9.2 – Carbacyclic Silanes

[1]  T. Barton,et al.  Radical rearrangements in the pyrolysis of allyldisilanes , 1980 .

[2]  C. Guérin,et al.  Nucleophilic displacement at silicon sterochemistry and mechanistic implications , 1980 .

[3]  M. Kumada,et al.  PHOTOLYSIS OF ORGANOPOLYSILANES. THE SYNTHESIS AND REACTIONS OF STABLE SILACYCLOPROPENES , 1980 .

[4]  J. Y. Corey,et al.  Tricyclic systems which contain silicon and nitrogen heteroatoms in central seven- and eight-membered rings , 1980 .

[5]  J. Y. Corey,et al.  Synthesis and chemistry of the phenoxasilins and dihydro-dibenzo-oxasilepins , 1980 .

[6]  G. Märkl,et al.  cis-dicarbonyl-η-1-silacyclohexa-2,4-dien-molybdän(0) und -wolfram(0)-komplexe, dimere 4-alkyl-1-silacyclohexa-1,3-diene mit 1,3-disilacyclobutanstruktur, und 2,2′-di-1-silacyclohexa-2,4-diene , 1980 .

[7]  Yizhen Tang,et al.  Formation of 1-silacyclopenta-2,4-diene through recoil silicon atom reactions , 1980 .

[8]  V. Tortorelli,et al.  Stereochemistry of the addition of dimethylsilylene to cis- and trans-2-butene , 1980 .

[9]  J. Soderquist,et al.  Vinylmetalloids. 3. Sila- and germacyclopentan-2-ones from metallated enol ethers , 1980 .

[10]  S. Hoekman,et al.  Bis(trimethylsilyl)-, trimethylsilyltrimethylgermyl-, and bis(trimethylgermyl)diazomethane. Synthesis and chemistry of quantitative silene and germene precursors , 1980 .

[11]  A. SoderquistJ,et al.  金属化エノールエーテルからのシラ‐およびゲルマシクロペンタン‐2‐オン , 1980 .

[12]  C. Easton,et al.  Some guidelines for radical reactions , 1980 .

[13]  J. Kiely,et al.  1,8-Difunctionalized naphthalenes as building blocks. A convenient low temperature synthesis of 1-silaacenaphthenes , 1979 .

[14]  N. S. Nametkin,et al.  Formation and properties of unstable intermediates containing multiple p.pi.-p.pi. bonded Group 4B metals , 1979 .

[15]  T. Barton,et al.  A novel synthesis of a C-unsubstituted silole , 1979 .

[16]  M. Kumada,et al.  Photolysis of organopolysilanes. The reaction of trimethylsilylphenylsilylene with olefins and conjugated dienes , 1979 .

[17]  H. Baier,et al.  Synthese und chemie von 4R-silacyclohexa-2,5-dienen und 4R-silacyclohexa-2,4-dienen , 1979 .

[18]  J. Y. Corey,et al.  Synthesis of tricyclic compounds with sulfur and silicon heteroatoms in the central ring , 1979 .

[19]  Cs S. Liu,et al.  Reaction of vinyl chloride with difluorosilylene by cocondensation , 1979 .

[20]  U. Schubert,et al.  Photochemische umsetzung von (π-C5H5)Mn(CO)3 mit diphenylsilacyclobutan und disilanen , 1979 .

[21]  J. Clardy,et al.  Silicon-carbon double-bond formation via 1,5-sigmatropic migration of trimethylsilyl from silicon to carbon , 1979 .

[22]  H. Bürger,et al.  Darstellung und eigenschaften cyclischer silylamide des berylliums. Kristall- und molekülstruktur eines dimeren diaza-disila-berylla-cyclohexans ☆ , 1979 .

[23]  T. Barton,et al.  Serendipitous synthesis of a sila-.alpha.-pyran - convenient, penultimate precursor to dimethylsilanone , 1979 .

[24]  Toshi-aki Kobayashi,et al.  Chemistry of organosilicon compounds. 109. trans- and cis-1,2-Dimethyl-1,2-diphenyldisilene. Is Silicon:silicon a true double bond? , 1979 .

[25]  M. E. Sheikh,et al.  RELATIVELY STABLE SILAETHYLENES. PHOTOLYSIS OF ACYLPOLYSILANES , 1979 .

[26]  W. Reynolds,et al.  New evidence for the involvement of monomeric silicon difluoride in reactions with olefins , 1979 .

[27]  R. A. Benkeser,et al.  Organic chemistry of dichlorosilane. Additions to conjugated and unconjugated diene systems followed by intramolecular cyclizations , 1979 .

[28]  T. Barton,et al.  Silene generation from a silyl 1,3-migration , 1979 .

[29]  M. Kumada,et al.  Photochemically generated silicon-carbon double-bonded intermediates. 9. Synthesis, reactions, and molecular structure of a 1,2-disilacyclobutane , 1979 .

[30]  D. Seyferth,et al.  Reactions of siliranes with elemental sulfur and with t-butyl mercaptan. Preparation of the 2,3-dithia-1-silacyclopentane ring system , 1979 .

[31]  J. Wolcott,et al.  Stereochemistry of reactions in the 1,2-dimethylsilacyclopentane ring system. II. Stereoselective transformation , 1978 .

[32]  D. Seyferth,et al.  1,1-Difluoro-2,2,3,3-tetramethyl-1-silirane: synthesis and novel chemistry. Reinterpretation of difluorosilylene reaction mechanisms , 1978 .

[33]  H. Schmidbaur,et al.  Reactions of silacyclopropanes with 1,2-dipolar reagents: diazomethane and methylenetrimethylphosphorane , 1978 .

[34]  D. Seyferth,et al.  Reactions of hexamethylsilacyclopropane with carbonyl compounds in the presence of tertiary phosphines. The possible intermediacy of a dimethylsilylenephosphorane , 1978 .

[35]  P. Gaspar,et al.  REACTIONS OF RECOILING SILICON ATOMS WITH PHOSPHINE‐DIENE MIXTURES AND THE QUESTION OF SILYLENE INTERMEDIATES , 1978 .

