Orientation dependence of HgCdTe epitaxial layers grown by MOCVD on Si substrates

Orientation dependence of HgCdTe epilayers grown by MOCVD on Si substrates was studied. Substrate orientation is considered to be one of the most sensitive factors to enable hetero-epitaxial growth on silicon substrates, especially in the case of a low temperature growth process. The present work was carried out with characterized features of a low temperature process for HgCdTe growth on Si and using a thin CdTe buffer layer. The (100), (100) misoriented toward [110], (311), (211), (111), and (331) oriented Si substrates were used in the present work. The best results were obtained on (211)Si substrates with an x-ray full width at half maximum of 153 arc sec for a 5 (im thickness HgCdTe layer and 69 arc sec for a 10 um thickness layer. It was found that the effective lattice mismatch of CdTe/Si heterosystem was reduced to 0.6% (for the 611 lattice spacing of CdTe and 333 spacing of Si) in the case of (133)CdTe/(211)Si.

[1]  J. W. Matthews,et al.  Effect of coherency strain and misfit dislocations on the mode of growth of thin films , 1975 .

[2]  H. Lewerenz,et al.  In situ preparation of hydrogen-terminated silicon single-crystal surfaces , 1992 .

[3]  D. B. Fenner,et al.  Silicon surface passivation by hydrogen termination: A comparative study of preparation methods , 1989 .

[4]  S. Sivananthan,et al.  Current status of direct growth of CdTe and HgCdTe on silicon by molecular‐beam epitaxy , 1992 .

[5]  Michael Schenk,et al.  New defect etchants for CdTe and Hg1-xCdxTe , 1990 .

[6]  L. Sugiura,et al.  Effects of growth rate and mercury partial pressure on twin formation in HgCdTe (111) layers grown by metalorganic chemical vapor deposition , 1993 .

[7]  J. W. Matthews,et al.  Defects in epitaxial multilayers: I. Misfit dislocations* , 1974 .

[8]  G. S. Higashi,et al.  Infrared spectroscopy of Si(111) and Si(100) surfaces after HF treatment: Hydrogen termination and surface morphology , 1989 .

[9]  R. Solanki,et al.  Ultraviolet photon‐assisted heteroepitaxy of CdTe and Hg1−xCdxTe on GaAs/Si substrates , 1989 .

[10]  R. Sporken,et al.  Molecular‐beam epitaxy of CdTe on large area Si(100) , 1991 .

[11]  G. B. Stringfellow Organometallic Vapor-Phase Epitaxy: Theory and Practice , 1989 .

[12]  N. Ōtsuka,et al.  Origin of dual epitaxy in the growth of CdTe on (211) GaAs , 1992 .

[13]  Kenneth R. Zanio HgCdTe on Si for hybrid and monolithic FPAs , 1990, Defense, Security, and Sensing.

[14]  J. Bajaj,et al.  Material characteristics of metalorganic chemical vapor deposition Hg1-xCdxTe/GaAs/Si , 1990 .

[15]  L. Sugiura,et al.  Lattice relaxation in large mismatch systems of (111)CdTe/(100)GaAs and (133)CdTe/(211)GaAs layers , 1994 .