2018 Census of Interstellar, Circumstellar, Extragalactic, Protoplanetary Disk, and Exoplanetary Molecules

To date, 204 individual molecular species, comprised of 16 different elements, have been detected in the interstellar and circumstellar medium by astronomical observations. These molecules range in size from two atoms to seventy, and have been detected across the electromagnetic spectrum from cm-wavelengths to the ultraviolet. This census presents a summary of the first detection of each molecular species, including the observational facility, wavelength range, transitions, and enabling laboratory spectroscopic work, as well as listing tentative and disputed detections. Tables of molecules detected in interstellar ices, external galaxies, protoplanetary disks, and exoplanetary atmospheres are provided. A number of visual representations of this aggregate data are presented and briefly discussed in context.

[1]  P. Thaddeus,et al.  The ethynyl radical C2H - A new interstellar molecule , 1974 .

[2]  P. Bernath,et al.  Molecular oxygen in the ρ Ophiuchi cloud , 2007, astro-ph/0702474.

[3]  Y. Kasai,et al.  DETECTION OF A NEW MOLECULAR ION HC3NH+ IN TMC-1 , 1994 .

[4]  H. Gupta,et al.  LABORATORY MEASUREMENTS AND TENTATIVE ASTRONOMICAL IDENTIFICATION OF H2NCO+ , 2013 .

[5]  S. Saito,et al.  The microwave spectrum of the methoxy radical CH3O , 1984 .

[6]  R. Saykally,et al.  Laboratory Microwave Spectrum of HCO , 1975 .

[7]  T. Millar,et al.  FIRST DETECTION OF GAS-PHASE METHANOL IN A PROTOPLANETARY DISK , 2016, 1606.06492.

[8]  T. Amano,et al.  MICROWAVE SPECTRUM OF $SO^{+}$. , 1991 .

[9]  J. L. Highberger,et al.  More Metal Cyanide Species: Detection of AlNC (X 1Σ+) toward IRC +10216 , 2001 .

[10]  Detection of CO + in the Nucleus of M82 , 2006, astro-ph/0602509.

[11]  E. Bergin,et al.  Tentative Detection of Molecular Oxygen in the ρ Ophiuchi Cloud , 2002 .

[12]  J. Maier,et al.  Laboratory confirmation of C60+ as the carrier of two diffuse interstellar bands , 2015, Nature.

[13]  Discovery of Interstellar Hydrogen Fluoride , 1997, astro-ph/9708013.

[14]  K. Menten,et al.  Rotational spectroscopy, tentative interstellar detection, and chemical modeling of N-methylformamide , 2017, 1701.04640.

[15]  G. Lake,et al.  Hot Organic Molecules Toward a Young Low-mass Star: a Look at Inner Disk Chemistry , 2005 .

[16]  J. Francesco,et al.  Abundant Cyanopolyynes as a Probe of Infall in the Serpens South Cluster-Forming Region , 2013, 1309.1763.

[17]  R. Smalley,et al.  Visible spectroscopy of jet‐cooled SiC2: Geometry and electronic structure , 1984 .

[18]  D. Meier,et al.  Detection of Interstellar Cyanoformaldehyde (CNCHO) , 2007 .

[19]  C. Gudeman,et al.  Experimental Detection of HOC+by Microwave Spectroscopy , 1982 .

[20]  Charles H. Townes,et al.  The Ammonia Spectrum and Line Shapes Near 1.25-cm Wave-Length , 1946 .

[21]  J. Watson,et al.  The Excitation Temperatures of HC9N and Other Long Cyanopolyynes in TMC-1 , 1998 .

[22]  D. Walton,et al.  The microwave spectra of symmetric top polyacetylenes: 1,3,5-Heptatriyne, CH3(CC)3H and 1-cyano-2,4-pentadiyne, CH3(CC)2CN , 1978 .

[23]  R. Davies,et al.  Excited OH+, H2O+, and H3O+ in NGC 4418 and Arp 220 , 2012, 1211.5064.

[24]  H. Müller,et al.  Terahertz spectroscopy of oxygen, O2, in its 3Σ−g and 1Δ electronic states: THz Spectroscopy of O2 , 2010 .

[25]  K. Menten,et al.  The Rotational Spectrum of TiO2 , 2008 .

[26]  L. Ziurys,et al.  Confirmation of Interstellar HOC+: Reevaluating the [HCO+]/[HOC+] Abundance Ratio , 1995 .

[27]  R. J. Myers,et al.  Microwave Spectra and Structure of Dimethyl Ether , 1963 .

[28]  Bonn,et al.  A precise and accurate determination of the cosmic microwave background temperature at z = 0.89 , 2012, 1212.5456.

[29]  P. Thaddeus,et al.  Detection of HC11N in the Cold Dust Cloud TMC-1 , 1985, astro-ph/9704233.

[30]  J. R. Houck,et al.  THE SPITZER IRS SPECTRUM OF SMP LMC 11 , 2006 .

[31]  M. Bogey,et al.  Formyl cyanide: Efficient production from allyloxyacetonitrile and its millimeter-wave spectrum , 1988 .

[32]  F. Gillett,et al.  SPECTRA OF THE BECKLIN--NEUGEBAUER POINT SOURCE AND THE KLEINMANN--LOW NEBULA FROM 2.8 TO 13.5 MICRONS. , 1973 .

[33]  R. Cook,et al.  Millimeter Wave Spectroscopy of Unstable Molecular Species. II. Sulfur Monoxide , 1964 .

[34]  S. Saito,et al.  The microwave spectrum of the CH2N radical in the X̃ 2B2 ground electronic state , 1992 .

[35]  A. Tielens,et al.  Solid Carbonyl Sulphide (OCS) in W33A , 1995 .

[36]  K. Szalewicz,et al.  WEAK MASER EMISSION OF METHYL FORMATE TOWARD SAGITTARIUS B2(N) IN THE GREEN BANK TELESCOPE PRIMOS SURVEY , 2014, 1401.1136.

[37]  Michiro Hayashi,et al.  Microwave spectrum, structure, dipole moment and internal rotation of trans-ethylmethylether , 1975 .

[38]  William M. Irvine,et al.  Infrared optical properties of water and ice spheres , 1968 .

[39]  J. Cernicharo,et al.  Detection of the SiNC radical in IRC+10216 , 2004 .

[40]  B. Zuckerman,et al.  Observations of cs, HCN, U89.2, and U90.7 in NGC 2264 , 1971 .

[41]  A. Apponi,et al.  The rotational spectra of the HCCCNH+, NCCNH+, and CH3CNH+ ions , 2000 .

[42]  Technology,et al.  Detection of chloronium and measurement of the Cl-35/Cl-37 isotopic ratio at z=0.89 toward PKS 1830-211 , 2014, 1404.7668.

[43]  E. Chapillon,et al.  First detection of H2S in a protoplanetary disk , 2018, Astronomy & Astrophysics.

[44]  L. Ziurys,et al.  The millimeter-wave spectrum of AlOH , 1993 .

[45]  H. Heise,et al.  Molecular Structure, Quadrupole Coupling Tensor and Dipole Moment of Ethyl Cyanide , 1974 .

[46]  A. Mckellar,et al.  EVIDENCE FOR THE MOLECULAR ORIGIN OF SOME HITHERTO UNIDENTIFIED INTERSTELLAR LINES , 1940 .

[47]  L. Ziurys,et al.  DETECTION OF FeCN (X4Δi) IN IRC+10216: A NEW INTERSTELLAR MOLECULE , 2011 .

[48]  W. Gordy,et al.  Microwave Spectra: Methyl Cyanide and Methyl Isocyanide , 1947 .

[49]  E. Cochran,et al.  ESR Study of Ethynyl and Vinyl Free Radicals , 1964 .

[50]  J. Goicoechea,et al.  Trans-cis molecular photoswitching in interstellar Space. , 2016, Astronomy and astrophysics.

[51]  J. Hougen,et al.  Ground and first excited torsional states of acetamide , 2004 .

[52]  T. Forveille,et al.  X-ray and molecular emission from the nearest region of recent star formation. , 1997, Science.

[53]  E. A. Alekseev,et al.  A Rigorous Attempt to Verify Interstellar Glycine , 2004, astro-ph/0410335.

[54]  J. Goicoechea,et al.  Probing the dust formation region in IRC +10216 with the high vibrational states of hydrogen cyanide , , 2011 .

[55]  J. Cernicharo,et al.  LABORATORY AND ASTRONOMICAL DISCOVERY OF HYDROMAGNESIUM ISOCYANIDE , 2013, 1309.0371.

[56]  E. Gottlieb,et al.  Laboratory detection of the C3H radical , 1985 .

[57]  P. Friberg,et al.  Identification of the interstellar cyanomethyl radical (CH2CN) in the molecular clouds TMC-1 and Sagittarius B2. , 1988, The Astrophysical journal.

[58]  L. Ziurys,et al.  Toward Extragalactic Chemistry: Detections of N 2H + and SiO in Nearby Galaxies , 1995 .

[59]  D. Woon Modeling Gas-Grain Chemistry with Quantum Chemical Cluster Calculations. I. Heterogeneous Hydrogenation of CO and H2CO on Icy Grain Mantles , 2002 .

[60]  R. Linke,et al.  Interstellar methyl mercaptan. , 1979 .

[61]  Detection of Interstellar Methylamine by its 2_{02}->1_{10} A_{a^{-}} State Transition , 1974 .

[62]  K. Roth,et al.  Discovery of interstellar NH , 1991 .

[63]  D. Buhl,et al.  Interstellar Isocyanic Acid , 1972 .

[64]  G. Langston,et al.  Non-detection of HC11N towards TMC-1: constraining the chemistry of large carbon-chain molecules , 2016, 1609.02570.

[65]  M. Gerin,et al.  DISCOVERY OF THE METHOXY RADICAL, CH3O, TOWARD B1: DUST GRAIN AND GAS-PHASE CHEMISTRY IN COLD DARK CLOUDS , 2012 .