[36]  T. Barton,et al.  Synthesis and thermochemistry of 4-diazo-1,1-dimethyl-1-silacyclohexa-2,5-diene , 1978 .

[37]  M. Curtis,et al.  Small ring metallocycles. 4. Synthesis and chemical reactivity of cyclo-metalladisiloxanes, MSiR2OSiR2, and cyclo-metalladisilabutanes, MSiR2CH2SiR2 , 1978 .

[38]  T. Barton,et al.  The role of trimethylsilylmethylsilylene in the gas-phase reactions of tetramethyldisilene , 1978 .

[39]  T. Barton,et al.  Unambiguous generation and trapping of a silabenzene , 1978 .

[40]  P. Jones,et al.  The aromatic character of silacyclopropenes , 1978 .

[41]  R. Farrell,et al.  Silipramine and related derivatives , 1978 .

[42]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. 72. Zur Reaktionsfähigkeit von Carbosilanen und ihren C‐chlorierten Derivaten bei Umsetzungen mit CH3MgCl und LiCH3 , 1978 .

[43]  R. F. Cunico,et al.  Synthesis and monochlorintion of 1-1silabicyclo[2.2.2]octaine , 1978 .

[44]  A. Sekiguchi,et al.  Chemistry of oxasilacyclopropane. 2. Formations of dioxasilacyclopentanes in the reaction of oxasilacyclopropane derivatives with adamantanone and norbornone , 1978 .

[45]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. 70 [1]. Reaktionen Si‐fluorierter 1,3,5‐Trisilapentane mit CH3MgCl und LiCH3 , 1978 .

[46]  M. Lappert,et al.  Metal-substituted silacyclobutanes. 2. Derivatives of silicon, germanium, and tin , 1978 .

[47]  D. Seyferth,et al.  REACTIONS OF 1,1-DIMETHYL-2,3-BIS(TRIMETHYLSILYL)-1-SILIRENE AND HEXAMETHYLSILIRANE WITH DIMETHYL SULFOXIDE. INSERTION OF DIMETHYLSILANONE INTO THE SILIRENE AND SILIRANE RINGS , 1978 .

[48]  L. Revelle,et al.  Silacyclobutenes: a simple synthesis , 1978 .

[49]  M. Lappert,et al.  Reactions of hydridosilacyclobutanes with low-valent complexes of iron or platinum , 1978 .

[50]  G. Bertrand,et al.  Syntheses et rearrangements thermiques de sila-1 et sila-2 dichloro-6,6 bicyclo[3.1.0]hexanes , 1978 .

[51]  C. Kapfer,et al.  The synthesis of 1-methyl-1-silaadamantane , 1978 .

[52]  M. Laguerre,et al.  Syntheses originales de nouveaux derives sila-bicycliques , 1978 .

[53]  Y. Nagai,et al.  Formation of a new silicon-containing ring system, 1,1,2,2,3,3-hexamethyl-4,5-diphenyl-1,2,3-trisilacyclopent-4-ene , 1978 .

[54]  M. Lappert,et al.  Reactions of strained organosilicon heterocycles with nonacarbonyldi-iron(0). Part 2. Preparation and reactions of silaferracyclopentanes , 1978 .

[55]  M. Kumada,et al.  Chemistry of a 1-silacyclopropene. Thermal production of 1,4-disilacyclohexa-2,5-dienes , 1977 .

[56]  H. Sakurai,et al.  Chemistry of organosilicon compounds: CIV. Syntheses of novel organoelement heterocycles containing titanium and silicon , 1977 .

[57]  L. Birkofer,et al.  Siliciumorganische verbindungen : LXV. Bromierende spaltung von 1,1,2,2-tetramethyl-1,2-disila-4-cyclohexen , 1977 .

[58]  J. Grobe,et al.  Alternativ-Liganden VII1: Chelatkomplexe des typs (Me = CH3; X = CH3, Cl) , 1977 .

[59]  J. Y. Corey,et al.  Silicon analogs of phenothiazine , 1977 .

[60]  A. Sekiguchi,et al.  Evidence of the formation of oxasilacyclopropane from the reaction of silylene with ketone , 1977 .

[61]  M. Kumada,et al.  PHOTOLYSIS OF ORGANOPOLYSILANES. REACTIONS OF TRIMETHYLSILYLPHENYLSILYLENE WITH CARBONYL COMPOUNDS , 1977 .

[62]  P. Jutzi,et al.  Synthese und reaktionen des (1Z, 4Z)1,5-dilithium-1,4-pentadiens , 1977 .

[63]  M. Curtis,et al.  Catalysis of siloxane metathesis by cyclometalladisiloxanes. Mechanistic similarities to olefin metathesis catalysis , 1977 .

[64]  T. Barton,et al.  Evidence for the generation and trapping of a silabenzene , 1977 .

[65]  C. Eaborn,et al.  The reaction of bis(phenyldimethylphosphine)bis(diphenylsilyl)platinum(II) with acetylenes , 1977 .

[66]  H. Bürger,et al.  Spirocyclische vanadium(iv)-silylamide , 1977 .

[67]  M. Kumada,et al.  PHOTOLYSIS OF ORGANOPOLYSILANES. FORMATION AND REACTIONS OF SUBSTITUTED 1-SILACYCLOPROPENE AND 1-SILA-1,2-PROPADIENE , 1977 .

[68]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. 68. Zur Lithinierung und Umlagerung Si-methylierter 1,3,5-Trisilacyclohexane , 1977 .

[69]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. 67. Untersuchungen zur metallorganischen Synthese Si-methylierter und C-chlorierter Carbosilane über Chlorcarbenoide , 1977 .

[70]  P. Jones,et al.  THE ADDITION OF TERT-BUTYLLITHIUM TO VINYLHALOSILANES. A NOVEL, HIGH YIELD ROUTE TO 1,3-DISILACYCLOBUTANES , 1977 .

[71]  G. Whitesides,et al.  Propane-1,3-di(magnesium halide) , 1977 .

