Electrochemical Properties of NaTi2(PO4)3 Anode for Rechargeable Aqueous Sodium-Ion Batteries

The charge/discharge characteristics of NaTi2(PO4)3 as an anode active material for aqueous sodium-ion battery containing 2 M Na2SO4 aqueous electrolyte were examined. Cyclic voltammograms, galvanostatic discharge/charge and XRD data of the material indicated that sodium can be reversibly intercalated into NASICON-type NaTi2(PO4)3 without serious degradation of the host structure. The best reversible capacity at rate of 2.0 mA cm−2 was 93% of the theoretical capacity of 133 mAh g−1 and the plateau voltage was 2.1 V versus Na/Na+.

[1]  Donghan Kim,et al.  Enabling Sodium Batteries Using Lithium‐Substituted Sodium Layered Transition Metal Oxide Cathodes , 2011 .

[2]  P. He,et al.  Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte. , 2010, Nature chemistry.

[3]  Yi Cui,et al.  Recent results on aqueous electrolyte cells , 2010 .

[4]  B. Scrosati,et al.  Lithium batteries: Status, prospects and future , 2010 .

[5]  J. Yamaki,et al.  Electrochemical properties of rechargeable aqueous lithium ion batteries with an olivine-type cathode and a Nasicon-type anode , 2009 .

[6]  Jun-ichi Yamaki,et al.  Mechanochemical synthesis of NaMF3 (M = Fe, Mn, Ni) and their electrochemical properties as positive electrode materials for sodium batteries , 2009 .

[7]  Kathryn E. Toghill,et al.  A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries. , 2007, Nature materials.

[8]  Chaoyang Wang,et al.  Power and thermal characterization of a lithium-ion battery pack for hybrid-electric vehicles , 2006 .

[9]  L. T. Lam,et al.  Development of ultra-battery for hybrid-electric vehicle applications , 2006 .

[10]  Thomas A. Stuart,et al.  An ultracapacitor circuit for reducing sulfation in lead acid batteries for Mild Hybrid Electric Vehicles , 2006 .

[11]  Ilias Belharouak,et al.  Safety characteristics of Li(Ni0.8Co0.15Al0.05)O2 and Li(Ni1/3Co1/3Mn1/3)O2 , 2006 .

[12]  C. Galven,et al.  Synthesis of nanostructured LiTi2(PO4)3 powder by a Pechini-type polymerizable complex method , 2006 .

[13]  Yongyao Xia,et al.  A new concept hybrid electrochemical surpercapacitor: Carbon/LiMn2O4 aqueous system , 2005 .

[14]  Karim Zaghib,et al.  LiFePO4/polymer/natural graphite: low cost Li-ion batteries , 2004 .

[15]  Irene M. Plitz,et al.  A comparative study of Li-ion battery, supercapacitor and nonaqueous asymmetric hybrid devices for automotive applications , 2003 .

[16]  Joachim Köhler,et al.  LiV3O8: characterization as anode material for an aqueous rechargeable Li-ion battery system , 2000 .

[17]  Charles R. Martin,et al.  Rate Capabilities of Nanostructured LiMn2 O 4 Electrodes in Aqueous Electrolyte , 2000 .

[18]  P. C Frost,et al.  Developments in lead–acid batteries: a lead producer's perspective , 1999 .

[19]  Paul A. Nelson,et al.  Development of a high-power lithium-ion battery , 1998 .

[20]  D. H. Bradhurst,et al.  Secondary aqueous lithium-ion batteries with spinel anodes and cathodes , 1998 .

[21]  G. Rigobert,et al.  Lithium-ion batteries for electric vehicles: performances of 100 Ah cells , 1997 .

[22]  Jeff Dahn,et al.  Lithium‐Ion Cells with Aqueous Electrolytes , 1995 .

[23]  J. Dahn,et al.  Rechargeable Lithium Batteries with Aqueous Electrolytes , 1994, Science.

[24]  C. Delmas,et al.  Relationships between structure and magnetic properties of titanium(III) nasicon-type phosphates , 1988 .

[25]  P. Hagenmuller,et al.  A nasicon-type phase as intercalation electrode: NaTi2(PO4)3 , 1987 .