[66]  Takeshi Oka,et al.  Observation of the infrared spectrum of H 3 , 1980 .

[67]  L. Weliachew Detection of Interstellar OH in Two External Galaxies , 1971 .

[68]  R. Saykally,et al.  Laboratory Microwave Spectrum and Rest Frequencies of the N2H(+) Ion , 1976 .

[69]  P. Encrenaz,et al.  Detection of interstellar H3O+ : a confirming line , 1991 .

[70]  P. Friberg,et al.  The detection of interstellar methylcyanoacetylene. , 1984, The Astrophysical journal.

[71]  W. Meerts,et al.  Study of the torsion-rotation Hamiltonian for symmetric tops using the millimeter wave spectrum of methyl silane , 1983 .

[72]  R. Kakar,et al.  Detection of 2.6-millimeter radiation probably due to nitrogen sulfide , 1975 .

[73]  L. Coudert,et al.  The Rotational/Concerted Torsional Spectrum of the g' Ga Conformer of Ethylene Glycol , 1995 .

[74]  Edwin A. Bergin,et al.  THE EFFECTS OF SNOWLINES ON C/O IN PLANETARY ATMOSPHERES , 2011, 1110.5567.

[75]  R. Garrod,et al.  ALMA Detection of Interstellar Methoxymethanol (CH3OCH2OH) , 2017, 1712.03256.

[76]  M. Gerin,et al.  HYDROGEN CHLORIDE IN DIFFUSE INTERSTELLAR CLOUDS ALONG THE LINE OF SIGHT TO W31C (G10.6-0.4) , 2013, 1302.6616.

[77]  J. M. Hollis,et al.  Radio detection of nitroxyl (HNO): the first interstellar NO bond. , 1977 .

[78]  Howard A. Peelle,et al.  Teaching a topic in cybernetics with APL: An introduction to neural net modelling , 1981, APL '81.

[79]  J. Goicoechea,et al.  First Detection of Interstellar S2H , 2017, The astrophysical journal. Letters.

[80]  Koichi M. T. Yamada,et al.  Rotational spectrum of CNCN in excited vibrational states , 1992 .

[81]  S. Saito,et al.  Millimeter-wave spectrum of the CCO radical , 1985 .

[82]  Patrick Thaddeus,et al.  Laboratory measurement of the rotational spectrum of SiCC , 1989 .

[83]  Walter Gordy,et al.  One-to-Two Millimeter Wave Spectroscopy. IV. Experimental Methods and Results for OCS, CH3F, andH2O , 1954 .

[84]  B. Drouin,et al.  THE ROTATIONAL SPECTRUM OF HCl+ , 2012 .

[85]  First detections of extragalactic SO2, NS and NO , 2003, astro-ph/0309663.

[86]  Y. Ohshima,et al.  Laboratory detection of HC9N using a Fourier transform microwave spectrometer , 1991 .

[87]  In situ infrared transmission study of Rb- and K-doped fullerenes. , 1993, Physical review. B, Condensed matter.

[88]  C. Masson,et al.  Small-Scale Structure of the Circumstellar Gas of HL Tauri and R Monocerotis , 1986 .

[89]  D. Goldhaber,et al.  Silane in IRC +10216 , 1984 .

[90]  L. Coudert,et al.  Interstellar Antifreeze: Ethylene Glycol , 2002 .

[91]  P. Thaddeus,et al.  Laboratory and astronomical identification of cyclopropenylidene, C3H2. , 1985 .

[92]  W. J. Tabor Microwave Spectrum and Barrier to Internal Rotation of Acetic Acid , 1957 .

[93]  W. Thi,et al.  Detection of H_2 Pure Rotational Line Emission from the GG Tauri Binary System , 1999, astro-ph/9906231.

[94]  J. Cernicharo,et al.  The millimeter wave tunneling–rotational spectrum of phenol , 2013 .

[95]  Germany,et al.  Molecules at z = 0.89 - A 4-mm-rest-frame absorption-line survey toward PKS 1830−211 , 2011, 1104.3361.

[96]  J. Stanton,et al.  DISCOVERY OF SiCSi IN IRC+10216: A MISSING LINK BETWEEN GAS AND DUST CARRIERS OF Si–C BONDS , 2015, The astrophysical journal. Letters.

[97]  U. Magg,et al.  Diode laser spectroscopy of the ν4 band of benzene , 1988 .

[98]  W. Meerts,et al.  Internal rotation in methyl silane by avoided-crossing molecular-beam spectroscopy , 1982 .

[99]  S. Saito,et al.  Microwave spectrum of the NCO radical , 1970 .

[100]  T. Miyaji,et al.  A 8.8-50 GHz Complete Spectral Line Survey toward TMC-1: I. Survey Data. , 2004 .

[101]  J. Goicoechea,et al.  Astronomical identification of CN^-, the smallest observed molecular anion , 2010, 1007.0662.

[102]  E. Herbst,et al.  Laboratory measurement of the P(2,1) submillimeter transition frequency of H3O(+) , 1985 .

[103]  R. Wilson,et al.  INTERSTELLAR CARBON MONOSULFIDE. , 1971 .

[104]  Foreign-Gas-Broadening Effects in the 15 μm CO2 Bands , 1972 .

[105]  M. Barlow,et al.  Discovery of Far-Infrared Pure Rotational Transitions of CH+ in NGC 7027 , 1997 .

[106]  Paul A. Jones,et al.  A Search for biomolecules in Sagittarius B2 (LMH) with the Australia Telescope Compact Array , 2007 .

[107]  D. Buhl,et al.  Radio detection of interstellar dimethyl ether , 1974 .

[108]  Y. Kasai,et al.  Laboratory detection of C5S by pulsed-discharge-nozzle Fourier transform microwave spectroscopy , 1993 .

[109]  F. D. Tak,et al.  Radiative Transfer and Molecular Data for Astrochemistry , 2011, Proceedings of the International Astronomical Union.

[110]  J. M. Hollis,et al.  An interstellar line coincident with the P(2,l)transition of hydronium (H3O+) , 1986, Nature.

[111]  C. Lin,et al.  Calculation of Energy Levels for Internal Torsion and Over‐All Rotation. II. CH3CHO Type Molecules; Acetaldehyde Spectra , 1957 .

[112]  H. Liszt,et al.  Microwave detection of interstellar NO , 1973 .

[113]  J. M. Hollis,et al.  Confirmation of Interstellar Methylene , 1995 .

[114]  Thaddeus,et al.  Experimental Structures of the Carbon Chains HC(7)N, HC(9)N, and HC(11)N by Isotopic Substitution. , 2000, Journal of molecular spectroscopy.

[115]  S. Strahan,et al.  Measurement of the rotational spectrum of the water cation (H2O+) by laser magnetic resonance , 1986 .

[116]  N. Woolf,et al.  Identification of Phosphorus Monoxide (X 2Πr) in VY Canis Majoris: Detection of the First P-O Bond in Space , 2007 .

[117]  T. Oka,et al.  Detection of H+3 in interstellar space , 1996, Nature.

[118]  M. Gerin,et al.  AN OBSERVATIONAL INVESTIGATION OF THE IDENTITY OF B11244 (l–C3H+/C3H−) , 2013, 1312.0153.

[119]  A. Cameron,et al.  Abundances of the elements in the solar system , 1973 .

[120]  D. Buhl,et al.  DETECTION OF SEVERAL NEW INTERSTELLAR MOLECULES , 1972, Annals of the New York Academy of Sciences.

[121]  L. T. Little,et al.  Observations of interstellar HC5N and HC7N in dark dust clouds , 1978 .

[122]  Winnewisser,et al.  The Millimeter- and Submillimeter-Wave Spectrum and the Dipole Moment of Ethylenimine. , 2000, Journal of molecular spectroscopy.

[123]  N. Kaifu,et al.  Laboratory and astronomical detection of the cyclic C3H radical , 1987 .

[124]  J. M. Hollis,et al.  Radio detection of the interstellar formyl radical. , 1976 .

[125]  S. Green,et al.  Theoretical study of the butadiynyl and cyanoethynyl radicals - Support for the identification of C3N in IRC + 10216 , 1977 .

[126]  A. Benz,et al.  Hydrides in young stellar objects: Radiation tracers in a protostar-disk-outflow system , 2010, 1007.3370.

[127]  E. Bergin,et al.  Chemistry of a newly detected circumbinary disk in Ophiuchus , 2018, Astronomy & Astrophysics.

[128]  P. Godfrey,et al.  The microwave spectrum of HNC: identification of U90.7 , 1976, Nature.

[129]  E. F. Dishoeck,et al.  A 3-5 mu m VLT spectroscopic survey of embedded young low mass stars II - Solid OCN- , 2005, astro-ph/0508551.

[130]  Stephan R. McCandliss,et al.  The interstellar N2 abundance towards HD 124314 from far-ultraviolet observations , 2004, Nature.

[131]  K. Menten,et al.  Exploring molecular complexity with ALMA (EMoCA): Alkanethiols and alkanols in Sagittarius B2(N2) , 2015, 1512.05301.

[132]  F. D. Lucia,et al.  Submillimeter-Wave Spectra and Equilibrium Structures of the Hydrogen Halides , 1971 .

[133]  B. Zuckerman,et al.  Methyl acetylene as a temperature probe for dense interstellar clouds , 1984 .

[134]  J. W. C. Johns,et al.  The bending energy levels of C4H2 , 1992 .

[135]  P. Caselli,et al.  HERSCHEL MEASUREMENTS OF MOLECULAR OXYGEN IN ORION , 2011, 1108.0441.

[136]  C. Hirose Laboratory Microwave Spectrum of Ethylene Oxide , 1974 .

[137]  P. Schilke,et al.  Interferometric observations of FeO towards Sagittarius B2 , 2003 .

