Otero,et al.  New alkenyl-substituted group 4 C-ansa-metallocene complexes. Reactivity of the substituent at the carbon ansa bridge , 2009 .

[50]  R. Fröhlich,et al.  Catalytic hydrogenation of sensitive organometallic compounds by antagonistic N/B Lewis pair catalyst systems. , 2009, Journal of the American Chemical Society.

[51]  Cristian G. Hrib,et al.  Secondary interactions in phosphane-functionalized group 4 cycloheptatrienyl-cyclopentadienyl sandwich complexes. , 2009, Chemistry.

[52]  M. C. Feiters,et al.  Novel Organometallic Gelators with Enhanced Amphiphilic Character: Structure-Property Correlations, Principles for Design, and Diversity of Gelation , 2009 .

[53]  Martin Nieger,et al.  Modular Synthesis of Functional Titanocenes , 2008 .

[54]  H. Alt,et al.  Dinuclear metallocene complexes as catalyst precursors for homogeneous ethylene polymerization , 2008 .

[55]  M. C. Sacchi,et al.  Self‐Immobilizing Precatalysts: Norbornene‐Bridged Zirconium ansa‐Metallocenes , 2008 .

[56]  M. Tamm Synthesis and reactivity of functionalized cycloheptatrienyl-cyclopentadienyl sandwich complexes. , 2008, Chemical communications.

[57]  D. Franke,et al.  Carbonyl-substituted titanocenes: a novel class of cytostatic compounds with high antitumor and antileukemic activity. , 2008, Chemistry.

[58]  M. Horáček,et al.  Reactivity of SiMe2H Substituents in Permethylated Titanocene Complexes: Dehydrocoupling and Ethene Hydrosilylation , 2008 .

[59]  O. Castaño,et al.  Olefin isomerisation versus hydrozirconation: a case of a stable beta-hydrogen-containing Zr-alkyl derivative. , 2008, Dalton transactions.

[60]  P. Chirik,et al.  Indenyl zirconium dinitrogen chemistry: N2 coordination to an isolated zirconium sandwich and synthesis of side-on, end-on dinitrogen compounds. , 2008, Journal of the American Chemical Society.

[61]  J. C. Chadwick,et al.  Tailor-Made Polymers , 2008 .

[62]  R. Fröhlich,et al.  Functionalized Alkali Metal Cyclopentadienides: Structural and Chemical Features† , 2008 .

[63]  G. Erker,et al.  Functional Group Chemistry at the Zirconocene Backbone: Addition Reactions to Pendant Alkynyl Substituents , 2008 .

[64]  A. Otero,et al.  Heterocycle-Substituted Indenes as Precursors for Supported Zirconocene Catalysts , 2008 .

[65]  J. Hartley,et al.  Functionalised cyclopentadienyl titanium compounds as potential anticancer drugs. , 2007, Dalton transactions.

[66]  A. Otero,et al.  Synthesis and Reactivity of Alkenyl‐Substituted Zirconocene Complexes and Their Application as Olefin Polymerisation Catalysts , 2007 .

[67]  P. Chirik,et al.  Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N(2) complexes. , 2007, Chemical communications.

[68]  S. Cole,et al.  A new series of titanocene dichloride derivatives bearing cyclic alkylammonium groups: Assessment of their cytotoxic properties , 2007 .

[69]  M. C. Feiters,et al.  A tailored organometallic gelator with enhanced amphiphilic character and structural diversity of gelation. , 2007, Chemical communications.

[70]  M. Lanfranchi,et al.  [(Allylsilyl)(η-amidosilyl)-η5-cyclopentadienyl] Group 4 Metal Complexes: Synthesis, Reactivity, and Olefin Polymerization , 2007 .

[71]  M. Tamm,et al.  Synthesis and Reactivity of Silicon- and Germanium-Bridged ansa-Cycloheptatrienyl−Cyclopentadienyl Titanium Complexes , 2007 .

[72]  R. Fröhlich,et al.  Formation of an organometallic ladderane derivative by dynamic topochemical reaction control. , 2006, Angewandte Chemie.

[73]  H. Braunschweig,et al.  Constrained geometry complexes—Synthesis and applications , 2006 .

[74]  R. Fröhlich,et al.  Ansa-metallocene polymerization catalysts derived from [2+2]cycloaddition reactions of bis(1-methylethenyl-cyclopentadienyl)zirconium systems , 2006, Proceedings of the National Academy of Sciences.

[75]  K. Osakada,et al.  Early-late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene. , 2006, Chemical communications.

[76]  G. Erker,et al.  [2+2]-Cycloaddition and subsequent meso/rac ansa-metallocene interconversion by photolysis of a bis(1,3-dialkenylcyclopentadienyl)zirconium complex , 2006 .

[77]  Jun Zhang,et al.  Self-immobilized and polymerized miscellaneous metallocene catalysts for ethylene polymerization , 2006 .

[78]  W. Kaminsky,et al.  Nanocomposites by In Situ Polymerization of Olefins with Metallocene Catalysts , 2006 .

[79]  G. Erker Syntheses and reactions of fulvene-derived substituted aminoalkyl-Cp and phosphinoalkyl-Cp-Group 4 metal complexes , 2006 .

[80]  P. Chirik,et al.  Synthesis of bis(indenyl)zirconium dihydrides and subsequent rearrangement to eta5,eta3-4,5-dihydroindenediyl ligands: evidence for intermediates during the hydrogenation to tetrahydroindenyl derivatives. , 2006, Journal of the American Chemical Society.

[81]  J. Benet‐Buchholz,et al.  Donor-acceptor metallocene catalysts for the production of UHMW-PE: pushing the selectivity for chain growth to its limits. , 2006, Angewandte Chemie.

[82]  G. Erker Ansa‐Metallocenes by Intramolecular Ring Closure Reactions – Syntheses and Applications , 2006 .

[83]  Jun Zhang,et al.  Polymerized metallocene catalysts and late transition metal catalysts for ethylene polymerization , 2006 .

[84]  A. Otero,et al.  Insights into group 4 and 5 ansa-bis(cyclopentadienyl) complexes with a single-atom bridge , 2006 .