[72]  Y. Nakadaira,et al.  Chemistry of organosilicon compounds. 98. Photochemical generation of silacyclopropene , 1977 .

[73]  S. C. Vick,et al.  The preparation of a 1,2-disilacyclobutane and a 1,2-disilacyclobut-3-ene by dimethylsilylene insertion into the silacyclopropane and silacyclopropene ring systems. New silacyclopropenes , 1977 .

[74]  S. C. Vick,et al.  Novel two atom insertions into the silacyclopropane and silacyclopropene rings , 1977 .

[75]  H. Baier,et al.  Heterocyclohexa-2,5-diene durch Kaliumhydroxid/[18]-Crown-6-katalysierte Cycloadditionen von Arylphosphinen, Arylarsinen und Dialkylstannanen an Hexa-1,4-diyne , 1977 .

[76]  G. Wilkinson,et al.  Interaction of magnesium dialkyls with binuclear transition metal acetates: crystal structure of bis(trimethylsilylmethyl)bis(trimethylphosphine) bis(µ-trimethylsilymethyl)-dichromium(II) , 1977 .

[77]  R. Whitley,et al.  Silacyclopentadiene complexes of molybdenum, chromium, iron, ruthenium, cobalt, and rhodium , 1977 .

[78]  G. Manuel,et al.  Synthese et reactivite de sila-1 cyclopentanols-2: formation d'oxa-1 sila-2 cyclohexanes par reaction d'extension de cycle , 1976 .

[79]  M. Anteunis,et al.  Preparation of (substituted) 3,3-dimethyl-3-sila-1-heterocyclohexanes , 1976 .

[80]  T. Barton,et al.  AN ALTERNATIVE MECHANISM FOR THE FORMATION OF 1,4-DISILACYCLOHEXA-2,5-DIENES FROM ACETYLENES AND SILYLENES , 1976 .

[81]  Y. Nakadaira,et al.  Chemistry of organosilicon compounds XCIV. Preparations of 8-silatricyclo[3.2.1.02,4]oct-6-enes, new photochemical silylene generators , 1976 .

[82]  M. Kumada,et al.  Photochemically generated silicon-carbon double-bonded intermidiates : II. Photolysis of aryldisilanes in the presence of dienes , 1976 .

[83]  Y. Nakadaira,et al.  Chemistry of organosilicon compounds. 93. New photochemical reactions of vinyldisilanes through silaethene or silacyclopropane intermediates , 1976 .

[84]  T. Aoyama,et al.  Synthesis and reactions of 1-substituted 3,3-dimethylbenzo[d]-1,3-azasilolines , 1976 .

[85]  D. Seyferth,et al.  Dimethylsilylene transfer from hexamethylsilirane to olefins , 1976 .

[86]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. 66. (H2SiCH2)2 und Si‐substituierte Derivate , 1976 .

[87]  Von G. Märkl,et al.  Cis,cis-1.5-dilithium-3-R-3-alkoxy-pentadiene-1.4 silacyclohexadiene-2.5 , 1976 .

[88]  S. C. Vick,et al.  1,1-Dimethyl-2,3-bis(trimethylsilyl)-1-silirene, a stable silacyclopropene , 1976 .

[89]  K. Tamao,et al.  Fluorinated polysilanes. palladium-catalyzed disilane metathesis, double silylation of acetylenes, and the stereo chemical course , 1976 .

[90]  M. Laguerre,et al.  Silylation d'hydrocarbures mono-aromatiques mono- ou disubstitues , 1976 .

[91]  D. Seyferth,et al.  Evidence for the generation of a disilacyclopropane in solution , 1976 .

[92]  W. Weber,et al.  Copyrolysis of sym-tetramethoxydimethyldisilane and 2,5-dimethylfuran , 1976 .

[93]  M. Kumada,et al.  Photolysis of organopolysilanes. Photochemical one-step synthesis of mono- and disubstituted silepins , 1976 .

[94]  N. Bhacca,et al.  Stereochemistry of reactions of silacyclobutanes , 1976 .

[95]  W. Fink Metall‐Bis(silyl)chelat‐Komplexe , 1976 .

[96]  G. Stucky,et al.  Molecular structure and bonding of a silacyclopropane, dimethyldispiro[bicyclo[4.1.0]heptane-7,2'-silacyclopropane-3',7''-bicyclo[4.1.0]heptane] , 1976 .

[97]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. LXIV. Untersuchungen zur Pyrolyse des C2H5SiCl3 , 1976 .

[98]  Toshi-aki Kobayashi,et al.  Chemistry of organosilicon compounds , 1976 .

[99]  H. Vogt,et al.  Bildung siliciumorganischer Verbindungen. LVIII. Die Synthese eines Carbosilans mit Propellan-Struktur , 1976 .

[100]  H. Shechter,et al.  Single-atom peri-bridged naphthalenes; 1,1-dialkylnaphtho[1,8-bc]siletes , 1976 .

[101]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen LXIII. Synthese und thermische Umlagerung des 1,1,3,3,4,4-Hexamethyl-1,3,4-trisilacyclopentan† , 1976 .

[102]  J. Yoshida,et al.  Novel Decomposition Modes of Transition Metal Metallocycles Containing the Silicon–Silicon Bond: 1‐Nickela‐ and 1‐Platina‐3,4‐Disilacyclopentane Ring Systems , 1976 .

[103]  A. G. Osborne,et al.  Silicon Bridged [1] ferrocenophanes , 1975 .

[104]  C. Cheng,et al.  CYCLOADDITION OF DISILACYCLOBUTENES IN THE PRESENCE OF NICKEL TETRACARBONYL , 1975 .

[105]  D. Seyferth,et al.  Generation of dimethylsilylene under mild conditions by the thermolysis of hexamethylsilirane , 1975 .

[106]  D. Seyferth The elusive silacyclopropanes; the preparation and properies of a long sought class of organosilicon compounds , 1975 .

[107]  W. Weber,et al.  Synthesis and pyrolysis of 1,1-dimethyl-2-phenyl-1-silacyclobut-2-ene , 1975 .

[108]  H. Shechter,et al.  The chemistry of trimethylsilylcarbene , 1975 .

