A Self-Repairing, Large Linear Working Range Shape Memory Carbon Nanotubes/Ethylene Vinyl Acetate Fiber Strain Sensor for Human Movement Monitoring.

Flexible strain sensors have shown great application value in wearable devices. In the past decades, researchers have spent numerous on developing high stretchability, excellent dynamic durability, and large linear working range flexible strain sensors and shaped a series of important research results. However, the viscoelasticity of the elastic polymer is always a big challenge to develop a flexible sensor. Here, to overcome this challenge, we developed a novel self-repairing carbon nanotubes/ethylene vinyl acetate (CNTs/EVA) fiber strain sensors, prepared by embedding the CNTs in the surface of the swollen shape memory EVA fiber via the ultrasonic method. The CNTs/EVA fiber strain sensors responded significant result which has high stretchability (190% strain), large linear working range (up to 88% strain), excellent dynamic durability (5000 cycles), and fast response speed (312 ms). In addition, the permanently damaged conductive network of the strain sensors, caused by the viscoelasticity of elastic polymer, can restore above the transforming temperature of the shape memory CNTs/EVA fiber. Moreover, the performance of the restored strain sensors was almost as same as that of the original strain sensors. Furthermore, terms of human health monitoring tests show that the CNTs/EVA fiber has a broad application prospects for human health monitoring in wearable electronic devices.

[1]  Jonathan N. Coleman,et al.  Mechanical Reinforcement of Polymers Using Carbon Nanotubes , 2006 .

[2]  Polyaniline, ethylene vinyl acetate semi-conductive composites as pressure sensitive sensor , 2013 .

[3]  R. Li,et al.  Graphite-nanoplatelet-decorated polymer nanofiber with improved thermal, electrical, and mechanical properties. , 2013, ACS applied materials & interfaces.

[4]  L. Castano,et al.  Smart fabric sensors and e-textile technologies: a review , 2014 .

[5]  H. Haick,et al.  Dynamic Nanoparticle-Based Flexible Sensors: Diagnosis of Ovarian Carcinoma from Exhaled Breath. , 2015, Nano letters.

[6]  Yang Yang,et al.  Flexible self-healing nanocomposites for recoverable motion sensor , 2015 .

[7]  Qing-Qing Ni,et al.  Effect of epoxy-graft-polyoxyethylene octyl phenyl ether on preparation, mechanical properties and triple-shape memory effect of carbon nanotube/water-borne epoxy nanocomposites , 2015 .

[8]  Xiaodong Chen,et al.  Healable, Transparent, Room-Temperature Electronic Sensors Based on Carbon Nanotube Network-Coated Polyelectrolyte Multilayers. , 2015, Small.

[9]  Mehmet Turan,et al.  Parallel Microcracks-based Ultrasensitive and Highly Stretchable Strain Sensors. , 2016, ACS applied materials & interfaces.

[10]  Changyu Shen,et al.  Electrically conductive strain sensing polyurethane nanocomposites with synergistic carbon nanotubes and graphene bifillers. , 2016, Nanoscale.

[11]  Yong Lin,et al.  Ultrasensitive Cracking-Assisted Strain Sensors Based on Silver Nanowires/Graphene Hybrid Particles. , 2016, ACS applied materials & interfaces.

[12]  I. Park,et al.  Stretchable, Skin‐Mountable, and Wearable Strain Sensors and Their Potential Applications: A Review , 2016 .

[13]  K. Jeppson,et al.  Embedded Fin-Like Metal/CNT Hybrid Structures for Flexible and Transparent Conductors. , 2016, Small.

[14]  R. Sun,et al.  Highly Stretchable and Sensitive Strain Sensor Based on Facilely Prepared Three-Dimensional Graphene Foam Composite. , 2016, ACS applied materials & interfaces.

[15]  C. Qian,et al.  Two-way shape memory behavior of semi-crystalline elastomer under stress-free condition , 2016 .

[16]  C. Qian,et al.  Vapor-grown carbon nanofiber/poly(ethylene-co-vinyl acetate) composites with electrical-active two-way shape memory behavior , 2017 .

[17]  Quankang Wang,et al.  A multifunctional skin-like sensor based on a 3D printed thermo-responsive hydrogel , 2017 .

[18]  Michael C. Yip,et al.  On the Control and Properties of Supercoiled Polymer Artificial Muscles , 2017, IEEE Transactions on Robotics.

[19]  Yong Lin,et al.  A high performance self-healing strain sensor with synergetic networks of poly(ɛ-caprolactone) microspheres, graphene and silver nanowires , 2017 .

[20]  Kun Dai,et al.  The effect of filler dimensionality on the electromechanical performance of polydimethylsiloxane based conductive nanocomposites for flexible strain sensors , 2017 .

[21]  H. Shea,et al.  Flexible Active Skin: Large Reconfigurable Arrays of Individually Addressed Shape Memory Polymer Actuators , 2017 .

[22]  Changyu Shen,et al.  Flexible and Lightweight Pressure Sensor Based on Carbon Nanotube/Thermoplastic Polyurethane-Aligned Conductive Foam with Superior Compressibility and Stability. , 2017, ACS applied materials & interfaces.

[23]  Changyu Shen,et al.  Conductive thermoplastic polyurethane composites with tunable piezoresistivity by modulating the filler dimensionality for flexible strain sensors , 2017 .

[24]  Sijun Liu,et al.  Ultrastretchable and Self-Healing Double-Network Hydrogel for 3D Printing and Strain Sensor. , 2017, ACS applied materials & interfaces.