[85]  H. Alt,et al.  Metallacyclic metallocene complexes as catalysts for olefin polymerization , 2006 .

[86]  H. Alt Metallocene complexes as catalysts for olefin polymerization , 2006 .

[87]  G. Erker,et al.  Group 4 bent metallocenes and functional groups—Finding convenient pathways in a difficult terrain , 2006 .

[88]  Baiquan Wang Ansa-metallocene polymerization catalysts: Effects of the bridges on the catalytic activities , 2006 .

[89]  H. Müller‐Bunz,et al.  Novel benzyl substituted titanocene anti-cancer drugs , 2005 .

[90]  H. Alt Self-immobilizing catalysts and cocatalysts for olefin polymerization. , 2005, Dalton transactions.

[91]  P. Royo,et al.  Allyldimethylsilylcyclopentadienyl Hafnium Complexes: Formation and Trapping of Hafnocenium Cations , 2005 .

[92]  A. Otero,et al.  Synthesis, hydrosilylation reactivity and catalytic properties of group 4 ansa-metallocene complexes , 2005 .

[93]  G. Erker Building bridges: ansa-Metallocene construction by carbon–carbon coupling reactions at preformed Group 4 bent metallocene frameworks , 2005 .

[94]  M. Nieger,et al.  A modular and efficient synthesis of functional titanocenes. , 2005, Journal of the American Chemical Society.

[95]  Laurianne Bareille,et al.  Towards a Library of “Early‐Late” Ti–Ru Bimetallic Complexes , 2005 .

[96]  K. Osakada,et al.  Zr/Zr and Zr/Fe dinuclear complexes with flexible bridging ligands. preparation by olefin metathesis reaction of the mononuclear precursors and properties as polymerization catalysts , 2005 .

[97]  Marta E. G. Mosquera,et al.  Insertion Reactions into the Metal‒Alkyl and Metal‒Amido Bonds of 1,3-Di(silyl-η-amido)cyclopentadienyl Titanium and Zirconium Complexes , 2005 .

[98]  Reko Leino,et al.  Chiral Indenes and Group-4 Metallocene Dichlorides Containing α- and β-Pinenyl-Derived Ligand Substituents: Synthesis and Catalytic Applications in Polymerization and Carboalumination Reactions , 2005 .

[99]  M. Tamm,et al.  Regioselective Si-C bond activation in silicon-bridged ansa-cycloheptatrienyl-cyclopentadienyl complexes. , 2005, Chemical communications.

[100]  P. Richard,et al.  Ruthenium titanocene and ruthenium titanium half-sandwich bimetallic complexes in catalytic cyclopropanation , 2005 .

[101]  K. Osakada,et al.  Synthesis and properties of Zr–Co heterodinuclear complexes with a bridging bis(cyclopentadienyl) ligand , 2005 .

[102]  G. Erker,et al.  Bis(enamino-Cp) Group 4 metal complex chemistry: developing a Mannich-type carbon-carbon coupling reaction at the bent metallocene famework , 2005 .

[103]  G. Erker,et al.  Chemistry of Metal-Metal-Bonded Early-Late Heterobimetallics: Cooperative Reactions of Functional Groups at a Persistent Organometallic Zr-Rh Framework , 2005 .

[104]  A. Churakov,et al.  2-Phosphinothioyl- and 2-phosphinoylethylcyclopentadienyl zirconium and titanium complexes. Crystal structure of [η5:η1-C5H4CH2CH2P(O)Ph2]TiCl3 , 2005 .

[105]  G. Erker,et al.  Formation and reactions of metal-metal bonded heterobimetallic (C5H4PR2)-bridged (Zr-Ir) and (Zr-Rh) complexes: evidence for the participation of metal hydride intermediates. , 2004, Dalton transactions.

[106]  H. Nakazawa,et al.  Ethylene polymerization and ethylene/styrene copolymerization with secondary phosphine-pendant and phosphide-pendant complexes of Zr and Hf , 2004 .

[107]  Taku Kato,et al.  Photochemical Intramolecular [2+2] Cycloaddition of Bridged Bis-azulenyl Zirconocenes , 2004 .

[108]  C. J. Elsevier,et al.  Ansa-cycloheptatrienyl-cyclopentadienyl complexes. , 2004, Angewandte Chemie.

[109]  M. Horáček,et al.  Synthesis and structure of bis{η5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-κS)cyclopentadienyl}titanium(IV) , 2004 .

[110]  T. Marks,et al.  Covalently Linked Heterobimetallic Catalysts for Olefin Polymerization , 2004 .

[111]  S. Cole,et al.  Synthesis, Characterization, and Assessment of Cytotoxic Properties of a Series of Titanocene Dichloride Derivatives , 2004 .

[112]  G. Erker,et al.  Exploring CH-activation pathways in bifunctional zirconocene/borane systems. , 2004, Journal of the American Chemical Society.

[113]  B. Twamley,et al.  Zwitterionic Phosphorus Ylide Adducts of Boron‐Bridged ansa‐Zirconocene Complexes as Precatalysts for Olefin Polymerization , 2004 .

[114]  A. Lehtonen,et al.  Heteroatom‐Substituted Group 4 Bis(indenyl)metallocenes , 2004 .

[115]  E. Herdtweck,et al.  Studies Related to the Chloro Titanium and Zirconium Complexes with [η5‐Cyclopentadienyldi(silylamido)] Ligands , 2004 .

[116]  D. O′Hare,et al.  Mesoporous silica-supported zirconocene catalysts for highly isotactic polypropylene. , 2004, Chemical communications.

[117]  A. Otero,et al.  Hydrosilylation in the Design and Functionalization of ansa-Metallocene Complexes , 2004 .

[118]  G. Erker,et al.  Metallocene carbene chemistry , 2004 .

[119]  G. Erker,et al.  Developing Some Functional Group Chemistry at the Group 4 Bent Metallocene Frameworks , 2004 .

[120]  R. Fröhlich,et al.  Formation of a bifunctional zirconocene complex that favours intramolecular -B(C6F5)2 addition to a Cp ring over sigma-ligand abstraction. , 2004, Chemical communications.