[109]  R. Hoffmann,et al.  AUGMENTED SILICON-CARBON BOND STRENGTHS VIA D-SIGMA HYPERCONJUGATION , 1975 .

[110]  J. Dunogues,et al.  Acetylation de dimethyl-1,1 silacyclopentenes-3. Synthese de cetones ethyleniques β-siliciees , 1975 .

[111]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. LVII. Untersuchungen zur Umsetzung von (Cl3SiCCl2)2SiCl2 mit LiCH3 , 1975 .

[112]  P. Gaspar,et al.  Silylene additions to cyclopentadiene and 1,3-cyclohexadiene. Evidence for the addition mechanism , 1975 .

[113]  SakuraiHideki,et al.  NOVEL [σ+π] CYCLOADDITION OF SILACYCLOBUTANES WITH ACETYLENES CATALYZED BY PALLADIUM COMPLEXES , 1975 .

[114]  M. Kumada,et al.  Photochemical behavior of 2-phenylheptamethyltrisilane in the presence of alkenyltrimethylsilanes , 1975 .

[115]  W. Fink 1,1‐Dimethyl‐1‐silacyclohexa‐2,4‐dien‐tricarbonyleisen Vorläufige Mitteilung , 1975 .

[116]  D. Seyferth,et al.  Hexamethylsilirane. Simple, isolable silacyclopropane , 1975 .

[117]  P. Mariano,et al.  Photochemistry of di-.pi.-silanes , 1975 .

[118]  J. Maire,et al.  Sythese Et Structure Du Disila-5,6 Bispiro[4.0.4.4]Tetradecane , 1975 .

[119]  A. Brook,et al.  Synthesis of cyclic acylsilanes , 1975 .

[120]  J. D. Citron Preparation, resolution and dynamic stereochemistry of the 7H-7-methyl-7-silabenz[d,e]anthracene system , 1975 .

[121]  T. Barton,et al.  ADDITION OF N-CHLOROSULFONYL ISOCYANATE TO 1,1-DIMETHYL-2,5-DIPHENYL-1-SILACYCLOPENTA-2,4-DIENE , 1975 .

[122]  M. Kumada,et al.  A novel double silylation of dimethyl acetylenedicarboxylate catalyzed by phosphinepalladium(II) complexes , 1975 .

[123]  A. Bassindale,et al.  The mechanism of the β-ketosilane to siloxyalkene thermal rearrangement , 1975 .

[124]  M. Kumada,et al.  Photolysis of organopolysilanes. Insertion of silylene species into a conjugated diene , 1975 .

[125]  R. Balasubramanian,et al.  Alkali metal, alkaline and acidic decomposition of silacyclopentadienes , 1975 .

[126]  T. Barton,et al.  Pyrolysis of 1,1,2-trimethyl-1-silacyclobutane. Site of initial ring cleavage , 1975 .

[127]  H. Sakurai,et al.  Chemistry of organosilicon compounds. 79. Novel [.sigma. + .pi.]reactions of hexaorganodisilanes with acetylenes catalyzed by palladium complexes , 1975 .

[128]  T. Barton,et al.  Alleged intermediacy of a silacyclopropane in the pyrolysis of phenyltrimethylsilyldiazomethane , 1975 .

[129]  T. Barton,et al.  The addition of dimethylsilylene to cyclooctatetraene , 1975 .

[130]  T. Barton,et al.  Synthesis and chemistry of 9,9-dimethyl-9-silabicyclo[4.2.1]nona-2,4,7-triene , 1975 .

[131]  M. Newlands,et al.  Organosilicon chemistry. Part XVII. Some reactions of 1,1,3,3-tetramethyl-1,3-disilacyclobutane , 1975 .

[132]  A. E. Tipping,et al.  Organosilicon chemistry. Part XIX. Reactions of 1,1,3,3-tetramethyl- and 1,3-dimethyl-1,3-diphenyl-1,3-disilacyclobutane with chlorosilanes in the presence of hexachlorophatinic(IV) acid, tin(IV) chloride, trimethylsilanol, and triphenylsilanol , 1975 .

[133]  J. Pounds,et al.  A direct route to a novel tetraphenyldisilabicyclo[2.2.2.]octa-2,5-diene: a tetraphenyldisilene precursor , 1975 .

[134]  W. Weber,et al.  Synthesis of unsaturated organosilicon heterocycles - reaction of silylenes with cyclic dienes , 1975 .

[135]  M. Kumada,et al.  Photolysis of organopolysilanes. Evidences for the formation of silacyclopropane derivatives and photorearrangement of methylphenylsilacyclopropane to an isomeric olefin , 1974 .

[136]  R. Gooden,et al.  1‐OXA‐2‐SILACYCLOHEXANES, MECHANISM OF FORMATION FROM MAGNESIUM HALIDE CATALYZED REACTIONS OF SOME DICHLOROSILANES AND MAGNESIUM METAL IN TETRAHYDROFURAN , 1974 .

[137]  R. G. Salomon Facile one-step synthesis of 5-silaspiro[4.4]nona-2,7-diene , 1974 .

[138]  W. Weber,et al.  Pyrolytic and photochemical fragmentation of 1,1-dimethyl-2-phenyl-1-silacyclobutane , 1974 .

[139]  S. S. Washburne,et al.  Fragmentation of the silacyclohexane ring , 1974 .

[140]  J. Satge,et al.  Oxametallacycloalcanes : V. Synthese de sila-2, germa-2 et stanna-2 oxa-1 cyclopentanes par deshydrocondensation intramoleculaire d'hydrures silicies, germanies ou stanniques γ-hydroxyles , 1974 .

[141]  W. Weber,et al.  Unsaturated Organosilicon Heterocycles. , 1974 .

[142]  P. Gaspar,et al.  Stereochemistry of a silylene addition reaction , 1974 .

[143]  Y. Nakadaira,et al.  Photochemistry of 1,2-disila-3,5-cyclohexadienes , 1974 .

[144]  T. Koch,et al.  Photochemical rearrangement of 4,4-disubstituted-4-sila-2,5-cyclohexadienones , 1974 .