[25]  Changyu Shen,et al.  A flexible and self-formed sandwich structure strain sensor based on AgNW decorated electrospun fibrous mats with excellent sensing capability and good oxidation inhibition properties , 2017 .

[26]  Ju Young Kim,et al.  3D printable composite dough for stretchable, ultrasensitive and body-patchable strain sensors. , 2017, Nanoscale.

[27]  Ling Zhang,et al.  Kirigami-patterned highly stretchable conductors from flexible carbon nanotube-embedded polymer films , 2017 .

[28]  Changyu Shen,et al.  Ultrastretchable Multilayered Fiber with a Hollow-Monolith Structure for High-Performance Strain Sensor. , 2018, ACS applied materials & interfaces.

[29]  Jing Li,et al.  A linear and large-range pressure sensor based on a graphene/silver nanowires nanobiocomposites network and a hierarchical structural sponge , 2018 .

[30]  Pei Huang,et al.  High-Performance Structural Flexible Strain Sensors Based on Graphene-Coated Glass Fabric/Silicone Composite. , 2018, ACS applied materials & interfaces.

[31]  J. Leng,et al.  Preparation and characterization of shape memory composite foams based on solid foaming method , 2018, Journal of Applied Polymer Science.

[32]  Zicai Zhu,et al.  Printing Carbon Nanotube-Embedded Silicone Elastomers via Direct Writing. , 2018, ACS applied materials & interfaces.

[33]  Changyu Shen,et al.  Flexible electrically resistive-type strain sensors based on reduced graphene oxide-decorated electrospun polymer fibrous mats for human motion monitoring , 2018 .

[34]  John A. Nychka,et al.  Preparation of fabric strain sensor based on graphene for human motion monitoring , 2018, Journal of Materials Science.

[35]  Kang Yang,et al.  Multi-functional interface sensor with targeted IFSS enhancing, interface monitoring and self-healing of GF/EVA thermoplastic composites , 2018, Composites Science and Technology.

[36]  Tao Shen,et al.  Stretchable and multifunctional strain sensors based on 3D graphene foams for active and adaptive tactile imaging , 2018, Science China Materials.

[37]  Xinyu Xue,et al.  A Self‐Powered Brain‐Linked Vision Electronic‐Skin Based on Triboelectric‐Photodetecing Pixel‐Addressable Matrix for Visual‐Image Recognition and Behavior Intervention , 2018 .

[38]  R. Sun,et al.  Three-Dimensional Graphene Structure for Healable Flexible Electronics Based on Diels-Alder Chemistry. , 2018, ACS applied materials & interfaces.

[39]  Selçuk Aslan,et al.  Thermomechanical and Shape Memory Performances of Thermo-sensitive Polyurethane Fibers , 2018, Fibers and Polymers.

[40]  Yezhou Yang,et al.  Simultaneously Detecting Subtle and Intensive Human Motions Based on a Silver Nanoparticles Bridged Graphene Strain Sensor. , 2017, ACS applied materials & interfaces.

[41]  Chunhua Lu,et al.  Preparation and assembly of five photoresponsive polymers to achieve complex light-induced shape deformations , 2018 .

[42]  Tao Xi Wang,et al.  A Brief Review of the Shape Memory Phenomena in Polymers and Their Typical Sensor Applications , 2019, Polymers.

[43]  Lijun Qu,et al.  Stretchable Conductive Fibers of Ultra-high Tensile Strain and Stable Conductance Enabled by Worm-shape Graphene Microlayer. , 2019, Nano letters.

[44]  Guo-Dong Zhang,et al.  Construction of sandwich-like porous structure of graphene-coated foam composites for ultrasensitive and flexible pressure sensors. , 2019, Nanoscale.

[45]  Yubing Dong,et al.  Design of Ethylene-Vinyl Acetate Copolymer Fiber with Two-Way Shape Memory Effect , 2019, Polymers.

[46]  N. Hu,et al.  Effect of graphene oxide-carbon nanotube hybrid filler on the mechanical property and thermal response speed of shape memory epoxy composites , 2019, Composites Science and Technology.

[47]  Tao Liu,et al.  A wearable strain sensor based on the ZnO/graphene nanoplatelets nanocomposite with large linear working range , 2019, Journal of Materials Science.

[48]  Duli Yu,et al.  Flexible and Stretchable Electronic Skin with High Durability and Shock Resistance via Embedded 3D Printing Technology for Human Activity Monitoring and Personal Healthcare , 2019, Advanced Materials Technologies.

[49]  D. Kwon,et al.  Wearable Strain Sensor Using Light Transmittance Change of Carbon Nanotube Embedded Elastomer with Microcrack. , 2019, ACS applied materials & interfaces.

[50]  Tao Zhang,et al.  Repurposed Leather with Sensing Capabilities for Multifunctional Electronic Skin , 2018, Advanced science.

[51]  Homayoun Najjaran,et al.  Graphene-Coated Spandex Sensors Embedded into Silicone Sheath for Composites Health Monitoring and Wearable Applications. , 2019, Small.

[52]  Chunhua Lu,et al.  Near-Infrared Light-Induced Sequential Shape Recovery and Separation of Assembled Temperature Memory Polymer Microparticles. , 2020, Macromolecular rapid communications.

[53]  M. Imran,et al.  Ferromagnetic shape memory Ni-Fe-Ga alloy foams for elastocaloric cooling , 2020, Journal of Physics D: Applied Physics.

[54]  Feng Xu,et al.  A Smart Glove Integrated with Tunable MWNTs/PDMS Fibers Made of One-Step Extrusion Method for Finger Dexterity, Gesture and Temperature Recognition. , 2020, ACS applied materials & interfaces.