[121]  G. Erker,et al.  Formation of a unique ansa-metallocene framework by intramolecular photochemical [2+2] cycloaddition of bis(2-alkenylindenyl)zirconium complexes. , 2004, Angewandte Chemie.

[122]  P. McGowan,et al.  Functionalized Cyclopentadienyl Titanium Organometallic Compounds as New Antitumor Drugs , 2004 .

[123]  H. Alt,et al.  Umsetzungen von ω-alkenylsubstituierten Zirconocendichloridkomplexen mit n-Alkyllithiumverbindungen in Gegenwart von Alkenen bzw. Alkinen , 2003 .

[124]  A. Otero,et al.  Group 4 metallocene complexes incorporating vinyl or allyl substituted ansa ligands. X-Ray crystal structures of [Zr{Me(CH2CH)Si(η5-C5Me4)2}Cl2], [Zr{Me(CH2CHCH2)Si(η5-C5H4)2}Cl2] and [Zr{Me(CH2CHCH2)Si(η5-C5Me4)(η5-C5H4)}Cl2] , 2003 .

[125]  E. Herdtweck,et al.  Hydro- and chloro-substituted silyl- and silyl-η1-amido-η5-tetramethylcyclopentadienyl titanium complexes , 2003 .

[126]  G. Erker,et al.  Organic Functional Group Transformations in the Periphery of a Group‐4 Metallocene Complex: 2H‐Pyrrole Formation at a Pendant Boron Lewis Acid , 2003 .

[127]  K. Mach,et al.  Crystal structures and solution dynamics of monocyclopentadienyl titanium(IV) complexes bearing pendant ether and phosphanyl type functionalities , 2003 .

[128]  G. Erker,et al.  Formation of dinuclear titanium and zirconium complexes by olefin metathesis--catalytic preparation of organometallic catalyst systems. , 2003, Chemistry.

[129]  P. Gendre,et al.  Synthesis of enol esters catalysed by ‘early–late’ Ti–Ru complexes , 2003 .

[130]  H. Jacobsen,et al.  Neutral and Cationic [Bis(η1‐amidosilyl)‐η5‐cyclopentadienyl]titanium and ‐zirconium Complexes: Synthesis, X‐ray Molecular Structures and DFT Calculations , 2003 .

[131]  Jiling. Huang,et al.  Synthesis, structures, and catalytic reactions of ring-substituted titanium(IV) complexes. , 2003, Chemical reviews.

[132]  A. Spek,et al.  Silsesquioxane-bonded zirconocene complexes; soluble models for silica-tethered olefin polymerization catalysts. , 2003 .

[133]  S. Lancaster,et al.  The synthesis of half-sandwich bis(pentafluorophenyl)boryl-substituted cyclopentadienyl zirconium, niobium and tantalum complexes and the isolation and molecular structure of a zwitterionic niobocene , 2003 .

[134]  P. Hitchcock,et al.  Synthesis of titanium(IV) (cyclopentadienylalkyl)aminate complexes , 2003 .

[135]  H. Alt,et al.  Bridged and unbridged substituted indenyl complexes of titanium and zirconium as catalysts for homogeneous and heterogeneous homo- and copolymerization of olefins , 2003 .

[136]  H. Nakazawa,et al.  Synthesis and characterization of some zirconium and hafnium complexes with a phosphide-pendant cyclopentadienyl ligand , 2003 .

[137]  G. Erker,et al.  Selective Intramolecular [N]CH Activation in Bis(1-ethenylamino-Cp)zirconium−Butadiene Complexes and Related Systems , 2003 .

[138]  H. Nakazawa,et al.  Formation of Novel Phosphide Dichloride Zr Complex from Trichloride Zr Complex with a Secondary Phosphine-pendant Cyclopentadienyl Ligand: Structure of [{η5-C5H4(CH2)2PMes-κP}ZrCl2(N-methylimidazole)2] (Mes = 2,4,6-Trimethylphenyl) , 2003 .

[139]  M. Horáček,et al.  Polymerization of propene with modified constrained geometry complexes. Double-bond isomerization in pendant alkenyl groups attached to cyclopentadienyl ligands , 2003 .

[140]  G. Erker,et al.  Synthesis, Structural and Chemical Characterization of Unsaturated C4‐ and C10‐Bridged Group‐4 ansa‐Metallocenes Obtained Through a Ring‐Closing Olefin Metathesis Reaction , 2002 .

[141]  P. Shapiro The evolution of the ansa-bridge and its effect on the scope of metallocene chemistry , 2002 .

[142]  G. Jin,et al.  Polymer immobilized silane bridged metallocene catalysts for ethylene polymerization , 2002 .

[143]  M. Ogasawara,et al.  Metathesis route to bridged metallocenes. , 2002, Journal of the American Chemical Society.

[144]  I. Císařová,et al.  Reduction-Induced Cyclization and Redox Reactions of Fully Methylated Titanocene Dichlorides Bearing Pendant Alkenyldimethylsilyl Groups, [TiCl2{η5-C5Me4(SiMe2R)}2] (R = Vinyl and Allyl) , 2002 .

[145]  E. Herdtweck,et al.  Cyclopentadienyl-Amido Ligands with a Pendant “−NHR” Amino Functionality in Titanium Chemistry. Molecular Structure of [Ti{η5-C5H4SiMe2-η-N(CH2)2-η-NHCHMe2}Cl2] , 2002 .

[146]  H. Alt,et al.  Synthesis of novel metallacyclic zirconocene complexes from ω-alkenyl-functionalized zirconocene dichloride complexes and their use in the α-olefin polymerization , 2002 .

[147]  G. Erker,et al.  Synthesis and structural characterization of Group 4 metallocene complexes that contain remote carboxamide functionalities at their Cp-side chains , 2002 .

[148]  G. Erker,et al.  Formation of sp3-C1-Bridged Cp/Amido Titanium and Zirconium “CpCN” Constrained-Geometry Ziegler−Natta Catalyst Systems , 2002 .

[149]  M. Picquet,et al.  Ti–Ru bimetallic complexes: catalysts for ring-closing metathesis , 2002 .