[145]  Y. Nakadaira,et al.  Photochemical isomerization of 1-sila-2,4-cyclohexadienes , 1974 .

[146]  H. Schmidbaur,et al.  Isomerization by Ring Expansion in Silylated Phosphorus Ylides , 1974 .

[147]  J. Barrau,et al.  Oxametallocycloalcanes et cycloalcenes , 1974 .

[148]  G. Zon,et al.  Synthesis of 3,4-Benzo-1,1,2,2-Tetramethyl-1,2-Disilacyclopentene , 1974 .

[149]  J. V. Swisher,et al.  Silicon heterocyclic compounds I. The synthesis of medium sized silacycloalkanes by a modified clemmensen reduction of silaacyloins , 1974 .

[150]  J. V. Swisher,et al.  Silicon heterocyclic compounds I. Ring size effect in ring closure by hydrosilation , 1974 .

[151]  T. Barton,et al.  Synthesis of 1,1-dimethyl-2,7-diphenyl-1-silacyclohepta-2,4,6-triene. Nonannulated silepin , 1974 .

[152]  N. Bhacca,et al.  Stereochemistry of chloride displacement from silacyclobutanes , 1974 .

[153]  Y. Nakadaira,et al.  Stereochemical course in the photochemistry of the 1,2,3-trisilacycloheptane system , 1974 .

[154]  B. Ramsey Electronic transitions of polysilanes and their photochemistry , 1974 .

[155]  W. Graham,et al.  Silicon-transition metal chemistry. VII. Metal carbonyl derivatives of 1,2-bis(dimethylsilyl)ethane , 1974 .

[156]  T. Dolzine,et al.  Intramolecular cyclization of dimethyl(1-pent-4-enyl)-silyllithium , 1974 .

[157]  W. Andō,et al.  Reactions of carboalkoxycarbenes with alkylsilanes , 1974 .

[158]  D. C. Bradley,et al.  4,4-Bis-(π-cyclopentadienyl)-2,2-dimethyl-1-trimethylsilylaza-2-sila-4-titanacyclobutane: a novel organometallic heterocycle , 1974 .

[159]  W. Fink Metall-π-Komplexe des 2, 5-Diphenyl-1-silacyclopentadiens , 1974 .

[160]  P. Mazerolles,et al.  Dihalogeno-6, 6 Sila-3 et Germa-3 Bicyclo [3.1.0] Hexanes: Synthese et Stabilite Thermique , 1974 .

[161]  P. Mazerolles,et al.  Influence du Solvant sur une Reaction d'Heterocyclisation a Partir des Dichlorosilanes: Synthese de Nouveaux Sila-1 Cyclopentenes-3 , 1974 .

[162]  C. Cheng,et al.  Chelate compound with silicon atoms as ‘donors’ , 1974 .

[163]  P. Mazerolles,et al.  Stereochimie d'heterocycles du groupe IVB—II , 1974 .

[164]  T. Kauffmann,et al.  Sila-thiopheno-protophane und -phane , 1974 .

[165]  C. Eaborn,et al.  Some platinum complexes containing chelating bis(silyl) ligands , 1973 .

[166]  H. Sakurai,et al.  Preparation and some properties of silacyclopentadiene complexes of cobalt , 1973 .

[167]  J. Y. Corey,et al.  Organosilicon heterocycles from ring expansion reactions , 1973 .

[168]  L. Birkofer,et al.  1,1,2,2‐Tetramethyl‐1,2‐disila‐4‐cyclohexen , 1973 .

[169]  P. Mazerolles,et al.  Synthése de disila-1,2 (et digerma-1,2) cyclohexénes-4 , 1973 .

[170]  L. Birkofer,et al.  Preliminary communicationSiliciumorganische Verbindungen : LIV. 1,1-Diorgano-2-vinyl-sila-3-cyclopentene aus 1,3,4-Hexatrien und diorganodichlorsilanen , 1973 .

[171]  P. Mazerolles,et al.  Passage des β aux α-silacyclopentènes , 1973 .

[172]  G. Fritz,et al.  Carbosilanes Having a New Silicon‐Carbon Skeleton (“Silascaphanes”) , 1973 .

[173]  J. Connolly,et al.  A novel ring-opening reaction of 2,2-dimethyl-2-silabicyclo[3.1.0]hexane , 1973 .

[174]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. LI. Reaktionen verschieden chlorierter 1,3,5‐Trisila‐cyclohexane mit CH 3TMgCl und ihre 29SiNMR‐Spektren , 1973 .

[175]  G. Fritz,et al.  Carbosilane mit neuem Silicium‐Kohlenstoff‐Gerüst ( „Silascaphane”︁) , 1973 .

[176]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. L. Untersuchungen zur Hydrierung, Methylierung und Spaltung des Octachloro-hexasila-asterans Si6Cl8C6H8† , 1973 .

[177]  W. H. Atwell,et al.  Preparation of hexamethyl-1,2-disila-3-cyclobutene , 1973 .

[178]  H. Schmidbaur,et al.  Anormale Silacyclobutan‐Ringöffnung durch Alkyliden‐trialkylphosphorane , 1973 .

[179]  J. Dubac,et al.  The insertion of phenyl(bromodichloromethyl)mercury-derived dichlorocarbene into the SiC(ring) and βCH bonds of the cis and trans isomers of 1,3-dimethyl-1-n-butyl-1-silacyclobutane , 1973 .

[180]  J. Eisch,et al.  Chemistry of alkali metal-unsaturated hydrocarbon adducts IX. Radical-anionic coupling of group IV organometalloidal compounds , 1973 .

[181]  L. H. Sommer,et al.  Facile reactions of functionally substituted 1,3,5,7-tetrasilaadamantanes with nucleophilic reagents , 1973 .

[182]  Louise L. Roseman,et al.  Hydrolytic and themal decomposition studies of some 7-silanorbornadienes , 1973 .

[183]  L. H. Sommer,et al.  Dramatic stereochemistry crossover to retention of configuration with angle-strained asymmetric silicon , 1973 .