[138]  N. Piltch,et al.  The observation of the J = 1-2 transition of HCS/+/ in a laboratory glow discharge , 1981 .

[139]  Takayuki Kotani,et al.  High-resolution Spectroscopic Detection of TiO and a Stratosphere in the Day-side of WASP-33b , 2017, 1710.05276.

[140]  T. Miyaji,et al.  Detection of intense unidentified lines in TMC-1 , 1987 .

[141]  D. Wilner,et al.  The comet-like composition of a protoplanetary disk as revealed by complex cyanides , 2015, Nature.

[142]  Y. Ohshima,et al.  Determination of the hyperfine constants for HCCO by pulsed-discharge-nozzle Fourier-transform microwave spectroscopy , 1993 .

[143]  P. Bernath,et al.  Detection of C3 in the Circumstellar Shell of IRC+10216 , 1988, Science.

[144]  J. Whiteoak,et al.  The detection of CH in external galaxies , 1980 .

[145]  Sara Seager,et al.  A PRECISE WATER ABUNDANCE MEASUREMENT FOR THE HOT JUPITER WASP-43b , 2014, 1410.2255.

[146]  Kenji Ito,et al.  Line Oscillator Strength Measurements in the 0-0 Band of the c′4 1Σu+ ← X 1Σg+ Transition of N2 , 2000 .

[147]  A. Cooksy,et al.  Rotational spectra of the carbon-chain radicals HC5O, HC6O, and HC7O. , 2005, The Journal of chemical physics.

[148]  J. Sheridan,et al.  Structural studies of linear molecules by microwave spectroscopy , 1963 .

[149]  K. Menten,et al.  Submillimeter absorption from SH+, a new widespread interstellar radical, 13CH+ and HCl , 2010, 1009.2825.

[150]  P. Thaddeus,et al.  LABORATORY DETECTION OF THIOCYANIC ACID HSCN , 2009 .

[151]  J. T. Hougen,et al.  A fitting program for molecules with two inequivalent methyl tops and a plane of symmetry at equilibrium: Application to new microwave and millimeter-wave measurements of methyl acetate , 2011 .

[152]  F. Ménard,et al.  Detection of CH+ emission from the disc around HD 100546 , 2011, 1104.2283.

[153]  Cristina Puzzarini,et al.  The Lamb-dip spectrum of phosphine: The nuclear hyperfine structure due to hydrogen and phosphorus , 2006 .

[154]  B. McCall,et al.  On the discovery of the diffuse interstellar bands , 2013, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[155]  R. S. Ram,et al.  Gas-phase infrared emission spectra of C60 and C70. Temperature-dependent studies , 1994 .

[156]  Microwave spectrum, dipole moment, and structure of anti-vinyl alcohol , 1985 .

[157]  D. Wilner,et al.  FIRST DETECTION OF c-C3H2 IN A CIRCUMSTELLAR DISK , 2013, 1302.0251.

[158]  R. Brown,et al.  Detection of a new carbon-chain molecule, CCO. , 1991, The Astrophysical journal.

[159]  K. M. Menten,et al.  Detection of interstellar hydrogen peroxide , 2011, 1105.5799.

[160]  U. N. Dame,et al.  Detection of interstellar C2 and C3 in the Small Magellanic Cloud , 2012, 1209.6420.

[161]  J. Grabow,et al.  Precise dipole moment and quadrupole coupling constants of benzonitrile , 2007, 0709.2984.

[162]  A. Charo,et al.  Laboratory measurements of millimeter and submillimeter rotational transitions of NH2 , 1981 .

[163]  A. Giorgio,et al.  Detection of interstellar oxidaniumyl : Abundant H2O+ towards the star-forming regions DR21, Sgr B2, and NGC6334 , 2010, 1005.2521.

[164]  L. Ziurys,et al.  Laboratory detection of a new interstellar free radical CH2CN(2B1). , 1988, Astrophysical Journal.

[165]  Walter Gordy,et al.  Microwave Molecular Spectra , 1970 .

[166]  A. H. Barrett,et al.  Radio Observations of OH in the Interstellar Medium , 1963, Nature.

[167]  J. Cernicharo,et al.  Detection of interstellar HCS and its metastable isomer HSC: new pieces in the puzzle of sulfur chemistry. , 2018, Astronomy and astrophysics.

[168]  James J. Condon,et al.  Essential Radio Astronomy , 2016 .

[169]  S. Sandford,et al.  Unraveling the 10 Micron “Silicate” Feature of Protostars: The Detection of Frozen Interstellar Ammonia , 1998, The Astrophysical journal.

[170]  B. Parise,et al.  Detection of the hydroperoxyl radical HO2 toward ρ Ophiuchi A - Additional constraints on the water chemical network , 2012, 1205.0361.

[171]  J. Bally,et al.  Detection of Interstellar PN: The First Identified Phosphorus Compound in the Interstellar Medium , 1987 .

[172]  CNRS,et al.  Discovery of interstellar mercapto radicals (SH) with the GREAT instrument on SOFIA , 2012, 1202.3142.

[173]  M. W. Sinclair,et al.  Discovery of Interstellar Methanimine (Formaldimine) , 1973 .

[174]  Santiago,et al.  An ALMA Early Science survey of molecular absorption lines toward PKS 1830−211 - Analysis of the absorption profiles , 2014, 1404.7667.

[175]  Molecular gas chemistry in AGN I. The IRAM 30 m survey of NGC 1068 , 2004, astro-ph/0402556.

[176]  J. Ball,et al.  Detection of interstellar nitrogen sulfide , 1975 .

[177]  A. Apponi,et al.  The rotational spectrum of rhomboidal SiC3 , 1999 .

[178]  Klaus,et al.  Rotational Spectra of the Thiosulfeno Radical, HSS and DSS, between 0.3 and 0.9 THz. , 2000, Journal of molecular spectroscopy.

[179]  G. Wlodarczak,et al.  The microwave and submillimeter-wave spectrum of methyl chloride , 1986 .

[180]  Jan Cami,et al.  Detection of C60 and C70 in a Young Planetary Nebula , 2010, Science.

[181]  G. Blake,et al.  INTERSTELLAR CARBODIIMIDE (HNCNH): A NEW ASTRONOMICAL DETECTION FROM THE GBT PRIMOS SURVEY VIA MASER EMISSION FEATURES , 2012, 1209.1590.

[182]  S. Butcher,et al.  Microwave Spectrum of Propionaldehyde , 1964 .

[183]  A. Charo,et al.  Laboratory millimeter and submillimeter spectrum of HOC , 1981 .

[184]  J. Cernicharo,et al.  Tentative detection of phosphine in IRC +10216 , 2008, 0805.4297.

[185]  L. Mundy,et al.  The detection of interstellar methyl-diacetylene. , 1984 .

[186]  P. Godfrey,et al.  Generation, microwave spectrum and dipole moment of ketenimine , 1984 .

[187]  J. Goicoechea,et al.  The IRAM-30 m line survey of the Horsehead PDR. III. High abundance of complex (iso-)nitrile molecules in UV-illuminated gas , 2013, 1305.2371.

[188]  M. Bogey,et al.  The millimeter-wave spectrum of aminoacetonitrile , 1990 .

[189]  K. Kawaguchi,et al.  Laboratory detection and astronomical identification of a new free radical, CCS 3Sigma/-/ , 1987 .

[190]  S. Ikuta An ab initio MO study on structures and energetics of C3H−, C3H, and C3H+ , 1997 .

[191]  S. Yamamoto,et al.  Microwave spectrum and molecular structure of the HSC radical , 2000 .

[192]  T. Forveille,et al.  Direct evidence of multiple reservoirs of volatile nitrogen in a protosolar nebula analogue , 2017, 1706.10095.

[193]  P. Hennebelle,et al.  Herschel/HIFI discovery of interstellar chloronium (H2Cl+) , 2010, 1007.1461.

[194]  F. Combes,et al.  Dynamics of galaxies and their molecular cloud distributions : proceedings of the 146th Symposium of the International Astronomical Union, held in Paris, France, June 4-9, 1990 , 1991 .

[195]  W. Jevons Report on band-spectra of diatomic molecules , 1932 .

[196]  J. Burkholder,et al.  Fourier transform infrared spectrum of the ν2 band of the NH2 radical , 1988 .

[197]  H. Müller,et al.  Millimeter-wave spectroscopy of titanium dioxide, TiO2 , 2011 .

[198]  Carl A. Gottlieb,et al.  Detection of Methyl Alcohol in Sagittarius , 1970 .

[199]  K. Kawaguchi,et al.  Detection of HNCCC in TMC-1 , 1992 .

[200]  B. Turner A molecular line survey of Sagittarius B2 and Orion-KL from 70 to 115 GHz. I - The observational data , 1989 .

[201]  T. Goyette,et al.  Millimeter/Submillimeter-Wave Spectrum of the First Excited Torsional State in HOOH , 1995 .

[202]  H. Gupta,et al.  Rotational Spectra of the Carbon Chain Negative Ions C4H– and C8H– , 2007 .

[203]  R. Wilson,et al.  Discovery of interstellar silicon monoxide , 1971 .

[204]  K. Menten,et al.  Complex organic molecules in diffuse clouds along the line of sight to Sagittarius B2 , 2017, 1708.07292.

[205]  W. Langer,et al.  First astronomical detection of the cumulene carbon chain molecule H2C6 in TMC-1. , 1997, The Astrophysical journal.

[206]  Alan T. Tokunaga,et al.  Hot H2O Emission and Evidence for Turbulence in the Disk of a Young Star , 2003 .

[207]  J. Cernicharo,et al.  A rigorous detection of interstellar CH3NCO: An important missing species in astrochemical networks. , 2016, Astronomy and astrophysics.

[208]  Detection of SiN in IRC +10216 , 1992 .

[209]  I. Yamamura,et al.  Very Large Telescope Spectra of Carbon Stars in the Large Magellanic Cloud and Their Metallicity Dependence , 2002 .