[150]  Jian Yu,et al.  Preparation of isospecific metallocene catalysts for olefin polymerization that are covalently tethered on solid surface , 2002 .

[151]  Malcolm L. H. Green,et al.  Synthesis of metallocenes of zirconium, hafnium, manganese, iron, tin, lead and half-sandwich complexes of rhodium and iridium containing the ligands(η-C5R4CR'2PMe2), where R and R' may be H or Me , 2001 .

[152]  Y. Yamaguchi,et al.  Electronic effects in homogeneous Ziegler–Natta catalysts: Zr–Rh early–late heterobimetallic complexes , 2001 .

[153]  H. Alt,et al.  Diastereomeric amido functionalized ansa half-sandwich complexes of titanium and zirconium as catalyst precursors for ethylene polymerization to give resins with bimodal molecular weight distributions , 2001 .

[154]  J. Čejka,et al.  Synthesis of {1,3-bis(η5-tetramethylcyclopentadienyl)-1,1,3,3-tetramethyldisiloxane}dichlorotitanium(IV) via hydrolysis of bis{η5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV) , 2001 .

[155]  G. Luft,et al.  Synthesis, Structure and Reactivity of a Zirconocene Dichloride with (Me3Si)2NSiMe2 Side‐Chains , 2001 .

[156]  H. Alt,et al.  Amido functionalized ansa half-sandwich dichloride complexes of titanium, zirconium and hafnium with alkyl and ω-alkenyl substituents as homogeneous and self-immobilizing catalyst precursors for ethylene polymerization , 2001 .

[157]  P. Gómez-Sal,et al.  A Versatile Synthetic Route for Cyclopentadienyl−Amido Titanium(IV) Compounds. NMR Spectroscopy Study and X-ray Molecular Structure of [Ti{η5-C5H4SiMe2NMe(CH2)2-η-NMe}Cl2] , 2001 .

[158]  M. Bochmann,et al.  Anionic ansa-Zirconocenes with Pentafluorophenyl-Substituted Borato Bridges , 2001 .

[159]  S. Collins,et al.  Synthesis of and Olefin Polymerization Using Tethered, ansa-Metallocene Complexes , 2001 .

[160]  P. Shapiro Boron‐Bridged Group‐4 ansa‐Metallocene Complexes , 2001 .

[161]  R. Gómez,et al.  Mono- and di-cyclopentadienyl zirconium derivatives containing the dimethylsilylcyclopentadienyl ligand. Agostic linear Si–H–Zr interaction in the molecular structure of [Zr{η5-C5H4(SiMe2H)}Cl3]2 , 2001 .

[162]  F. Fronczek,et al.  Influence of the Departing Group on the Electrophilic Cleavage of Silicon−Carbon Bonds Adjacent to Zirconocene Dichloride. Preparation of Electrophile-Functionalized Zirconocene Dibromides , 2000 .

[163]  H. Alt,et al.  Boryl-substituted Zirconocene Dichloride Complexes as Catalyst Precursors for Homogeneous Ethylene Polymerization , 2000 .

[164]  F. Fronczek,et al.  Selective tin-carbon bond cleavage reactions of trimethylstannylzirconocene dichloride with electrophiles. , 2000, Inorganic chemistry.

[165]  K. Nicholas,et al.  Preparation of [2,5-Diisopropylcyclohexane-1,4- bis(indenyl)]titanium Dichloride and [2,5-Diisopropylcyclohexane-1,4-bis(tetrahydroindenyl)]- titanium Dichloride and Their Comparison as Catalysts for the Enantioselective Pinacol Coupling of Benzaldehyde† , 2000 .

[166]  G. Erker,et al.  Addition and Coupling Reactions of Zirconocene Cation Complexes that Contain a Pendant η2-Formaldiminium Side Chain , 2000 .

[167]  P. Richard,et al.  Synthesis and structural studies of Ti Ru polymetallic systems , 2000 .

[168]  I. Císařová,et al.  Reduction of Bis[η5‐(ω‐alkenyl)tetramethylcyclopentadienyl]titanium Dichlorides: An Efficient Synthesis of Long‐Chain ansa‐Bridged Titanocene Dichlorides by Acidolysis of Cyclopentadienyl‐Ring‐ Tethered Titanacyclopentanes , 2000 .

[169]  P. McGowan,et al.  A one-step synthesis of protected functionalised titanocene dichlorides , 2000 .

[170]  P. Gómez-Sal,et al.  Synthetic and reactivity studies of mono- and dicyclopentadienyl titanium, zirconium and hafnium complexes with the chlorodimethylsilyl-cyclopentadienyl ligand. X-ray molecular structure of Hf{(η5-C5H4)SiMe2OSiMe2(η5-C5H4)}Cl2 and Zr(η5-1,3-tBu2C5H3)(η5-C5H4SiMe2-η-NtBu)Cl , 2000 .

[171]  E. Hey‐Hawkins,et al.  Unexpected P-Si or P-C Bond Cleavage in the Reaction of Li2[(C5Me4)SiMe2-PR] (R = Cyclohexyl, 2,4,6-Me3C6H2) and Li[(C5H4)CMe2-PHR] (R = Ph, tBu) with ZrCl4 or [TiCl3(thf)3]: Formation and Molecular Structure of the ansa-Metallocenes [{(η-C5Me4)2SiMe2}ZrCl2] and [{(η-C5H4)2CMe2}MCl2] (M = Ti, Zr) , 2000 .

[172]  P. Jutzi,et al.  Results and perspectives in the chemistry of side-chain-functionalized cyclopentadienyl compounds , 2000 .

[173]  H. Alt,et al.  Synthesis, characterization and catalytic properties of metallacyclic zirconocene complexes , 2000 .

[174]  J. Gladysz Frontiers in Metal-Catalyzed Polymerization: Designer Metallocenes, Designs on New Monomers, Demystifying MAO, Metathesis Déshabillé. , 2000, Chemical reviews.

[175]  H. Butenschön,et al.  Cyclopentadienylmetal complexes bearing pendant phosphorus, arsenic, and sulfur ligands. , 2000, Chemical reviews.