[184]  Z. Lasocki Silylation of Cycloaliphatic Vicinal Diols , 1973 .

[185]  J. Pola,et al.  Organosilicon compounds. XCVII. Cyclization of terminal ethoxysilyl-substituted propoxy- and butoxymethylsilanes , 1973 .

[186]  L. H. Sommer,et al.  Photochemical generation of an intermediate containing a silicon-carbon double bond or its equivalent from 1,1-diphenylsilacylobutane , 1973 .

[187]  N. L. Allinger,et al.  On the inversion barriers in the di- and tri-benzosilepins , 1973 .

[188]  R. Balasubramanian,et al.  Symmetry allowed π4s+π2s additions silacyclopentadienes , 1973 .

[189]  T. Barton,et al.  Convenient Synthesis of 1,1-Dimethyl-2, 5-Diphenyl-1-Silacyclopentadiene , 1973 .

[190]  A. Krebs,et al.  Untersuchungen über gespannte cyclische acetylene, VI Nachweis des 1,1-dimethylsila-4-cycloheptins , 1973 .

[191]  Y. Nakadaira,et al.  Synthesis and oxidation of 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,4-cyclohexadiene , 1973 .

[192]  R. Fessenden,et al.  Silicon heterocyclic compounds. Ring closure by hydrosilation , 1973 .

[193]  D. Seyferth,et al.  Substituted 7-siladispiro[2.0.2.1]heptanes. The first stable silacyclopropanes , 1972 .

[194]  M. Kumada,et al.  Dichlorobis(triethylphosphine)nickel(II) as a catalyst for reactions of sym-tetramethyldisilane with unsaturated hydrocarbons. Novel synthetic routes to 1-silacyclopentadienes and 1,4-bis(dimethylsilyl)2-butenes , 1972 .

[195]  T. Barton,et al.  2,3-Bis(trifluoromethyl)-7,7-dimethyl-7-silabicyclo[2.2.2] octa-2,5-diene. A silaalkene generator. , 1972 .

[196]  D. N. Roark,et al.  Reactions of 7,8-disilabicyclo[2.2.2]octa-2,5-dienes. Evidence for the transient existence of a disilene , 1972 .

[197]  T. Barton,et al.  Thermal decomposition of 1,4-diphenyl-2,3-bis(trifluoromethyl)-7-dimethylsilabicyclo[2.2.1]heptadiene , 1972 .

[198]  E. Janzen,et al.  Chemiluminescence in the oxidation of phenyl-substituted silole radical anions and dianions , 1972 .

[199]  L. Birkofer,et al.  3.3‐Dimethyl‐3H‐3‐benzosilepin und 3H‐3‐Benzosilepin , 1972 .

[200]  H. Sakurai,et al.  New conformationally stable 4-tert-butyl-1-silacyclohexanes and stereochemistry of insertion of dimethylsilylenes into the silicon-hydrogen bond , 1972 .

[201]  J. Clardy,et al.  Heterocyclopentadienes. II. Reaction of benzenediazonium-2-carboxylate with 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene , 1972 .

[202]  J. Y. Corey,et al.  Synthesis and characterization of 10,11-dihydro-5H-dibenzo[b,f]metallepins of group IV , 1972 .

[203]  J. Thompson,et al.  Reactions of Silicon Difluoride with Unsaturated Organic Compounds. Part II. Alkyl Substituted Alkynes , 1972 .

[204]  M. Lappert,et al.  2,2-Dimethyl-1,1,1,1-tetracarbonyl-1-ferra-2-silacyclopentane: insertion of [Fe(CO)4] into a strained organosilicon ring , 1972 .

[205]  J. Clardy,et al.  A novel solid-state molecular complex of diphenylacetylene and 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene , 1972 .

[206]  P. Mazerolles,et al.  Silylation d'alcools et d'amines par les dimethyl-1,2 (et dimethyl-1,3) chloro-1 sila-1 cyclobutanes: synthese de silacyclobutanes a stereoisomere preferentiel. , 1972 .

[207]  D. Terunuma,et al.  The Synthesis of Silacyclopentane Derivatives , 1972 .

[208]  J. Y. Corey,et al.  9,9-Dimethyl-9H-tribenzo [b,d,f]silepin: A stereochemically rigid silicon heterocycle , 1972 .

[209]  J. Y. Corey Substituted 5-Phenyl-10,11-dihydrodibenzo[b,f]silepins and Reactions at the 10,11-Positions , 1972 .

[210]  E. Rosenberg,et al.  The synthesis of 2-silanorcaranes , 1971 .

[211]  R. Laine,et al.  Transannular interactions of the silyl center with distant keto groups in the mass spectra of medium-sized organosilicon heterocycles. Improved synthetic routes to six-, seven-, and eight-membered silicon ring systems , 1971 .

[212]  T. J. Barton,et al.  1,1-Dimethyl-1-sila-2,3:6,7-dibenzocycloheptatriene. A dibenzosilepin , 1971 .

[213]  L. Birkofer,et al.  Siliciumorganische Verbindungen XXXXVII. 3,3-Dimethyl-3-silabicyclo[3.2.0]heptan , 1971 .

[214]  Tamio Sato,et al.  The Polymerization of Silacyclopentene and -pentane Derivatives , 1971 .

[215]  R. R. Chawla,et al.  Fragmentation of the silacyclohexane ring. Solvolysis of 4-tosyl-1, 1-dimethyl-1-silacyclohexane , 1971 .

[216]  J. Connolly,et al.  Intramolecular reactions of (alkenyldimethylsilyl)carbenes , 1971 .

[217]  K. Tamao,et al.  Silicon-containing heterocyclic compounds , 1971 .

[218]  R. Damrauer,et al.  Halomethyl metal compounds. XLIV. Reactions of phenyl (bromodichloromethyl) mercury derived dichlorocarbene with silacyclobutanes. Novel ring expansion reaction , 1971 .

[219]  G. Manuel a- et -silacyclopentanols , 1971 .