[210]  G. Bird,et al.  Microwave Spectrum of Carbon Monsulfide , 1955 .

[211]  R. Gilliland,et al.  Detection of an Extrasolar Planet Atmosphere , 2001, astro-ph/0111544.

[212]  Anthony J. Remijan,et al.  Detection of Ketenimine (CH2CNH) in Sagittarius B2(N) Hot Cores , 2006 .

[213]  Igor I. Leonov,et al.  Reinvestigation of the Microwave Spectrum of Acetamide , 2001 .

[214]  P. Feldman,et al.  C3S and C5S in IRC +10216 , 1993 .

[215]  S. Kwok,et al.  UNIDENTIFIED INFRARED EMISSION BANDS: PAHs or MAONs? , 2013, 1304.7629.

[216]  R. Wertheimer,et al.  Étude du spectre de rotation de la molécule d'acide formique: B. Étude de quelques substituons isotopiques. Application à la détermination de la structure de la molécule , 1971 .

[217]  M. Gerin,et al.  Discovery of Interstellar Propylene (CH2CHCH3): Missing Links in Interstellar Gas-Phase Chemistry , 2007, 0707.1308.

[218]  J. Maillard,et al.  Ground state molecular constants of 12C16O , 1975 .

[219]  R. Brown,et al.  A new interstellar polyatomic molecule: detection of propynal in the cold cloud TMC-1. , 1988, The Astrophysical journal.

[220]  F. Lovas,et al.  Millimeter wave spectrum of glycine , 1978 .

[221]  Ana Heras,et al.  Infrared Space Observatory's Discovery of C4H2, C6H2, and Benzene in CRL 618 , 2001 .

[222]  G. Winnewisser The ground state of propynal , 1973 .

[223]  M. Winnewisser,et al.  The microwave fourier transform, millimeter-wave, and submillimeter-wave rotational spectra of isocyanogen, CNCN , 1990 .

[224]  Gautam Vasisht,et al.  The presence of methane in the atmosphere of an extrasolar planet , 2008, Nature.

[225]  H. Møllendal,et al.  Microwave spectra of isotopic glycolaldehydes, substitution structure, intramolecular hydrogen bond and dipole moment , 1973 .

[226]  J. Cernicharo,et al.  Discovery of Phosphaethyne (HCP) in Space: Phosphorus Chemistry in Circumstellar Envelopes , 2007 .

[227]  Antonio Claret,et al.  Detection of titanium oxide in the atmosphere of a hot Jupiter , 2017, Nature.

[228]  T. Momose,et al.  The submillimeter‐wave spectrum of the 13CH3O radical , 1988 .

[229]  K. Kawaguchi,et al.  Laboratory detection of a new carbon-chain molecule C3S and its astronomical identification , 1987 .

[230]  R. W. Kilb Internal Barrier Height of Methyl Mercaptan , 1955 .

[231]  M. Birk,et al.  The rotational-torsional spectrum of carbodiimide: A probe for the unusual dynamics , 1989 .

[232]  Geoffrey A. Blake,et al.  An old disk still capable of forming a planetary system , 2013, Nature.

[233]  H. Matthews,et al.  The detection of vinyl cyanide in TMC-1. , 1983 .

[234]  R. Wertheimer,et al.  Étude du spectre de rotation de la molecule d'acide formique: A. Étude de la molécule H12C16O16OH dans l'état fondamental , 1971 .

[235]  V. Wakelam,et al.  Oxygen depletion in dense molecular clouds: a clue to a low O_2 abundance? , 2011, 1104.1530.

[236]  L. Ziurys,et al.  MILLIMETER DETECTION OF AlO (X 2Σ+): METAL OXIDE CHEMISTRY IN THE ENVELOPE OF VY CANIS MAJORIS , 2009 .

[237]  Tokyo Institute of Technology,et al.  Complex organic molecules in protoplanetary disks , 2013, 1403.0390.

[238]  G. Winnewisser,et al.  Sub-Doppler Saturation Spectroscopy of HCN up to 1 THz and Detection of J = 3 —> 2 (4—> 3) Emission from TMC1 , 2002 .

[239]  D. Zafra PRECISE LABORATORY DETERMINATION OF ROTATIONAL TRANSITION FREQUENCIES IN CYANOACETYLENE. , 1971 .

[240]  J. Cernicharo,et al.  Searching for trans ethyl methyl ether in Orion KL. , 2015, Astronomy and astrophysics.

[241]  F. Lovas,et al.  Detection and Confirmation of Interstellar Acetic Acid , 1997 .

[242]  G. V. Zadelhoff,et al.  Detection of DCO+ in a circumstellar disk , 2003, astro-ph/0301571.

[243]  W. Welch,et al.  Detection of NH sub 3 molecules in the interstellar medium by their microwave emission. , 1968 .

[244]  D. Lide Vibration-rotation interactions in cyanamide; the question of planarity of amides , 1962 .

[245]  G. Blake,et al.  Chemistry in circumstellar disks: CS toward HL Tauri , 1992 .

[246]  P. Kalmus,et al.  Laboratory Detection of the Linear Cyanopolyyne HC11N , 1996 .

[247]  A. Fuente,et al.  TENTATIVE DETECTION OF THE NITROSYLIUM ION IN SPACE , 2014, 1409.2126.

[248]  M. Strandberg,et al.  The microwave spectrum of ketene , 1952 .

[249]  P. Goldsmith,et al.  Population Diagram Analysis of Molecular Line Emission , 1999 .

[250]  E. Gottlieb,et al.  Detection of interstellar ethyl cyanide , 1977 .

[251]  The Rotational Spectrum of Propene: Internal Rotation Analysis and ab Initio and Experimental Centrifugal Distortion Constants , 1994 .

[252]  T. Phillips,et al.  Exotic fluoride molecules in IRC +10216: Confirmation of AlF and searches for MgF and CaF , 1994 .

[253]  T. Amano Extended negative glow and "hollow anode" discharges for submillimeter-wave observation of CN-, C2H-, and C4H-. , 2008, The Journal of chemical physics.

[254]  Y. Endo,et al.  Detection of the triplet HC4N radical by Fourier transform microwave spectroscopy , 1999 .

[255]  H. Kroto,et al.  The detection of HC 9 N in interstellar space. , 1978 .

[256]  J. Ball,et al.  Microwave Detection of Interstellar Formic Acid , 1971 .

[257]  P. Thaddeus,et al.  Detection of the C4H radical toward IRC plus 10216 , 1978 .

[258]  G. R. Gunther-Mohr,et al.  HYPERFINE STRUCTURE IN THE SPECTRUM OF N¹⁴H. I. EXPERIMENTAL RESULTS , 1954 .

[259]  P. Caselli,et al.  Detection of H2D+: Measuring the Midplane Degree of Ionization in the Disks of DM Tauri and TW Hydrae , 2004 .

[260]  A. Belloche,et al.  First interstellar detection of OH , 2010, 1004.2627.

[261]  D. Despois,et al.  Laboratory spectroscopy of methoxymethanol in the millimeter-wave range. , 2018, Physical chemistry chemical physics : PCCP.

[262]  K. Rao,et al.  Infrared combination bands of 12C2H2 involving 0000011 state , 1973 .

[263]  S. Novick,et al.  Detection and Characterization of the Cumulene Carbenes H2C5 and H2C6 , 1997, Science.

[264]  K. Meiwes-Broer,et al.  Infrared-active vibrational modes in C70 fullerene , 1995 .

[265]  A. Tielens The Physics and Chemistry of the Interstellar Medium , 2005 .

[266]  K. Kawaguchi,et al.  Diode laser study of the ν2 band of the methyl radical , 1981 .

[267]  Patrick Thaddeus,et al.  Laboratory detection of propadienylidene, H2CCC , 1990 .

[268]  T. Steimle,et al.  Detection of Sodium Cyanide (NaCN) in IRC 10216 , 1994 .

[269]  S. Saito,et al.  Hyperfine interactions and Λ-type doubling in the microwave spectrum of the NS radical , 1969 .

[270]  Bruce Macintosh,et al.  SIMULTANEOUS DETECTION OF WATER, METHANE, AND CARBON MONOXIDE IN THE ATMOSPHERE OF EXOPLANET HR 8799 b , 2015, 1503.03539.

[271]  L. Ziurys Detection of interstellar PN: the first phosphorus-bearing species observed in molecular clouds. , 1987, The Astrophysical journal.

[272]  J. Goicoechea,et al.  Far-infrared Detection of C3 in Sagittarius B2 and IRC +10216 , 2000, The Astrophysical journal.

[273]  J. Tennyson,et al.  A computed room temperature line list for phosphine , 2013, 1302.1997.

[274]  W. Meerts,et al.  High-resolution molecular-beam spectroscopy of NaCN and Na13CN , 1984 .

[275]  D. Horne,et al.  DETECTION OF CH4 IN THE GV TAU N PROTOPLANETARY DISK , 2013 .

[276]  Michael C. McCarthy,et al.  Laboratory and Astronomical Identification of the Negative Molecular Ion C6H– , 2006 .

[277]  P. Friberg,et al.  Interstellar C3N - Detection in Taurus dark clouds , 1980 .

[278]  Jiangshui Zhang,et al.  Deep millimeter spectroscopy observations toward NGC 1068 , 2018 .

[279]  J. Cernicharo,et al.  Detection of the Linear Radical HC4N in IRC +10216 , 2004, astro-ph/0410657.

[280]  J. Whiteoak,et al.  Discovery of interstellar methyl formate , 1975 .

[281]  N. Kaifu,et al.  Detection of Interstellar Methylamine , 1974 .

[282]  L. Mundy,et al.  Detection of interstellar CO/+/ toward OMC-1 , 1981 .

[283]  B. Macintosh,et al.  CLOUDS AND CHEMISTRY IN THE ATMOSPHERE OF EXTRASOLAR PLANET HR8799b , 2011, 1103.3895.

