Simultaneous temperature and multispecies measurement in a lifted hydrogen diffusion flame

This paper reports that ultraviolet (UV) spontaneous vibrational Raman scattering and laser-induced predissociative fluorescence (LIPF) techniques are combined and applied to a lifted hydrogen jet diffusion flame. Simultaneous, temporally and spatially resolved point measurements of temperature, major species concentrations (H[sub 2], O[sub 2] N[sub 2], H[sub 2]O), and absolute hydroxyl radical concentration (OH) are obtained with a single excimer laser for the first time. For OH measurements, the use of LIPF makes quenching corrections unnecessary. Results demonstrate that fuel and oxidizer are in a rich, premixed, and unignited condition in the center core of the lifted flame base. In the lifted zone, combustion occurs in an intermittent annular turbulent flame brush and strong finite-rate chemistry effects result in nonequilibrium values of temperature, major species, and OH radicals. Downstream in the slow three-body recombination zone, the major species concentrations are in partial equilibrium, the OH concentrations are in superequilibrium, and the temperatures are in subequilibrium. Far downstream in the flame, equilibrium values of temperature, OH radical, and major species are found.