[220]  W. Pringle Microwave Spectrum, Vibration–Rotation Interaction, and Ring Puckering Vibration in Silacyclobutane and Silacyclobutane‐1,1‐d2 , 1971 .

[221]  R. Maruca Reaction of 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene with diphenylacetylene, 2,3-dimethyl-1,3-butadiene, and benzyne , 1971 .

[222]  F. Wudl,et al.  Dodecamethyldioxa[1.1]di-p-disilinocyclophane. Novel organosilicon cyclophane , 1971 .

[223]  P. Jutzi 9‐Sila‐, ‐Germa‐ und ‐Stanna‐dihydroanthracene , 1971 .

[224]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. LXII. Teilbromierte Carbosilane , 1971 .

[225]  J. Y. Corey,et al.  Synthesis of dibenzo[b, f]silepins , 1971 .

[226]  F. K. Cartledge,et al.  5,5-dimethyl-5H-dibenzo[b,f]silepin: A 14π-electron silicon heterocycle , 1971 .

[227]  G. Märkl,et al.  Eine einfache synthese von silacyclohexadienen [Ein Beitrag zum Problem des Silabenzols] , 1971 .

[228]  M. Lesbre,et al.  Cycloaddition de dienophiles organometalliques au dimethyl-1,1 diphenyl-2,5 silacyclopentadiene , 1971 .

[229]  L. Birkofer,et al.  3,3-Dichlor-3H-3-benzosilepin☆ , 1970 .

[230]  M. Lesbre,et al.  Sultones organométalliques : IV. Réactions de sulfonation en série silacyclobutanique , 1970 .

[231]  M. Joly,et al.  Preliminary communicationSultones et sultines organométalliques V. Réactions d'insertion de l'anhydride sulfureux dans la liaison siliciumcarbone: sultines organosiliciques , 1970 .

[232]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. XXXVI. Reaktionen von Disilyläthinen mit R2AlH (Cyclierung von Carbosilanen) , 1970 .

[233]  J. Laane Vibrational spectra and normal-coordinate analyses of silacyclobutanes , 1970 .

[234]  D. Seyferth,et al.  1,1,3,3-tetramethyl-1,3-disilacyclobutane and 1,1,3,3-Tetra- methyl-1-sila-3-germacyclobutane via active metal derivatives of bis(chloromethyl)dimethylsilane , 1970 .

[235]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen. XXX. Metallorganische Synthese cyclischer Carbosilane , 1970 .

[236]  M. Curtis,et al.  Synthesis and reactions of some functionally substituted sila- and germacyclopentadienes , 1969 .

[237]  L. Birkofer,et al.  3.3-Diphenyl-3H-3-benzosilepin , 1969 .

[238]  L. Birkofer,et al.  1.2.4.5‐Tetrahydro‐3H‐3‐benzosilepine , 1969 .

[239]  Toru Sato,et al.  Photochemistry of organometallic compounds. II Photooxygenation reaction of silole derivatives. , 1969 .

[240]  M. Kumada,et al.  Silyl radicals V : Novel cyclization reactions involving homolytic aromatic silylation , 1969 .

[241]  W. H. Atwell,et al.  Silylene chemistry. I. The thermolysis of methoxypolysilanes , 1968 .

[242]  L. Nelson,et al.  Disilylation of conjugated dienes. Configuration of diene anion radicals annd dianions , 1968 .

[243]  Stanley G. Smith,et al.  The Preparation and Properties of Cyclic Six-Membered Silicon Compounds , 1968 .

[244]  G. Fritz,et al.  Umsetzung von Perchlor-1,3,5-trisilacyclohexan mit Methylmagnesium-chlorid , 1967 .

[245]  M. Rausch,et al.  Heterocyclic metallo-indene systems , 1967 .

[246]  M. Kumada,et al.  Some ferrocene-substituted carbosilanes , 1967 .

[247]  D. Walton,et al.  Organosilicon compounds : XL. Rates of ring-opening of some benzosilacycloalkenes , 1967 .

[248]  K. Tamao,et al.  Silicon-containing heterocyclic compounds I. Preparation and reactions of 1,1,2,2,-tetramethyl-1,2-disilacycloalkanes, from disilacyclopentane to disilacyclooctane , 1967 .

[249]  H. Gilman,et al.  Silacyclopentadiene chemistry. I. 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene , 1967 .

[250]  R. Damrauer,et al.  Insertion of CCl2into the Silicon-Carbon Bond of Silacyclobutanes , 1967 .

[251]  J. Laane Synthesis of Silacyclobutane and Some Related Compounds , 1967 .

[252]  R. A. Benkeser,et al.  Synthesis and properties of seven-, eight-, and nine-membered silicon ring systems , 1967 .

[253]  V. Chvalovský,et al.  Organosilicon compounds. L. Pyrolysis of phenyldimethylsilane , 1967 .

[254]  C. Pitt,et al.  The preparation and isomerization of monocyclic silyhydrazines , 1966 .

[255]  D. Seyferth,et al.  CCl2 insertion into tetraalkyl-silicon and -tin compounds via phenyl (bromodichloromethyl)mercury , 1966 .

[256]  D. Stump,et al.  Silicon-Fluorine Chemistry. IV. The Reaction of Silicon Difluoride with Aromatic Compounds , 1966 .

[257]  W. A. Kriner Catalytic polymerization of 1,3‐disilacyclobutane derivatives , 1966 .

[258]  G. Sonntag,et al.  Bildung siliciumorganischer Verbindungen. XXIII. Untersuchungen zur Struktur des Si2C7H16 aus der Pyrolyse des Si(CH3)4 (1,1,3,3‐Tetramethyl‐1,3‐disilacyclopenten) , 1966 .

[259]  D. R. Weyenberg,et al.  The Disilylation of Styrene and α-Methylstyrene. The Trapping of Short-Lived Intermediates from Alkali Metals and Aryl Olefins1 , 1965 .

[260]  R. A. Benkeser,et al.  The preparation and properties of cyclic silicon olefins and diene systems , 1965 .

[261]  A. Brook,et al.  1,1-Diphenylsila-2-cyclohexanone1 , 1965 .