[284]  A. Fuente,et al.  DETECTION OF THE AMMONIUM ION IN SPACE , 2013, 1306.3364.

[285]  H. Müller,et al.  The rotational spectrum of the SH+ radical in its X3Σ− state , 2009 .

[286]  William H. Kirchhoff,et al.  On the calculation and interpretation of centrifugal distortion constants: A statistical basis for model testing: The calculation of the force field , 1972 .

[287]  Timothy A. Davis,et al.  THE 2014 ALMA LONG BASELINE CAMPAIGN: AN OVERVIEW , 2015 .

[288]  Anthony Remijan,et al.  Cyclopropenone (c-H2C3O): A New Interstellar Ring Molecule , 2006 .

[289]  K. Menten,et al.  Pure rotational spectra of TiO and TiO2 in VY Canis Majoris , 2013, 1301.4344.

[290]  J. Cernicharo,et al.  DISCOVERY OF METHYL ACETATE AND GAUCHE ETHYL FORMATE IN ORION , 2013, 1305.1135.

[291]  M. DiSanti,et al.  THE VOLATILE COMPOSITION OF COMET C/2003 K4 (LINEAR) AT NEAR-IR WAVELENGTHS—COMPARISONS WITH RESULTS FROM THE NANÇAY RADIO TELESCOPE AND FROM THE ODIN, SPITZER, AND SOHO SPACE OBSERVATORIES , 2015 .

[292]  E. Gottlieb,et al.  Laboratory detection of the C3N an C4H free radicals , 1983 .

[293]  D. Walton,et al.  The microwave spectrum of cyanohexatriyne, HCCCCCCCN , 1980 .

[294]  T. Phillips,et al.  Detection of the interstellar NH2 radical , 1993 .

[295]  L. F. Thomas,et al.  The microwave spectrum and structure of methyl diacetylene , 1955 .

[296]  R. Woods,et al.  Microwave absorption spectrum of the CO + ion , 1975 .

[297]  P. Godfrey,et al.  The rotation-inversion spectrum of ketenimine, H2CCNH , 1986 .

[298]  J. M. Hollis,et al.  Hyperfine Structure Identification of Interstellar Cyanoallene toward TMC-1 , 2006 .

[299]  A. Dutrey,et al.  Deuterated molecules in DM Tauri: DCO$^+$, but no HDO , 2006, astro-ph/0602396.

[300]  J. P. McMillan,et al.  An analysis of a preliminary ALMA Orion KL spectrum via the use of complete experimental spectra from the laboratory , 2012 .

[301]  J. Montgomery,et al.  Tentative identification of U93.174 as the molecular ion N2H/+/. [interstellar microwave spectroscopy , 1974 .

[302]  P. Friberg,et al.  A new interstellar molecule: triearbon monoxide , 1984, Nature.

[303]  Patrick Thaddeus,et al.  Astronomical detection of H2CCC , 1991 .

[304]  L. Testi,et al.  First Detection of the Simplest Organic Acid in a Protoplanetary Disk , 2018, The Astrophysical Journal.

[305]  S. Saito,et al.  Microwave spectroscopy of isotopically substituted HCCN and its molecular structure , 1990 .

[306]  W. Gordy,et al.  Millimeter Wave Rotational Spectrum and Molecular Constants of 31P14N , 1972 .

[307]  A. Fuente,et al.  IMPROVED DETERMINATION OF THE 10–00 ROTATIONAL FREQUENCY OF NH3D+ FROM THE HIGH-RESOLUTION SPECTRUM OF THE ν4 INFRARED BAND , 2013, 1306.3792.

[308]  Jane Huang,et al.  Detecting Weak Spectral Lines in Interferometric Data through Matched Filtering , 2018, 1803.04987.

[309]  L. Ziurys,et al.  Detection of the CCP Radical (X2Πr) in IRC +10216: A New Interstellar Phosphorus-containing Species , 2008 .

[310]  The rQ1 branch of carbodiimide, HNCNH, at 1.1 THz , 1997 .

[311]  Arno A. Penzias,et al.  CARBON MONOXIDE IN THE ORION NEBULA. , 1970 .

[312]  G. Blake,et al.  Chlorine in dense interstellar clouds : the abundance of HCl in OMC-1. , 1985 .

[313]  S. Ridgway,et al.  Circumstellar acetylene in the infrared spectrum of IRC +10° 216 , 1976, Nature.

[314]  B. Turner Microwave detection of interstellar ketene. , 1977 .

[315]  J. Cernicharo,et al.  New molecules in IRC +10216: confirmation of C5S and tentative identification of MgCCH, NCCP, and SiH3CN , 2014, 1408.6306.

[316]  M. Mizushima,et al.  Microwave Resonance Lines of 16 O 2 in Its Electronic Ground State (X 3 Σ g , 1982 .

[317]  W. Klemperer Carrier of the Interstellar 89.190 GHz Line , 1970, Nature.

[318]  F. Delucia,et al.  Molecular-Beam Maser for the Shorter-Millimeter-Wave Region: Spectral Constants of HCN and DCN , 1969 .

[319]  Koichi M. T. Yamada,et al.  The High-Resolution Spectra of the ν11 Band of Triacetylene near 622 cm−1: Revised Assignments for Hot Bands , 1994 .

[320]  G. Swenson,et al.  MICROWAVE DETECTION OF INTERSTELLAR FORMAMIDE. , 1971 .

[321]  The pure rotational spectra of TiO(X3Δ) and TiN(X2Σ , 1998 .

[322]  J. Anderson,et al.  The millimeter-wave spectrum of CCN (X ∼ 2Πr): A combined Fourier transform and direct absorption study , 2015 .

[323]  Astrophysics,et al.  Chemistry in disks , 2012, Astronomy & Astrophysics.

[324]  Feuchtgruber,et al.  Detection of Interstellar CH3. , 2000, The Astrophysical journal.

[325]  J. Whiteoak,et al.  Physical Sciences: Detection of formaldehyde in external galaxies , 1974, Nature.

[326]  L. Ziurys,et al.  A Search for Phosphine in Circumstellar Envelopes: PH3 in IRC +10216 and CRL 2688? , 2008 .

[327]  O. Krause,et al.  Detection of a Noble Gas Molecular Ion, 36ArH+, in the Crab Nebula , 2013, Science.

[328]  J. Cernicharo,et al.  Detection of C5N− and Vibrationally Excited C6H in IRC +10216 , 2008, 0810.2729.

[329]  K. Menten,et al.  Interstellar HOCN in the Galactic center region , 2010, 1005.2489.

[330]  R. Linke,et al.  Interstellar isothiocyanic acid , 1979 .

[331]  R. Linke,et al.  Three new 'nonterrestrial' molecules , 1981 .

[332]  R. J. Myers,et al.  Microwave Spectrum, Structure, and Internal Rotation of Dimethyl Ether , 1959 .

[333]  Paul H. Krupenie,et al.  The spectrum of molecular nitrogen , 1977 .

[334]  P. Bernath,et al.  Detection of C5 in the Circumstellar Shell of IRC+10216 , 1988, Science.

[335]  G. Savini,et al.  Black hole accretion and star formation as drivers of gas excitation and chemistry in Markarian 231 , 2010, 1005.2877.

[336]  G. Plass,et al.  Vibrational Energies of the CO2 Molecule , 1962 .

[337]  N. Fourikis,et al.  Detection of interstellar thioformaldehyde , 1973 .

[338]  E. F. Pearson,et al.  Millimeter and Submillimeter Wave Spectrum and Molecular Constants of Aluminum Monofluoride , 1970 .

[339]  S. Ioppolo,et al.  Experimental evidence for glycolaldehyde and ethylene glycol formation by surface hydrogenation of CO molecules under dense molecular cloud conditions , 2015, 1705.09235.

[340]  G. Winnewisser,et al.  The millimeter wave spectrum of cyanoallene, CH2CCHCN, using a new digital lock-in technique , 1986 .

[341]  J. López,et al.  Preferred conformers of proteinogenic glutamic acid. , 2012, Journal of the American Chemical Society.

[342]  M. Strandberg,et al.  Stark Spectrum of H 2 O , 1948 .

[343]  R. Dixon THE 0–0 AND 1–0 BANDS OF THE A(3Πi)–X(3Σ−) SYSTEM OF NH , 1959 .

[344]  L. Ziurys,et al.  EXOTIC METAL MOLECULES IN OXYGEN-RICH ENVELOPES: DETECTION OF AlOH (X1Σ+) IN VY CANIS MAJORIS , 2010 .

[345]  Jonathan Tennyson,et al.  Water vapour in the atmosphere of a transiting extrasolar planet , 2007, Nature.

[346]  Mark Clampin,et al.  INFRARED TRANSMISSION SPECTROSCOPY OF THE EXOPLANETS HD 209458b AND XO-1b USING THE WIDE FIELD CAMERA-3 ON THE HUBBLE SPACE TELESCOPE , 2013, 1302.1141.

[347]  E. Herbst,et al.  Gauche Ethyl Alcohol: Laboratory Assignments and Interstellar Identification , 1997 .

[348]  S. Kalenskii,et al.  Detection of Interstellar HC5O in TMC-1 with the Green Bank Telescope , 2017, 1706.09766.

[349]  R. Trotta,et al.  BAHAMAS: NEW ANALYSIS OF TYPE Ia SUPERNOVAE REVEALS INCONSISTENCIES WITH STANDARD COSMOLOGY , 2015, 1510.05954.

[350]  J. Cernicharo,et al.  Detection of MgCN in IRC +10216: A New Metal-bearing Free Radical , 1995 .

[351]  Benjamin J. McCall,et al.  Diffuse Atomic and Molecular Clouds , 2006 .

[352]  Michael C. McCarthy,et al.  Detection of the aromatic molecule benzonitrile (c-C6H5CN) in the interstellar medium , 2018, Science.

