Removal of ternary VOCs in air streams at high loads using a compost-based biofilter

Abstract Waste gases in the industry process are often characterized by the presence of multi-pollutants and concentration varieties of the compounds. In this study, the behavior of a biofilter system under high loads of ternary VOCs was studied. The biofilter was operated using a mixture of compost, lava and soil and applied to treat the air containing ethyl acetate, isopropanol and toluene. The biofilter treated up to 200 g m −3  bed h −1 of ethyl acetate and 120 g m −3  bed h −1 of isopropanol with percentage removals of nearly 100% and the empty bed retention time between 45 and 90 s. Toluene removal efficiencies were in the range of 40–100% with the inlet concentration about 0.5 g m −3 due to the inhibition of ethyl acetate and isopropanol. During the 3 months operation, filter media clogging/channeling, pH decrease and nitrogen loss from the media resulted in the deterioration of the biofilter performance. The results demonstrated that under the conditions of pH ranging from 6.4 to 7.4 and the nitrogen content of the media above 0.3 mg g −1 , the mixture of ethyl acetate, isopropanol and toluene could be treated effectively using a compost-based biofilter.

[1]  Ryszard Brzezinski,et al.  Toluene removal by biofiltration: Influence of the nitrogen concentration on operational parameters : Novel reactor engineering for the new millennium , 2001 .

[2]  K. Chang,et al.  Biofiltration of isopropyl alcohol and acetone mixtures by a trickle-bed air biofilter , 2003 .

[3]  Sergio Revah,et al.  Effect of drying on biofilter performance: modeling and experimental approach. , 2003, Environmental science & technology.

[4]  S. Hwang,et al.  Biofiltration of waste gases containing both ethyl acetate and toluene using different combinations of bacterial cultures. , 2003, Journal of biotechnology.

[5]  D. Chang,et al.  Nutrient Limitation in a Compost Biofilter Degrading Hexane. , 2012, Journal of the Air & Waste Management Association.

[6]  S. Revah,et al.  Influence of mixing and water addition on the removal rate of toluene vapors in a biofilter. , 2000, Biotechnology and bioengineering.

[7]  Pratim Biswas,et al.  Evaluation of Trickle Bed Biofilter Media for Toluene Removal , 1995 .

[8]  D. Grant Allen,et al.  Biofiltration of mixtures of hydrophilic and hydrophobic volatile organic compounds , 2000 .

[9]  F J Weber,et al.  Prevention of clogging in a biological trickle‐bed reactor removing toluene from contaminated air , 1996, Biotechnology and bioengineering.

[10]  Marc A. Deshusses,et al.  Development and Validation of a Simple Protocol To Rapidly Determine the Performance of Biofilters for VOC Treatment , 2000 .

[11]  Byung J. Kim,et al.  Dynamic mathematical model for the biodegradation of VOCs in a biofilter: Biomass accumulation study , 1998 .

[12]  R. Auria,et al.  Influence of water content on degradation rates for ethanol in biofiltration. , 1998, Journal of the Air & Waste Management Association.

[13]  J. Roux,et al.  Biofiltration of a Mixture of Volatile Organic Emissions , 2001, Journal of the Air & Waste Management Association.

[14]  W. Moe,et al.  Effect of nitrogen limitation on performance of toluene degrading biofilters. , 2001, Water research.

[15]  M. Lin,et al.  Removal of ethylacetate vapor from waste gases by a trickle-bed air biofilter. , 2001, Journal of biotechnology.

[16]  I. Dunn,et al.  Behavior of biofilters for waste air biotreatment. 1. Dynamic model development. , 1995, Environmental science & technology.

[17]  B. C. Baltzis,et al.  Modeling the removal of VOC mixtures in biotrickling filters. , 2001, Biotechnology and bioengineering.

[18]  H. Langenhove,et al.  Regeneration of a Compost Biofilter Degrading High Loads of Ammonia by Addition of Gaseous Methanol , 2002, Journal of the Air & Waste Management Association.

[19]  M. Deshusses,et al.  Biofiltration of high loads of ethyl acetate in the presence of toluene. , 1999, Journal of the Air & Waste Management Association.

[20]  Ryszard Brzezinski,et al.  A study of clogging in a biofilter treating toluene vapors , 2003 .

[21]  Shyh-Jye Hwang,et al.  Kinetic Behavior of the Toluene Biofiltration Process , 1997 .

[22]  R. Loehr,et al.  Effect of Media Nitrogen Concentration on Biofilter Performance. , 1998, Journal of the Air & Waste Management Association.

[23]  D. S. Hodge,et al.  Formation of Acidic and Toxic intermediates in Overloaded Ethanol Biofilters , 1995 .

[24]  Sébastien Roy,et al.  Biofiltration of air contaminated with toluene on a compost-based bed , 2002 .

[25]  D. G. Allen,et al.  Transient Performance of Biofilters Treating Mixtures of Hydrophilic and Hydrophobic Volatile Organic Compounds. , 1999, Journal of the Air & Waste Management Association.

[26]  Fenglin Yang,et al.  Toluene vapour degradation and microbial community in biofilter at various moisture content , 2002 .

[27]  J. B. Sisson,et al.  Water Content Dynamics in Biofiltration: The Role of Humidity and Microbial Heat Generation , 1997 .

[28]  Su Yumei Effect of initial moisture content of packing material on the biofiltration of gaseous ethyl acetate , 2002 .

[29]  Xie Quan,et al.  Simultaneous removal of ethyl acetate and toluene in air streams using compost-based biofilters. , 2002, Journal of hazardous materials.