Enhancements in ElectroKinetic Remediation Technology: Environmental assessment in comparison with other configurations and consolidated solutions

Abstract The extraction of contaminants from an earthy matrix using the ElectroKinetic Remediation Technology (EKRT) requires suitable electric fields to be applied through the soil. In some cases, the further addition of appropriate chemicals helps the dissolution and thus the removal of the pollutants. EKRT has the potential to achieve results similar to other on-site and/or off-site interventions, but with substantially higher levels of acceptability, thus representing a very interesting approach in dealing with contamination by heavy metals. However, due to the use of consumable materials and basically high energy consumption, this technology can heavily impact on the environment, if non appropriately configured. In this study, the electrokinetic approach for the remediation of a multi-metal contaminated real site in terms of environmental assessment has been investigated by using the GaBi LCA software, to demonstrate that, in spite of expectation, a suitable system configuration can make this technology an excellent choice also in terms of environmental sustainability. The environmental assessment was conducted in terms of Global Warming Potential (GWP-100 years): the proposed technology has been compared with a different EKRT configuration taken from the literature, and the environmental impact evaluated against that of a conventional treatment, i.e. the excavation and disposal of contaminated soil in landfill. Despite the different configuration, the results show the advantages of the EKRT and in particular, how the specific improvements introduced are effective for reducing the ecological footprint. Moreover, having decreased the impacts related to the installation of the system above all, its simple coupling with alternative solutions for the production of energy could further increase the advantages of the approach, bringing the intervention to very high levels of environmental sustainability.

[1]  B. Grgur,et al.  Electrochemical oxidation of iodide in aqueous solution , 2006 .

[2]  K. Baek,et al.  Field Application of In Situ Electrokinetic Remediation for As-, Cu-, and Pb-Contaminated Paddy Soil , 2013, Water, Air and Soil Pollution.

[3]  J. Duruibe,et al.  Heavy metal pollution and human biotoxic effects , 2007 .

[4]  A. Alshawabkeh,et al.  Pilot-scale electrokinetic treatment of a Cu contaminated red soil. , 2006, Chemosphere.

[5]  Do-Hyung Kim,et al.  Environmental assessment on electrokinetic remediation of multimetal-contaminated site: a case study , 2014, Environmental Science and Pollution Research.

[6]  S. Morais,et al.  A perspective on LCA application in site remediation services: critical review of challenges. , 2010, Journal of hazardous materials.

[7]  D. Rahner,et al.  Electrochemically induced reactions in soils—a new approach to the in-situ remediation of contaminated soils?: Part 1: The microconductor principle , 2002 .

[8]  Yalcin B. Acar,et al.  Principles of electrokinetic remediation , 1993 .

[9]  Roberto Bagatin,et al.  Electrokinetic remediation of soils polluted by heavy metals (mercury in particular) , 2015 .

[10]  L. Ottosen Electrokinetics in the Removal of Metal Ions from Soils , 2014 .

[11]  S. Ferro Electrokinetic Barriers for Preventing Groundwater Pollution , 2014 .

[12]  Hans-Jürgen Dr. Klüppel,et al.  The Revision of ISO Standards 14040-3 - ISO 14040: Environmental management – Life cycle assessment – Principles and framework - ISO 14044: Environmental management – Life cycle assessment – Requirements and guidelines , 2005 .

[13]  Reinout Lageman,et al.  Electroreclamation. Applications in the Netherlands , 1993 .

[14]  Andrea P. Reverberi,et al.  Boron removal from water: needs, challenges and perspectives , 2014 .

[15]  A. Alshawabkeh,et al.  Bench- and field-scale evaluation of chromium and cadmium extraction by electrokinetics. , 2004, Journal of hazardous materials.

[16]  R. J. Gale,et al.  Optimization of 2-D Electrode Configuration for Electrokinetic Remediation , 1999 .

[17]  R. J. Gale,et al.  Electrokinetic remediation: Basics and technology status , 1995 .

[18]  Jeong‐Hee Choi,et al.  Pilot-scale study on in situ electrokinetic removal of nitrate from greenhouse soil , 2011 .

[19]  Ajay K. Dalai,et al.  Occurrence and Removal of Antiviral Drugs in Environment: A Review , 2013, Water, Air, & Soil Pollution.

[20]  G. Lemming Environmental assessment of contaminated site remediation in a life cycle perspective , 2010 .