[353]  Kenneth M. Evenson,et al.  Accurate rotational constants of CO, HCl, and HF: Spectral standards for the 0.3- to 6-THz (10- to 200-cm−1) region , 1987 .

[354]  K. Kawaguchi,et al.  Detection of Isocyanoacetylene HCCNC in TMC-1 , 1992 .

[355]  J. M. Hollis,et al.  Detection of interstellar N2O: A new molecule containing an N-O bond , 1994 .

[356]  P. Schilke,et al.  Discovery of interstellar CF , 2006, astro-ph/0603201.

[357]  P. Verhoeve,et al.  Submillimeter spectroscopy on OH(+) - The rotational transition at 1 THz , 1985 .

[358]  H. Kroto,et al.  Detection of the heavy interstellar molecule cyanodiacetylene. , 1976 .

[359]  S. Saito Microwave spectrum of the HO2 radical , 1977 .

[360]  T. Dunham,et al.  INTERSTELLAR NEUTRAL POTASSIUM AND NEUTRAL CALCIUM , 1937 .

[361]  John C. Pearson,et al.  Detection of the Water Reservoir in a Forming Planetary System , 2011, Science.

[362]  J. Gallagher,et al.  Uncoupling Effects in the Microwave Spectrum of Nitric Oxide , 1956 .

[363]  Patrick Thaddeus,et al.  Laboratory detection of a second carbon chain carbene - Butatrienylidene, H2CCCC , 1990 .

[364]  G. Winnewisser,et al.  The microwave spectrum and centrifugal distortion constants of vinyl cyanide , 1973 .

[365]  J. M. Serna,et al.  Probing non polar interstellar molecules through their protonated form: Detection of protonated cyanogen (NCCNH+). , 2015, Astronomy and astrophysics.

[366]  D. Buhl,et al.  An Interstellar Emission Line from Isocyanic Acid at 1.4 Centimeters , 1972 .

[367]  F. Lahuis,et al.  H2O and OH Gas in the Terrestrial Planet-forming Zones of Protoplanetary Disks , 2008, 0802.0037.

[368]  W. H. Hocking,et al.  The Other Rotamer of Formic Acid, cis-HCOOH1 , 1976 .

[369]  A. Apponi,et al.  Microwave Detection of Interstellar Vinyl Alcohol, CH2=CHOH , 2001 .

[370]  S. Saito,et al.  The microwave spectrum of the SiN(2Σ+) radical , 1983 .

[371]  C. Joblin,et al.  UNVEILING THE DUST NUCLEATION ZONE OF IRC+10216 WITH ALMA , 2013, 1310.7383.

[372]  O. Berné,et al.  Interstellar C 60 , 2012, 1211.7252.

[373]  S. Civiš,et al.  Millimetre-wave laboratory detection of H2COH+ , 1994 .

[374]  R. Wilson,et al.  Interstellar hydrogen sulfide. , 1972 .

[375]  Northern Arizona University,et al.  CONTINUUM AND CO/HCO + EMISSION FROM THE DISK AROUND THE T TAURI STAR LkCa 15 , 2003, astro-ph/0307246.

[376]  D. Walton,et al.  The microwave spectrum, substitution structure and dipole moment of cyanobutadiyne, HCCCCCN , 1976 .

[377]  J. Black,et al.  Detection of extragalactic CF+ toward PKS1830-211 -- Chemical differentiation in the absorbing gas , 2016, 1604.00414.

[378]  G. Herzberg,et al.  Note on CH^{+} in Interstellar Space and in the Laboratory. , 1941 .

[379]  K. Menten,et al.  Detection of a branched alkyl molecule in the interstellar medium: iso-propyl cyanide , 2014, Science.

[380]  The Interstellar Medium of IRAS 08572+3915 NW: H3+ and Warm High-Velocity CO , 2006, astro-ph/0603041.

[381]  R. Wilson,et al.  Observation of the CN Radical in the Orion Nebula and W51 , 1970 .

[382]  Brati Sankar Ray Über die Eigenwerte des asymmetrischen Kreisels , 1932 .

[383]  Cornell University,et al.  Increased complexity in interstellar chemistry: detection and chemical modeling of ethyl formate and n-propyl cyanide in Sagittarius B2(N) , 2009, 0902.4694.

[384]  V. Kaushik Centrifugal distortion effect in the microwave spectrum of vinyl alcohol , 1977 .

[385]  F. Scappini,et al.  Millimeter‐wave laboratory detection of HNCCN+ , 1991 .

[386]  John M. Brown,et al.  The microwave spectrum of the CH free radical , 1983 .

[387]  Demaison,et al.  Analysis of the Rotational Spectra of SiH3CN and Its Isotopomers: Experimental and Ab Initio Determinations of the Dipole Moment and the Structure. , 1998, Journal of molecular spectroscopy.

[388]  B. Turner DETECTION OF INTERSTELLAR CYANOACETYLENE. , 1971 .

[389]  A. Walsh,et al.  The Astrophysical Journal Supplement , 2020 .

[390]  B. Drouin,et al.  Determination of precise relative energies of conformers of n-propanol by rotational spectroscopy. , 2010, Physical chemistry chemical physics : PCCP.

[391]  P. Hennebelle,et al.  Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6–0.4 , 2010, 1005.5653.

[392]  J. M. Hollis,et al.  Green Bank Telescope Detection of New Interstellar Aldehydes: Propenal and Propanal , 2004 .

[393]  J. Burie,et al.  The rotational spectrum of acetone: Internal rotation and centrifugal distortion analysis , 1986 .

[394]  S. Saito,et al.  The microwave spectrum of a triplet carbene: HCCN in the X 3Σ− state , 1984 .

[395]  P. Caselli,et al.  Discovery of Deuterated Water in a Young Protoplanetary Disk , 2005 .

[396]  T. Amano Laboratory detection of CH3CNH(+) by infrared difference frequency laser spectroscopy , 1987 .

[397]  E. Chaisson,et al.  Molecules in the Galactic Environment , 1975 .

[398]  K. Kawaguchi,et al.  Laboratory Spectroscopy of MgNC: The First Radioastronomical Identification of Mg-bearing Molecule , 1993 .

[399]  Anthony J. Remijan,et al.  Detection of C8H– and Comparison with C8H toward IRC +10 216 , 2007 .

[400]  E. Seaquist,et al.  Detection of the hydrocarbon ring molecule C3H2 in the radio galaxy Centaurus A (=NGC 5128) , 1986 .

[401]  J. Cernicharo,et al.  Laboratory and Astronomical Detection of the Negative Molecular Ion C3N− , 2008 .

[402]  N. Fourikis,et al.  Microwave Emission of the 211?212 Rotational Transition in Interstellar Acetaldehyde , 1974 .

[403]  D. Buhl,et al.  Unidentified Interstellar Microwave Line , 1970, Nature.

[404]  P. Botschwina,et al.  Carbon chains of type C2n+1N(-) (n=2-6): A theoretical study of potential interstellar anions. , 2008, The Journal of chemical physics.

[405]  C. Kramer,et al.  Herschel / HIFI : first science highlights Special feature L etter to the E ditor HIFI spectroscopy of low-level water transitions in M 82 , 2010 .

[406]  J. G. Phillips A New Band System of the C_{2} Molecule. , 1948 .

[407]  T. Törring Notizen: Das Mikrowellenrotationsspektrum des SiO , 1968 .

[408]  A. Belloche,et al.  The IRAM-30 m line survey of the Horsehead PDR - II. First detection of the l-C3H+ hydrocarbon cation , 2012, 1210.8178.

[409]  N. Evans,et al.  HOT ORGANIC MOLECULES TOWARD A YOUNG LOW-MASS STAR: A LOOK AT INNER DISK CHEMISTRY , 2005, astro-ph/0511786.

[410]  N. H. Williams,et al.  Electromagnetic Waves of 1.1 cm Wave-Length and the Absorption Spectrum of Ammonia , 1934 .

[411]  W. Schade,et al.  The 14N quadrupole hyperfine structure in the rotational spectrum of laser vaporized urea observed by molecular beam Fourier transform microwave spectroscopy , 1996 .

[412]  G. Blake,et al.  Resolving the Chemistry in the Disk of TW Hydrae. I. Deuterated Species , 2008, 0803.2753.

[413]  B. Turner Detection of interstellar SO+ : a diagnostic of dissociative shock chemistry , 1992 .

[414]  R. Brown,et al.  Tricarbon monoxide in TMC-1. , 1985, Astrophysical Journal.

[415]  T. Shigenari Magnetic Hyperfine Structure and Zeeman Effect of the J=1, K-1=1 Transition of H2CO , 1967 .

[416]  P. Swings,et al.  Considerations Regarding Interstellar Molecules , 1937 .

[417]  L. Ziurys,et al.  Millimeter-wave rotational spectroscopy of FeCN (X 4Δi) and FeNC (X 6Δi): determining the lowest energy isomer. , 2011, The Journal of chemical physics.

[418]  P. Mürtz,et al.  Measurement of high-frequency rotational transitions of H2O+ in its ground state by far-infrared laser magnetic resonance (LMR) spectroscopy , 1998 .

[419]  J. Burie,et al.  Millimeter-wave spectrum of methylcyanoacetylene , 1982 .

[420]  R. Suenram,et al.  Laboratory measurement of the 4(04)-3(13) 70 GHz transition of ground-state methylene (CH2) , 1983 .

[421]  J. M. Hollis,et al.  A search for methylene in the Orion nebula , 1989 .

[422]  L. Ziurys,et al.  DETECTION OF A NEW INTERSTELLAR MOLECULE: THIOCYANIC ACID HSCN , 2009 .

[423]  E. Chapillon,et al.  First detection of H$_2$S in a protoplanetary disk. The dense GG Tau A ring. , 2018, 1808.00652.