[176]  M. Thornton-Pett,et al.  Synthetic, Reactivity, and Structural Studies on Borylcyclopentadienyl Complexes of Titanium: New CpB Titanocene Complexes with C−B−Cl, C−B−O, and C−B−N Bridges (CpB = η5-C5H4B(C6F5)2) , 2000 .

[177]  U. Siemeling,et al.  Chelate complexes of cyclopentadienyl ligands bearing pendant o-donors. , 2000, Chemical reviews.

[178]  H. Alt,et al.  Metallacyclic zirconocene complexes as catalysts for homogeneous and heterogeneous ethylene polymerization , 2000 .

[179]  G. Erker,et al.  Structural Characterization of Heterodimetallic Zr/Pd and Zr/Rh Catalyst Precursors Containing the C5H4PPh2 Ligand , 2000 .

[180]  W. Seo,et al.  Cyclopentadienyl−Hydrazido Titanium Complexes: Synthesis, Structure, Reactivity, and Catalytic Properties , 2000 .

[181]  G. Erker,et al.  Reactions of Functional Groups at the Periphery of Group 4 Metallocene Frameworks: Selective Formation of a Cp‐Bonded Azaboretidine Derivative by a Hydroboration Route , 2000 .

[182]  P. Gracia,et al.  Synthetic and reactivity studies of mono- and dicyclopentadienyl titanium, zirconium and hafnium complexes with the chlorodimethylsilyl-cyclopentadienyl ligand. X-ray molecular structure of Hf{(η5-C5H4)SiMe2OSiMe2(η5-C5H4)}Cl2 and Zr(η5-1,3-tBu2C5H3)(η5-C5H4SiMe2-η-NtBu)Cl , 2000 .

[183]  G. Erker,et al.  1,3-Doubly Bridged Group 4 Metallocenes by Intramolecular Reductive Coupling of Pendant Olefins , 2000 .

[184]  L. Zsolnai,et al.  SYNTHESIS AND MOLECULAR STRUCTURES OF CHIRAL ansa-TITANOCENE DERIVATIVES WITH BRIDGED TETRAHYDROINDENYL LIGANDS , 2000 .

[185]  J. Okuda,et al.  Complexes of titanium and zirconium containing a tridentate linked amido–cyclopentadienyl ligand with a soft donor group: synthesis, structure, and ethylene polymerization catalysis , 1999 .

[186]  A. Vij,et al.  Stable Borate-Bridged ansa-Zirconocene Complexes. Preparation and X-ray Crystallographic Characterization of [Cp*2Al]+[Me(Ph)B(η5-C5H4)2ZrCl2]- and [PPN]+[Cl(Ph)B(η5-C5H4)2ZrCl2]- , 1999 .

[187]  P. Royo,et al.  Transition metal complexes with functionalized silyl-substituted cyclopentadienyl and related ligands: synthesis and reactivity , 1999 .

[188]  G. Erker,et al.  Evidence for α-Nitrogen Participation in the Internal C−H Activation Reaction at ((Dimethylamino)methyl)cyclopentadienyl-Derived Methylzirconocene Cations , 1999 .

[189]  Freitag,et al.  Donor/Acceptor Metallocenes: A New Structure Principle in Catalyst Design. , 1999, Angewandte Chemie.

[190]  C. Slebodnick,et al.  ELECTROPHILE-FUNCTIONALIZED METALLOCENE INTERMEDIATES. APPLICATION IN THE DIASTEREOSELECTIVE SYNTHESIS OF A TETRAMETHYLDISILOXANE-BRIDGED C2-SYMMETRIC ANSA-ZIRCONOCENE DIBROMIDE , 1999 .

[191]  R. McDonald,et al.  ((Diaryl- and Dialkylphosphino)alkyl)cyclopentadienyl Ligands and Their Use in the Preparation of Heterobinuclear Ti/Mo and Zr/Mo Complexes , 1999 .

[192]  R. McDonald,et al.  Tetranuclear, Early−Late Heterobimetallic Complexes Bridged by the Bifunctional Phosphinoalkylcyclopentadienyl Ligands [Ph2P(CH2)nC5H4]- (n = 1, 2) , 1999 .

[193]  G. Erker,et al.  Organic Transformations at a Group 4 Metallocene Framework: Formation of a Rigid ansa-Metallocene by Mannich-type Carbon-Carbon Coupling. , 1999, Angewandte Chemie.

[194]  Zhongxin Zhou,et al.  Intramolecular NMe2H Elimination and Fulvene Coupling Leading to Novel Allyl-Bridged Zirconocene and Hafnocene Complexes. , 1999, Angewandte Chemie.

[195]  H. Alt,et al.  C2-bridged metallocene dichloride complexes of the types (C13H8–CH2CHR–C9H6−nR′n)ZrCl2 and (C13H8–CH2CHR–C13H8)MCl2 (n=0, 1; R=H, alkenyl; R′=alkenyl, benzyl; M=Zr, Hf) as self-immobilizing catalyst precursors for ethylene polymerization , 1999 .

[196]  Y. Yamaguchi,et al.  Synthesis of ansa-Zirconocene/Rhodium Heterobimetallic Complexes: Enhanced Catalytic Activity in Stereospecific Polymerization of α-Olefins , 1999 .

[197]  P. Kalck,et al.  Group 4 and Group 8 unbridged metallocene derivatives with a pendant fluorenyl group. X-ray structure of 1,1â²-bis[2-(2-fluorenyl)propyl]ferrocene , 1999 .

[198]  A. Slawin,et al.  Novel Routes to Bidentate Cyclopentadienyl−Alkoxide Complexes of Titanium: Synthesis of (η5-σ-C5R14CHR2CH2CR3R4O)TiCl2 , 1999 .

[199]  R. Goddard,et al.  Donor complexes of bis(1-indenyl)phenylborane dichlorozirconium as isospecific catalysts in propene polymerization , 1999 .

[200]  Malcolm L. H. Green,et al.  Synthesis of heterobinuclear metallocenes containing bridging ansa-bis-η-cyclopentadienyl ligands† , 1999 .

[201]  H. Alt The heterogenization of homogeneous metallocene catalysts for olefin polymerization , 1999 .

