Spark ignited hydrogen/air mixtures: two dimensional detailed modeling and laser based diagnostics

This study reports a detailed 2-D model which describes the spark ignition of an initially quiescent hydrogen/air mixture. The model includes the compressible Navier-Stokes equations, detailed chemistry and molecular transport in the gas phase as well as heat conduction to the electrodes. The spark is modeled for the phases subsequent to breakdown using the Maxwell equations for quasi-stationary conditions for the electric field. Initial and boundary conditions necessary for the simulations are chosen in accordance with experimental values. Heat conduction to the electrodes and different electrode shapes are investigated. The influence of these parameters on the shape of the initial flame kernel is discussed and compared qualitatively to experimental results. Spark ignition experiments are performed using a highly reproducible ignition system. Shapes of the early flame kernels are monitored by 2-D laser-induced fluorescence (PLIF) imaging of OH radicals produced during the ignition and the combustion process. The investigations are performed for different equivalence ratios. In addition, for a central position within the flame kernel, temperatures are measured at different times after ignition using vibrational coherent anti-Stokes Raman spectroscopy (CARS) of nitrogen.

[1]  Eran Sher,et al.  On the birth of spark channels , 1992 .

[2]  J. Heywood,et al.  From Spark Ignition to Flame Initiation , 1995 .

[3]  K. Kohse-Höinghaus Laser techniques for the quantitative detection of reactive intermediates in combustion systems , 1991 .

[4]  Derek Bradley,et al.  Spark ignition of turbulent gases , 1982 .

[5]  W. F. Noh Errors for calculations of strong shocks using an artificial viscosity and artificial heat flux , 1985 .

[6]  P. Ewart A modeless, variable bandwidth, tunable laser , 1985 .

[7]  A. Leipertz,et al.  Evaluation of two different gas temperatures and their volumetric fraction from broadband N(2) coherent anti-Stokes Raman spectroscopy spectra. , 1995, Applied optics.

[8]  A. Eckbreth Laser Diagnostics for Combustion Temperature and Species , 1988 .

[9]  Ulrich Maas,et al.  Ignition processes in hydrogenoxygen mixtures , 1988 .

[10]  Jonathan Dale,et al.  Application of high energy ignition systems to engines , 1997 .

[11]  M. Cottereau,et al.  Direct measurement of OH local concentration in a flame from the fluorescence induced by a single laser pulse. , 1979, Applied optics.

[12]  D. Snelling,et al.  Estimation of spatial averaging of temperatures from coherent anti-Stokes Raman spectroscopy. , 1996, Applied optics.

[13]  C. Kaminski,et al.  High repetition rate planar laser induced fluorescence of OH in a turbulent non-premixed flame , 1999 .

[14]  A. Dreizler,et al.  Time and spatially resolved LIF of OH A2Σ+(v′=1) in atmospheric-pressure flames using picosecond excitation , 1993 .

[15]  Eran Sher,et al.  Numerical modeling of spark ignition and flame initiation in a quiescent methane-air mixture , 1994 .

[16]  Myung Taeck Lim,et al.  Prediction of spark kernel development in constant volume combustion , 1987 .

[17]  G. Smallwood,et al.  Precision of multiplex CARS temperatures using both single-mode and multimode pump lasers. , 1987, Applied optics.

[18]  J. Boquillon,et al.  Spatial averaging and multiplex coherent anti-Stokes Raman scattering temperature-measurement error. , 1988, Optics letters.

[19]  D. Snelling,et al.  Noise in single-shot broadband coherent anti-Stokes Raman spectroscopy that employs a modeless dye laser. , 1994, Applied optics.

[20]  C. Kaminski,et al.  Characterisation of a spark ignition system by planar laser-induced fluorescence of OH at high repetition rates and comparison with chemical kinetic calculations , 2000 .

[21]  J. B. Cole,et al.  CARS measurements in an internal combustion engine. , 1979, Applied Optics.

[22]  M. Akram Two-Dimensional Model for Spark Discharge Simulation in Air , 1996 .

[23]  Alan C. Eckbreth,et al.  BOXCARS: Crossed‐beam phase‐matched CARS generation in gases , 1978 .