[424]  Y. Endo,et al.  The submillimeter‐wave spectrum of the HCCO radical , 1987 .

[425]  Joana M. Oliveira,et al.  The Detection of Hot Cores and Complex Organic Molecules in the Large Magellanic Cloud , 2018, 1801.10275.

[426]  M. Kappes,et al.  IR absorptions of C60(+) and C60(-) in neon matrixes. , 2013, The journal of physical chemistry. A.

[427]  S. Schlemmer,et al.  LABORATORY ROTATIONAL SPECTRUM OF l–C3H+ AND CONFIRMATION OF ITS ASTRONOMICAL DETECTION , 2014 .

[428]  Drake Deming,et al.  Possible thermochemical disequilibrium in the atmosphere of the exoplanet GJ 436b , 2010, Nature.

[429]  Patrick Thaddeus,et al.  Laboratory and astronomical spectroscopy of C3H2, the first interstellar organic ring , 1987 .

[430]  A. Apponi,et al.  Rhomboidal SiC 3 , 1999 .

[431]  R. Wilson,et al.  Detection of Millimeter Emission Lines from Interstellar Methyl Cyanide , 1971 .

[432]  M. J. Stevenson,et al.  Ground State Λ-Doubling Transitions of OH Radical , 1959 .

[433]  K. Menten,et al.  Exploring Molecular Complexity with ALMA (EMoCA): Deuterated complex organic molecules in Sagittarius B2(N2) , 2015, 1511.05721.

[434]  Donald R. Johnson,et al.  Microwave Detection of Thioformaldehyde , 1970, Science.

[435]  K. Kawaguchi,et al.  Microwave spectroscopy of the NCO radical in the ?2 = 0 ?, ?2 = 1 ?, and ?2 = 2 F vibronic states , 1985 .

[436]  C. J. Howard,et al.  The microwave spectrum of HO2 near 65 GHz , 1975 .

[437]  G. Herzberg,et al.  Analysis of the 4050-Å Group of the C_{3} Molecule. , 1965 .

[438]  C. Kramer,et al.  Discovery of methyl silane and confirmation of silyl cyanide in IRC +10216. , 2017, Astronomy and astrophysics.

[439]  J. Silverman,et al.  A HIGHER EFFICIENCY OF CONVERTING GAS TO STARS PUSHES GALAXIES AT z ∼ 1.6 WELL ABOVE THE STAR-FORMING MAIN SEQUENCE , 2015, 1505.04977.

[440]  W. Gordy,et al.  The Microwave Spectrum and Structure of Methyl Acetylene , 1950 .

[441]  K. Takagi,et al.  Laboratory Microwave Spectrum of Methylamine , 1973 .

[442]  Geoffrey A. Blake,et al.  NEAR-IR DIRECT DETECTION OF WATER VAPOR IN TAU BOÖTIS b , 2014 .

[443]  O. Berné,et al.  Molecular content of the circumstellar disk in AB Aurigae - First detection of SO in a circumstellar disk , 2010, 1009.5597.

[444]  J. Stanton,et al.  Discovery of a Missing Link: Detection and Structure of the Elusive Disilicon Carbide Cluster. , 2015, The journal of physical chemistry letters.

[445]  S. Yamamoto,et al.  Submillimeter-wave spectra of HCS and DCS , 2002 .

[446]  G. Winnewisser,et al.  Detection of formic acid in Sagittarius B2 by its 2/11/-2/12/ transition , 1975 .

[447]  A. Bauder,et al.  Molecular structure of s-cis- and s-trans-acrolein determined by microwave spectroscopy , 1984 .

[448]  B. Zuckerman,et al.  Detection of interstellar SiS and a study of the IRC + 10216 molecular envelope , 1975 .

[449]  W. Graham,et al.  C2H radical: 13C hyperfine interaction and optical spectrum , 1974 .

[450]  O. E. H. RYDBECK,et al.  Radio Detection of Interstellar CH , 1973, Nature.

[451]  E. Bergin,et al.  HERSCHEL OBSERVATIONS OF EXTRAORDINARY SOURCES: ANALYSIS OF THE FULL HERSCHEL/HIFI MOLECULAR LINE SURVEY OF SAGITTARIUS B2(N) , 2014, 1405.0706.

[452]  R. Garrod,et al.  Complex Chemistry in Star-forming Regions: An Expanded Gas-Grain Warm-up Chemical Model , 2008, 0803.1214.

[453]  S. Saito,et al.  Microwave spectrum of nitroxyl , 1973 .

[454]  Rotational spectroscopy, dipole moment and 14N nuclear hyperfine structure of iso-propyl cyanide , 2011, 1102.5675.

[455]  E. Tiemann,et al.  Microwave Spectral Tables I. Diatomic Molecules , 1974 .

[456]  Stony Brook University,et al.  A sensitive survey for 13CO, CN, H2CO, and SO in the disks of T Tauri and Herbig Ae stars , 2012, 1211.4776.

[457]  R. Garrod,et al.  Protostellar and cometary detections of organohalogens , 2017, Nature Astronomy.

[458]  P. Encrenaz,et al.  CONFIRMATION OF CIRCUMSTELLAR PHOSPHINE , 2014, 1407.1192.

[459]  L. Decin,et al.  Constraints on Metal Oxide and Metal Hydroxide Abundances in the Winds of AGB Stars: Potential Detection of FeO in R Dor , 2018, 1801.09302.

[460]  K. Kawaguchi,et al.  The microwave spectrum of the CP radical and related astronomical search , 1989 .

[461]  M. D. Allen,et al.  The millimeter-wave spectrum of FeO in its X5Δi state (v = 0): a study of all five spin components , 1996 .

[462]  G. Winnewisser,et al.  The detection of interstellar vinyl cyanide (acrylonitrile). , 1975 .

[463]  D. Deming,et al.  SPECTROSCOPIC EVIDENCE FOR A TEMPERATURE INVERSION IN THE DAYSIDE ATMOSPHERE OF HOT JUPITER WASP-33b , 2015, 1505.01490.

[464]  M. Crofton,et al.  Observation of the infrared ν2 band (CH stretch) of protonated hydrogen cyanide HCNH , 1984 .

[465]  A. Tielens,et al.  Solid Carbonyl Sulfide (OCS) in Dense Molecular Clouds , 1997 .

[466]  B. Lutz,et al.  Detection of C 2 in the interstellar spectrum of Cygnus OB2 Number 12 (IV Cygni Number 12). , 1977 .

[467]  L. Brown,et al.  Analysis of the ?2/?4 dyad of 12CH4 and 13CH41 , 1989 .

[468]  J. Ball,et al.  Interstellar sulfur monoxide , 1973 .

[469]  P. Thaddeus,et al.  Confirmation of interstellar N2H , 1975 .

[470]  R. Wiens,et al.  VARIATIONS IN SOLAR WIND FRACTIONATION AS SEEN BY ACE/SWICS AND THE IMPLICATIONS FOR GENESIS MISSION RESULTS , 2015, 1508.04566.

[471]  C. Kramer,et al.  Lambda = 3 mm line survey of nearby active galaxies , 2015, 1504.03743.

[472]  P. Goldsmith,et al.  The [HCO+]/[HOC+] abundance ratio in molecular clouds , 1983 .

[473]  A. Walters,et al.  Millimeter-Wave Spectroscopy of PO in Excited Vibrational States up to v=7 , 2002 .

[474]  J. Cernicharo,et al.  Astronomical detection of C$\mathsf{_{4}H^-}$, the second interstellar anion , 2007 .

[475]  P. Schilke,et al.  Detection of FeO toward Sagittarius B2 , 2002, astro-ph/0201311.

[476]  E. W. McDaniel,et al.  On the Possible Occurence of H 3 ^{+} in Interstellar Space. , 1961 .

[477]  Walter Gordy,et al.  Microwave Spectra and Molecular Structures of Methyl Cyanide and Methyl Isocyanide , 1950 .

[478]  D. Lis,et al.  Deep, Broadband Spectral Line Surveys of Molecule-rich Interstellar Clouds , 2017 .

[479]  D. Collins,et al.  THE RAZOR’S EDGE OF COLLAPSE: THE TRANSITION POINT FROM LOGNORMAL TO POWER-LAW DISTRIBUTIONS IN MOLECULAR CLOUDS , 2016, 1609.04409.

[480]  H. Müller Spectroscopic parameters of phosphine, PH3, in its ground vibrational state , 2013 .

[481]  R. Lees,et al.  Millimetre wave spectrum of methyl mercaptan , 1980 .

[482]  N. Evans,et al.  HIGH-RESOLUTION MID-INFRARED SPECTROSCOPY OF NGC 7538 IRS 1: PROBING CHEMISTRY IN A MASSIVE YOUNG STELLAR OBJECT , 2009, 0902.0610.

[483]  A. Apponi,et al.  Rotational Spectra of Sulfur-Carbon Chains. I. The Radicals C4S, C5S, C6S, C7S, C8S, and C9S , 2001 .

[484]  B. Drouin,et al.  Herschel/HIFI Discovery of HCL^+ in the Interstellar Medium , 2012 .

[485]  J. Brooks,et al.  Evidence for weak maser action in interstellar cyanodiacetylene , 1976 .

[486]  H. Liszt Upper limits on the abundance of the sulfur dimer in molecular clouds , 1978 .

[487]  D. Lide,et al.  Microwave spectrum and nonplanarity of cyanamide , 1962 .

[488]  L. Rickard,et al.  Detection of extragalactic carbon monoxide at millimeter wavelengths , 1975 .

[489]  J. Cernicharo,et al.  Microwave and submillimeter spectroscopy and first ISM detection of 18O-methyl formate , 2012 .

[490]  R. Woods,et al.  The laboratory microwave spectrum of the cyanide radical in its X 2Σ+ ground state , 1999 .

[491]  J. M. Hollis,et al.  Confirmation of Interstellar Methylcyanodiacetylene (CH3C5N) , 2006 .