[202]  M. Sabat,et al.  Co-ordinative ability of the new compounds [Ti(η5-C5H4R)2(CCBut)2] (R = PPh2, Ph2PO or Ph2PS) as precursors in the synthesis of heterodi- and heterotri-nuclear species. Crystal structure of [ClCu(µ-η5∶κP-C5H4PPh2)2Ti(µ-η2-CCBut)2CuCl] , 1999 .

[203]  Yimin Sun,et al.  Zwitterionic metallocenes via reactions of organozirconocenes with highly electrophilic perfluorophenyl substituted boranes , 1999 .

[204]  G. Parkin,et al.  Phosphorus-Bridged ansa-Metallocene Complexes of Titanium, Zirconium, and Hafnium: The Syntheses and Structures of [PhP(C5Me4)2]MX2 and [Ph(E)P(C5Me4)2]MX2 (E = O, S, Se) Derivatives , 1999 .

[205]  R. Waymouth,et al.  Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization. , 1998, Chemical reviews.

[206]  D. A. Lemenovskii,et al.  On the reduction behaviour of 2-methoxyethyl and 2-methylthioethyl substituted zirconocene dichlorides: crystal structure of (η5,σ-C5Me4CH2CH2S)2Zr , 1998 .

[207]  J. Chien,et al.  PENDENT AMINOALKYL-SUBSTITUTED MONOCYCLOPENTADIENYLTITANIUM COMPOUNDS AND THEIR POLYMERIZATION BEHAVIOR , 1998 .

[208]  G. Kehr,et al.  C1-verbrückte Fluorenyliden–Indenylidenkomplexe des Typs (C13H8–CR2–C9H6−nR′n)ZrCl2 (n=0, 1; R=Me, Ph, Butenyl; R′=Alkyl, Alkenyl) als Metallocenkatalysatorvorstufen für die Ethylenpolymerisation , 1998 .

[209]  H. Alt,et al.  ansa-Metallocenkomplexe des Typs (C13H8SiR2C9H6−nR′n)ZrCl2 (n=0, 1; R=Me, Ph, Alkenyl; R′=Alkyl, Alkenyl): Selbstimmobilisierende Katalysatorvorstufen für die Ethylenpolymerisation , 1998 .

[210]  A. Chan,et al.  Chlorination of differentially ring-substituted titanocene complex by SO2Cl2\SOCl2 and X-ray structure of chlorinated product [C5H4C (C2H5) 2-C6H2-3-Cl-5-Cl-2-O] TiCl2 , 1998 .

[211]  P. Jutzi,et al.  Aminoethyl‐Functionalized Cyclopentadienyl Complexes of d‐Block Elements , 1998 .

[212]  J. Näsman,et al.  Synthesis and characterization of ethylene-bridged 1-tert-butyldimethylsiloxy-substituted bis(indenyl) and bis(tetrahydroindenyl)zirconium dichlorides , 1998 .

[213]  J. H. Teuben,et al.  Titanium hydrocarbyl complexes with a linked cyclopentadienyl-alkoxide ancillary ligand: Participation of the ligand in an unusual activation of a (trimethylsilyl)methyl group , 1998 .

[214]  R. Fröhlich,et al.  The synthesis of substituted bis[(diarylphosphinomethyl)cyclopentadienyl]zirconocene dichloride complexes for the preparation of heterodimetallic complexes containing early/late transition metal combinations , 1998 .

[215]  Hendrik Luttikhedde,et al.  Bis(triisopropylsiloxyindenyl) zirconocenes , 1998 .

[216]  Malcolm L. H. Green,et al.  Homo- and hetero-binuclear ansa-metallocenes of the group 4 transition metals as homogeneous co-catalysts for the polymerisation of ethene and propene , 1998 .

[217]  A. Chan,et al.  Syntheses, structures and reactions of some new benzyl-substituted cyclopentadienyl titanium complexes , 1997 .

[218]  M. Thornton-Pett,et al.  Synthesis of Cyclopentadienyl-, Indenyl-, and Fluorenylbis(pentafluorophenyl)boranes as Ligands in Titanium and Zirconium Half-Sandwich Complexes. The Crystal Structures of C13H9B(C6F5)2·t-BuNH2, C13H8SiMe3B(C6F5)2, and {η5-C5H4B(C6F5)2}TiCl3 , 1997 .

[219]  A. Rheingold,et al.  Novel ansa-Metallocenes with a Single Boron Atom in the Bridge: Syntheses, Reactivities, and X-ray Structures of {Ph(L)B(η5-C5H4)2}ZrCl2 (L = SMe2, PMe3) , 1997 .

[220]  G. Erker,et al.  Uncovering Alternative Reaction Pathways Taken by Group 4 Metallocene Cations: Facile Intramolecular CH Activation of Cp−(Dimethylamino)alkyl Substituents by a Methylzirconocene Cation , 1997 .

[221]  R. Sjöholm,et al.  Homogeneous α-Olefin Polymerizations over Racemic Ethylene-Bridged ansa-Bis(2-(tert-butyldimethylsiloxy)- 1-indenyl) and ansa-Bis(2-(tert-butyldimethylsiloxy)- 4,5,6,7-tetrahydro-1-indenyl) Metallocene Dichlorides , 1997 .

[222]  J. S. Downey,et al.  BORON-SILICON EXCHANGE REACTIONS OF BORON TRIHALIDES WITH TRIMETHYLSILYL-SUBSTITUTED METALLOCENES , 1997 .

[223]  J. Okuda,et al.  Linked Benzylamido‐Cyclopentadienyl Ligands: Synthesis and Characterization of Alkyl Titanium Complexes , 1997 .

[224]  P. S. Ford,et al.  Lewis base functionalised cyclopentadienyl complexes of titanium , 1997 .

[225]  R. Gómez,et al.  Synthesis and Reactivity of [(Amidosilyl)cyclopentadienyl]titanium and -zirconium Complexes. X-ray Molecular Structure of [Zr{η5:η1-C5H4SiMe2(μ-O)}Cl2{H2N(CHMe)Ph}]2† , 1996 .