[262]  D. R. Weyenberg,et al.  Platinum-Catalyzed Reactions of Silacyclobutanes and 1,3-Disilacyclobutanes , 1965 .

[263]  H. Gilman,et al.  Small-Ring Organosilicon Compounds. III. 1,1,2-Triphenyl-1-silacyclobut-2-ene and 1,1,2-Triphenyl-1-silacyclopent-2-ene , 1965 .

[264]  H. Gilman,et al.  2:3-Benzo-1-silacycloalkenes. II. Improved Syntheses and Reactions , 1965 .

[265]  H. Gilman,et al.  Some Diels-Alder Adducts of 1,1,2,3,4,5-Hexaphenyl-1-silacyclopentadiene , 1964 .

[266]  H. Gilman,et al.  Small-Ring Organosilicon Compounds. II. 2:3-Benzo-1,1-diphenyl-1-silacyclobut-2-ene , 1964 .

[267]  H. Gilman,et al.  Synthesis of 2:3-Benzo-1-silacycloalkenes. I , 1964 .

[268]  H. Gilman,et al.  A preparation of 1,1,3,3-tetramethyl-1,3-disilacyclobutane , 1964 .

[269]  R. Fessenden,et al.  Silicon Heterocyclic Compounds. II. Synthesis of 3-Sila-1-heterocycloheptanes1 , 1964 .

[270]  H. Gilman,et al.  Small-Ring Organosilicon Compounds. I. A Comparison of the Reactivities of 1,1,2-Triphenyl-1-silacyclobutane and 1,1,2-Triphenyl-1-silacyclopentane , 1964 .

[271]  P. Gund,et al.  The Synthesis of Cyclic Silicon Systems , 1964 .

[272]  W. A. Kriner The Preparation of Cyclic Siliconmethylene Compounds , 1964 .

[273]  R. Fessenden,et al.  Silicon Heterocyclic Compounds. I. Synthesis of the 3-Sila-1-heterocyclohexanes1 , 1964 .

[274]  Von Gerd Rossmy,et al.  1,2—Siloxacycloalkane 1. Mitt. Synthese und polymerisationsverhalten , 1964 .

[275]  H. Gilman,et al.  The Preparation and Reactions of Some 7-Silanorbornadienes. I. An Approach to Dimethylsilylene , 1964 .

[276]  W. Müller,et al.  Über Silikone, LXXXII. Über Trichlorsilylgruppen enthaltende 1.3‐Disilacyclobutane , 1964 .

[277]  O. Nefedow,et al.  Entstehung und Reaktionen des Dimethylsilylens, eines Siliciumanalogons der Carbene , 1964 .

[278]  O. M. Nefedov,et al.  The Formation and Reactions of Dimethylsilylene, a Silicon-Analogue of the Carbenes , 1964 .

[279]  R. Bailey,et al.  The Nature of “Silirene” Compounds , 1963 .

[280]  G. Fritz,et al.  Bildung siliciumorganischer Verbindungen, XIX. Metallorganische Synthese Si‐funktioneller Cyclocarbosilane , 1963 .

[281]  G. Sonntag,et al.  Bildung siliciumorganischer Verbindungen. XVIII Zur Konstitution des Si2C6H16 aus der Pyrolyse des Si(CH3)4 , 1963 .

[282]  T. Kalmár,et al.  Dehydrierung von 1.1‐Dimethyl‐cyclotetramethylensilan , 1962 .

[283]  H. Gilman,et al.  5,10-Dihydrosilanthrene Derivatives , 1962 .

[284]  M. E. Vol’pin,et al.  Three-membered heteroaromatic compounds—I☆ , 1962 .

[285]  E. Braye,et al.  New Unsaturated Heterocyclic Systems. I , 1961 .

[286]  A. Smith,et al.  1,3,5,7-TETRACHLORO-1,3,5,7-TETRASILA-ADAMANTANE , 1961 .

[287]  R. Fessenden,et al.  Notes- The Use of Organodilithium Compounds for the Synthesis of 1,1-Dimethylsilacyclopentane and 1,1-Dimethylsilacyclohexane. , 1961 .

[288]  H. Gilman,et al.  o-Phenylene Silicon Derivatives. Dihydrosilanthrene and Related Compounds1 , 1960 .

[289]  H. Gilman,et al.  The Aluminum Chloride-catalyzed Intramolecular Cyclization of Some Organosilicon Compounds. Studies in the Benzosilacyclanone Series , 1960 .

[290]  L. H. Sommer,et al.  REACTIVITY AT BRIDGEHEAD SILICON. II. 1-SILABICYCLO [2.2.2] OCTANE , 1959 .

[291]  H. Gilman,et al.  Cyclic Organosilicon Compounds. II. Reactions Involving Certain Functional and Related Dibenzosilole Compounds , 1958 .

[292]  H. Gilman,et al.  An Intramolecular Cleavage-Cyclization Reaction of Silicon-containing Organolithium Compounds , 1958 .

[293]  H. Gilman,et al.  Cyclic Organosilicon Compounds. I. Synthesis of Compounds Containing the Dibenzosilole Nucleus , 1958 .

[294]  L. H. Sommer,et al.  STEREOCHEMISTRY OF HYDRIDE ION DISPLACEMENT FROM SILICON. ENHANCED RATES AT BRIDGEHEAD AND 4-RING SILICON ATOMS1 , 1957 .

[295]  L. H. Sommer,et al.  STEREOCHEMISTRY OF SUBSTITUTION AT A SILICON ATOM. BRIDGEHEAD ORGANOSILICON COMPOUNDS1 , 1957 .

[296]  E. G. Rochow,et al.  The Preparation of Chloromethyl Derivatives of Germanium and Silicon by the Diazomethane Method , 1955 .

[297]  R. West Cyclic Organosilicon Compounds. I. Preparation of Cyclic Silanes , 1954 .

[298]  L. H. Sommer,et al.  A SILICON-CONTAINING 4-RING , 1954 .

[299]  A. Bygdén Über einige heterocyclische Organosilicium-Verbindungen , 1915 .