PEM FC with improved water management

Water management problems of proton exchange membrane (PEM)-based H2/O2 and H2/air fuel cell systems (PEM FC) are considered. It is demonstrated that PEM FC performance and efficiency are strongly influenced by water transport phenomena. A new water management scheme, based on anode side water removal, is suggested. It is shown that such a scheme may be very efficient if implementing cathode modified by oxygen permeable liquid perfluorocarbones. Possible efficiency of such a PEM FC is estimated using literature-based parameters of existing practical PEM FC.

[1]  Qingfeng Li,et al.  Approaches and Recent Development of Polymer Electrolyte Membranes for Fuel Cells Operating above 100 °C , 2003 .

[2]  G. Wnek,et al.  Characterization of electrosprayed Nafion films , 2004 .

[3]  I. Hsing,et al.  Absorption, Desorption, and Transport of Water in Polymer Electrolyte Membranes for Fuel Cells , 2005 .

[4]  G. Eigenberger,et al.  Transport parameters for the modelling of water transport in ionomer membranes for PEM-fuel cells , 2004 .

[5]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[6]  Tatsuhiro Okada,et al.  Theory of water management at the anode side of polymer electrolyte fuel cell membranes , 1996 .

[7]  Harvey G. Stenger,et al.  Computational fluid dynamics modeling of polymer electrolyte membrane fuel cells , 2005 .

[8]  Shimshon Gottesfeld,et al.  Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes , 1991 .

[9]  Z. H. Wang,et al.  Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells , 2000 .

[10]  K. Kreuer On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells , 2001 .

[11]  Chao-Yang Wang,et al.  Liquid Water Transport in Gas Diffusion Layer of Polymer Electrolyte Fuel Cells , 2004 .

[12]  Shimshon Gottesfeld,et al.  The Water Content Dependence of Electro-Osmotic Drag in Proton-Conducting Polymer Electrolytes , 1995 .

[13]  Alexander Wokaun,et al.  Characterisation of Fuel Cell Membranes as a Function of Drying by Means of Contact Angle Measurements , 2004 .

[14]  G. Scherer,et al.  Proton-conducting polymer membranes in fuel cells—humidification aspects , 2004 .

[15]  Mark W. Verbrugge,et al.  A Mathematical Model of the Solid‐Polymer‐Electrolyte Fuel Cell , 1992 .

[16]  D. Wilkinson,et al.  Anode water removal: A water management and diagnostic technique for solid polymer fuel cells , 1995 .

[17]  B. Wetton,et al.  Water Management in PEM Fuel Cells , 2004 .

[18]  T. Nguyen,et al.  Multicomponent transport in porous electrodes of proton exchange membrane fuel cells using the interdigitated gas distributors , 1999 .