[226]  V. Bakhmutov,et al.  Synthesis, NMR Study, and Reactivity of Isomeric Early-Late Heterobimetallic Dihydrides. X-ray Crystal Structure of (PPh(3))HRu(&mgr;-H)(&mgr;-PMe(2)C(5)Me(4))(2)(&mgr;-Cl)ZrCl. , 1996, Inorganic chemistry.

[227]  J. Okuda,et al.  Optically Active Titanium Complexes Containing Linked Amido‐cyclopentadienyl Ligands: Their Use as Asymmetric Hydrogenation Catalysts , 1996 .

[228]  P. Jutzi,et al.  Mixed Bent Sandwich Titanium Complexes with the [2-(Diisopropylamino)ethyl]cyclopentadienyl Ligand — Catalysts for the Polymerization of Ethylene and the Dehydrocoupling of Phenylsilane , 1996 .

[229]  P. Jutzi,et al.  Titanium and Zirconium Bent-Sandwich Complexes with the New [2-(Diisopropylamino)ethyl]cyclopentadienyl Ligand: Catalysts for the Polymerization of Ethylene and the Dehydrocoupling of Phenylsilane , 1996 .

[230]  W. Tikkanen,et al.  Preparation, characterization and carbonylation of the ring-functionalized dibenzyl zirconocenes, , 1996 .

[231]  W. Massa,et al.  Synthesis and Characterization of Titanium Complexes Containing Potentially Tridentate Amido‐cyclopentadienyl Ligands , 1996 .

[232]  J. L. Petersen,et al.  Facile Conversion of an Appended Silylamido to a Silyloxy Ligand via Isocyanate Elimination. Synthesis of {[(C5Me4)SiMe2O]Zr(η2-O2CMe)(μ-O2CMe)}2 via the Carboxylation of [(C5Me4)SiMe2(N-t-Bu)]ZrMe2 , 1996 .

[233]  Malcolm L. H. Green,et al.  New mono- and bi-nuclear ansa-metallocenes of zirconium and hafnium as catalysts for the polymerisation of ethene and propene , 1996 .

[234]  J. Christoffers,et al.  Stereoselective Synthesis of Chiral Zirconocenes from Doubly Substituted, Donor Functionalized Cyclopentadienes via Helical Chelate Complexes , 1995 .

[235]  W. Piers,et al.  One-Component Group 4 Homogeneous Ziegler-Natta Olefin Polymerization Catalysts: Hydroboration of Zirconium Bisalkyls with Pendant 2-Propenyl Groups Using [(C6F5)2BH]2 , 1995 .

[236]  U. Siemeling,et al.  Cyclopentadienyl compounds with nitrogen donors in the side-chain , 1995 .

[237]  E. Lalinde,et al.  Thiolate derivatives of bis(diphenylphosphinocyclopentadienyl)titanium TiPt and TiPd heterobimetallic compounds , 1995 .

[238]  D. A. Lemenovskii,et al.  Synthesis of sandwich and half-sandwich complexes of Ti, Zr and Hf containing η5-C5H4SiMe2Cl ligand. Molecular structure of [TiCl2(μ-OSiMe2-η5-C5H4)]2 , 1995 .

[239]  Malcolm L. H. Green,et al.  Cycloheptatriene and -enyl Complexes of the Early Transition Metals , 1995 .

[240]  K. B. Lam,et al.  Synthesis, Characterization, and Carbonylation of the Asymmetric Mono-Ring-Functionalized Zirconocenes, (.eta.5-C5H5)(.eta.5-C5H4P(C6H5)2)Zr(CH3)X (X = CH3, Cl) , 1995 .

[241]  M. Visseaux,et al.  Reactivity of f-d heterobinuclear vs, d metal complexes: assisted or impeded catalysis. Evidence for the formation of stable chloro-bridged heterobimetallic species. Synthesis of RuH2PPh3[(C5Me4PMe2)2ZrCl2] , 1995 .

[242]  Y. Mu,et al.  New ligand environments for soluble Zieglernatta olefin polymerization catalyst precursors. X-ray structures of☆ , 1995 .

[243]  P. Gómez-Sal,et al.  New Silyl-Substituted Cyclopentadienyl Titanium and Zirconium Complexes. X-ray Molecular Structures of [TiCl2{.mu.-(OSiMe2-.eta.5-C5H4)}]2 and [ZrCl2{.mu.-[(.eta.5-C5H4)SiMe2OSiMe2(.eta.5-C5H4)]}] , 1995 .

[244]  B. Rieger,et al.  A Convenient Synthesis of Enantiomerically Pure Ethylene‐Bridged Metallocene Complexes Bearing Fluorenyl‐ and Octahydrofluorenyl Ligands[1] , 1994 .

[245]  J. C. Flores,et al.  {[2-(Dimethylamino)ethyl]cyclopentadienyl}trichlorotitanium: A New type of Olefin Polymerization Catalyst , 1994 .

[246]  R. Rogers,et al.  New sulfur and selenium derivatives of (μ5-cyclopentadienyl) (μ7-cycloheptatrienyl) titanium, and their application in the syntheses of heterobimetallic compounds , 1994 .

[247]  Xianglin Jin,et al.  A novel synthetic route to titanoxacycle complexes , 1994 .

[248]  Malcolm L. H. Green,et al.  Synthesis of homo- and hetero-bimetallic complexes incorporating the [(η5-C5H4)CMe2(η5-C9H6)] ligand , 1994 .

[249]  U. Thewalt,et al.  Zirkonocenkomplexe mit einem funktionalisierten Cyclopentadienylliganden. Molekülstruktur von (η5-C5H5)(η5:η2-C5H4CMe2C9H7)Zr(PMe3) , 1993 .

[250]  G. Erker,et al.  Synthesis of ansa-metallocenes by intramolecular photochemical [2 + 2] cycloaddition of bis(alkenylcyclopentadienyl)zirconium complexes , 1993 .

[251]  G. Erker,et al.  Intramolecular [2 + 2] cycloaddition of bis(alkenylcyclopentadienyl)zirconium dihalides: a novel way of synthesizing ansa-metallocene complexes , 1992 .

[252]  L. Atovmyan,et al.  Synthesis of bimetallic complexes via 4-stannatetrahydro-s-indacenes , 1992 .

[253]  A. Rheingold,et al.  Preparation and properties of (S,S)-[Ti((R,R)-cyclacene)Cl2], a chiral strapped bent metallocene , 1992 .

[254]  N. Coville,et al.  Monosubstituted cyclopentadienyl half-sandwich transition metal complexes , 1992 .

[255]  A. Rheingold,et al.  Preparation and properties of chiral titanocene and zirconocene dichloride complexes of a chiral ligand , 1992 .

[256]  G. Erker,et al.  Cp-substituent additivity effects controlling the stereochemistry of the propene polymerization reaction at conformationally unrestricted (Cp-CHR1R2)2ZrCl2/methylalumoxane catalysts , 1991 .

[257]  R. Rogers,et al.  Formation and molecular structure of hydridotricarbonyl{[.eta.5-(diphenylphosphino)cyclopentadienyl][.eta.7-(diphenylphosphino)cycloheptatrienyl]titanium-P,P'}manganese: a new chelated titanium-manganese heterobimetallic compound , 1991 .

[258]  J. Ziller,et al.  Preparation and carbonylation of ring-functionalized methyl zirconocenes [(.eta.5-C5H4)P(C6H5)2]2Zr(CH3)2-nCln (n = 0, 1). Observation and x-ray structure of a fluxional acyl-phosphonium moiety in the complex [cyclic] [(.eta.5-C5H4)P(C6H5)2][(.eta.5-C5H4)P(C6H5)2Zr[.eta.2-(OC)CH3]Cl , 1991 .

[259]  G. Erker,et al.  Hydroboration of Bis(alkenylcyclopentadienyl)zirconium Dichlorides , 1991 .

[260]  W. A. Schenk,et al.  M(IV)–M′(O)-Zweikernkomplexe (M = Ti, Zr, M′ = Cr, Mo, W) mit verbrückenden Phosphinocyclopentadienid-, Chlorid- und Thiolatliganden / M(IV)–M′(O) Dinuclear Complexes (M = Ti, Zr, M′ = Cr, Mo, W) with Bridging Phosphinocyclopentadienide, Chloride, and Thiolate Ligands , 1991 .

[261]  R. Rogers,et al.  New heterobimetallic compounds derived from [η5-(dimethylphosphino)cyclopentadienyl]-[η7-(dimethylphosphino)cycloheptatrienyl]titanium , 1991 .

[262]  J. Szymoniak,et al.  Synthesis of bent titanocene metalloligands with the (diphenylphosphino)tetramethylcyclopentadienyl moiety. X-ray structure of [(η5-C5Me42)2TiCl2]Mo(CO)4 , 1991 .

[263]  W. A. Schenk,et al.  Heterometallische Zweikernkomplexe, I: Reaktive Zr(IV)–M(0)‐Verbindungen (M = Cr, Mo, W) mit Diphenylphosphinocyclopentadienid‐Brückenliganden , 1989 .

[264]  W. Tikkanen,et al.  Bifunctional ligands for the preparation of heterobinuclear complexes. Synthesis and characterization of Tl(5H4)P(CH3)2, [(η5-C5H4)P(CH3)2]2ZrCl2 and the heterobinuclear complex {μ-(η5-C5H4)P(CH3)2]ZrCl2}Mo(CO)4 , 1989 .

[265]  R. Rogers,et al.  Synthesis of [.eta.5-(diphenylphosphino)cyclopentadienyl][.eta.7-(diphenylphosphino)cycloheptatrienyl]titanium and its utility in the formation of heterobimetallic complexes: the molecular structure of tetracarbonyl{[.eta.5-(diphenylphosphino)cyclopentadienyl][.eta.7-(diphenylphosphino)cycloheptatri , 1989 .

[266]  Minren Lin,et al.  Preparation of phenylplatinum-zirconium complexes with Ph2PC5H4 or PhP(C5H4)2 bridging ligands and their reactions with carbon monoxide , 1988 .

[267]  N. Taylor,et al.  X-Ray structures of ethylenebis(tetrahydroindenyl)-titanium and -zirconium dichlorides: a revision , 1988 .

[268]  R. Waymouth,et al.  Stereochemistry of PtO2-catalyzed hydrogenation of [ethylenebis(indenyl)]zirconium dichloride , 1988 .

[269]  R. Bullock,et al.  Heterobimetallic compounds linked by heterodifunctional ligands , 1987 .

[270]  N. Schore,et al.  Use of heterodifunctional ligands to bridge “early” and “late” transition metals. Construction and chemistry of complexes containing indirectly linked cobalt carbonyl and zirconocene units , 1987 .

[271]  Y. Fujita,et al.  Functionalized Group 4 metallocene complexes as binucleating ligands: synthesis and structural characterization of tetracarbonyl [[P,P'-bis(diphenylphosphino)cyclopentadienyl)]dichlorozirconium(IV)]molybdenum(0) , 1986 .

[272]  C. Casey,et al.  Early―late transition metal heterobimetallic compounds linked by a heterodifunctional (diphenylphosphino)cyclopentadienyl-bridging ligand , 1985 .

[273]  M. Wasiucionek,et al.  ansa-metallocene derivatives: XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands☆ , 1985 .

[274]  J. Atwood,et al.  Formation of [(diphenylphosphino)cyclopentadienyl]thallium and its utility in the synthesis of heterobimetallic titanium-manganese complexes: the molecular structure of (.eta.5-cyclopentadienyl)dicarbonyl[(.eta.5-cyclopentadienyl)[.eta.5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium-P]mangane , 1983 .

[275]  C. Leblanc,et al.  Complexes du titane et du zirconium contenant les ligands cyclopentadienyldiphenylphosphine et cyclopentadienylethyldiphenylphosphine: acces a des structures heterobimetalliques , 1982 .

[276]  M. Rausch,et al.  Functionally Substituted Cyclopentadienyl Metal Compounds , 1982 .

[277]  N. Schore Synthesis of (C6H5)2PCH2Si(CH3)2C5H4Li: a novel heterodifunctional system for the directed linkage of dissimilar transition metal fragments , 1979 .