[492]  George R. Carruthers,et al.  Rocket observation of interstellar molecular hydrogen , 1970 .

[493]  P. Siegbahn,et al.  Theoretical investigation of protonated carbon dioxide , 1976 .

[494]  D. Buhl,et al.  MICROWAVE DETECTION OF INTERSTELLAR FORMALDEHYDE. , 1969 .

[495]  Arnaud Belloche,et al.  Complex organic molecules in the interstellar medium: IRAM 30 m line survey of Sagittarius B2(N) and (M) , 2013, 1308.5062.

[496]  C. Walsh,et al.  Methanol formation in TW Hya and future prospects for detecting larger complex molecules in disks with ALMA , 2017, Proceedings of the International Astronomical Union.

[497]  Michael C. McCarthy,et al.  THE DETECTION OF INTERSTELLAR ETHANIMINE (CH3CHNH) FROM OBSERVATIONS TAKEN DURING THE GBT PRIMOS SURVEY , 2013 .

[498]  P. Thaddeus,et al.  Laboratory Detection of the C7H Radical , 1996 .

[499]  F. Lovas,et al.  Microwave detection of the molecular transient methyleneimine (CH2=NH) , 1972 .

[500]  E. Cohen,et al.  The microwave spectrum of the AlO radical , 1990 .

[501]  Rodger I. Thompson,et al.  The 2 - 2.5 micron spectrum of NGC 1068: a detection of extragalactic molecular hydrogen. , 1978 .

[502]  G. Winnewisser,et al.  The ground state of ketene , 1972 .

[503]  B. Pate,et al.  Laboratory and tentative interstellar detection of trans-methyl formate using the publicly available Green Bank Telescope PRIMOS survey , 2012, 1206.6021.

[504]  M. Winnewisser,et al.  The millimeter wave spectra of isocyanic and isothiocyanic acids , 1963 .

[505]  È. Roueff,et al.  DISCOVERY OF FULMINIC ACID, HCNO, IN DARK CLOUDS , 2008, 0811.2679.

[506]  Geronimo L. Villanueva,et al.  Discovery of OH in Circumstellar Disks around Young Intermediate-Mass Stars , 2008, 0805.3502.

[507]  W. J. Lafferty,et al.  Laboratory microwave spectrum of cyanamide , 1976 .

[508]  L. Ziurys,et al.  Detection of A New Interstellar Molecular Ion, H2COH+ (Protonated Formaldehyde) , 1996, The Astrophysical journal.

[509]  R. Cupp,et al.  Hyperfine Structure in the Millimeter Spectrum of Hydrogen Sulfide: Electric Resonance Spectroscopy on Asymmetric-Top Molecules , 1968 .

[510]  G. Walker,et al.  IDENTIFICATION OF MORE INTERSTELLAR C 60 + ?> BANDS , 2015, 1509.06818.

[511]  Y. Kasai,et al.  Laboratory Detection of the C5N Radical by Fourier Transform Microwave Spectroscopy , 1997 .

[512]  J. Demaison,et al.  Microwave spectrum of cyanoallene , 1973 .

[513]  E. Fayolle,et al.  CO2 INFRARED PHONON MODES IN INTERSTELLAR ICE MIXTURES , 2016, 1610.00294.

[514]  Michaeleen R. Munrow,et al.  Microwave Spectra of the Methylcyanopolyynes CH3(CC)nCN,n= 2, 3, 4, 5☆ , 1998 .

[515]  R. C. Benson,et al.  Microwave spectrum, substitutional structure, and Stark and Zeeman effects in cyclopropenone , 1973 .

[516]  S. Martín,et al.  A 2 Millimeter Spectral Line Survey of the Starburst Galaxy NGC 253 , 2006 .

[517]  J. Storey,et al.  The microwave spectrum of urea , 1975 .

[518]  K. Menten,et al.  Erratum: Detection of amino acetonitrile in Sgr B2(N) , 2008, 0801.3219.

[519]  E. Herbst,et al.  The millimeter and submillimeter spectrum of CF( , 1986 .

[520]  E. Herbst,et al.  Complex Organic Interstellar Molecules , 2009 .

[521]  K. Kawaguchi,et al.  The Laboratory Spectrum of the PS Radical and Related Astronomical Search , 1988 .

[522]  N. Kaifu,et al.  Microwave detection of interstellar cyanamide , 1971 .

[523]  Neal J. Evans,et al.  Discovery of interstellar methane - Observations of gaseous and solid CH4 absorption toward young stars in molecular clouds , 1991 .

[524]  E. Herbst,et al.  Laboratory millimeter and submillimeter spectra of HNO and DNO , 1984 .

[525]  A. D. McLean,et al.  Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible? , 1991, The Astrophysical journal.

[526]  T. Henning,et al.  Chemistry in disks. I. Deep search for N2H+ in the protoplanetary disks around LkCa 15, MWC 480, and DM Tauri , 2006, astro-ph/0612534.

[527]  A. Betz Ethylene in IRC+10216 , 1981 .

[528]  Yoshiaki Sasada,et al.  Microwave spectrum of ethyl alcohol: The trans rotamer , 1968 .

[529]  J. Anderson,et al.  DETECTION OF CCN (X2Πr) IN IRC+10216: CONSTRAINING CARBON-CHAIN CHEMISTRY , 2014 .

[530]  C. Walker,et al.  Detection of the Carbon Monoxide Ion (CO+) in the Interstellar Medium and a Planetary Nebula , 1993 .

[531]  H. Dreizler,et al.  Notizen: A Highly Resolved Rotational Transition of Urea Measured for Radioastronomical Searches. Analysis of the Nitrogen Quadrupole Coupling , 1986 .

[532]  J. M. Hollis,et al.  Methyltriacetylene (CH3C6H) toward TMC-1: The Largest Detected Symmetric Top , 2006 .

[533]  J. Cernicharo,et al.  SPECTROSCOPIC CHARACTERIZATION AND DETECTION OF ETHYL MERCAPTAN IN ORION , 2014, 1401.7810.

[534]  A chemical route to the formation of water in circumstellar envelopes around carbon-rich asymptotic branch stars: Fischer-Tropsch catalysis , 2004 .

[535]  D. Lis,et al.  DISCOVERY OF HYDROGEN FLUORIDE IN THE CLOVERLEAF QUASAR AT z = 2.56 , 2011, 1201.4882.

[536]  G. T. Fraser,et al.  Microwave Spectra, Hyperfine Structure, and Electric Dipole Moments for Conformers I and II of Glycine , 1995 .

[537]  S. Kukolich Measurement of ammonia hyperfine structure with a two-cavity maser , 1967 .

[538]  J. Mangum,et al.  How to Calculate Molecular Column Density , 2015, 1501.01703.

[539]  E. Bergin,et al.  First detection of gas-phase ammonia in a planet-forming disk , 2016, 1604.00323.

[540]  J. M. Hollis,et al.  OBSERVATIONAL RESULTS OF A MULTI-TELESCOPE CAMPAIGN IN SEARCH OF INTERSTELLAR UREA [(NH2)2CO] , 2014, 1401.4483.

[541]  M. A. Brewster,et al.  Millimeter-wave spectroscopy of vibrationally-excited NaCCH (X̃1Σ+) and MgCCH (X̃2Σ+): the v5 bending mode , 1999 .

[542]  D. Hovde,et al.  Laser magnetic resonance in supersonic plasmas: The rotational spectrum of SH+ , 1987 .

[543]  S. Ioppolo,et al.  Atom addition reactions in interstellar ice analogues , 2015, 1507.02729.

[544]  K. Kawaguchi,et al.  Far‐infrared laser magnetic resonance detection and microwave spectroscopy of the PO2 radical , 1983 .

[545]  P. Ehrenfreund,et al.  Spectroscopic diagnostics of organic chemistry in the protostellar environment. , 2001, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[546]  J. M. Hollis,et al.  New interstellar molecular transitions in the 2 millimeter range , 1981 .

[547]  J. Severinghaus,et al.  A redetermination of the isotopic abundances of atmospheric Ar , 2006 .

[548]  Timothy J. Lee,et al.  SPECTROSCOPIC CONSTANTS AND VIBRATIONAL FREQUENCIES FOR l-C3H+ AND ISOTOPOLOGUES FROM HIGHLY ACCURATE QUARTIC FORCE FIELDS: THE DETECTION OF l-C3H+ IN THE HORSEHEAD NEBULA PDR QUESTIONED , 2013, 1305.1658.

[549]  M. Vala,et al.  C5 molecule: Structure and infrared frequencies , 1989 .

[550]  G. Walker,et al.  GAS PHASE ABSORPTION SPECTROSCOPY OF AND IN A CRYOGENIC ION TRAP: COMPARISON WITH ASTRONOMICAL MEASUREMENTS , 2016 .

[551]  R. Cesaroni,et al.  Formation of ethylene glycol and other complex organic molecules in star-forming regions , 2016, 1608.07491.

[552]  Frank C. De Lucia,et al.  A study of the rotational-torsional spectrum of hydrogen peroxide between 80 and 700 GHz , 1981 .

[553]  Mark R. Morris,et al.  HIGH-PRECISION C17O, C18O, AND C16O MEASUREMENTS IN YOUNG STELLAR OBJECTS: ANALOGUES FOR CO SELF-SHIELDING IN THE EARLY SOLAR SYSTEM , 2009, 0906.1024.

[554]  J. M. Hollis,et al.  Interstellar Isomers: The Importance of Bonding Energy Differences , 2005, astro-ph/0506502.

[555]  W. Meerts,et al.  Rotational spectrum and structure of KCN , 1980 .

[556]  R. Kraft,et al.  HOT GASEOUS CORONAE AROUND SPIRAL GALAXIES: PROBING THE ILLUSTRIS SIMULATION , 2015, 1503.01107.

[557]  S. Kukolich High Resolution Measurements of Hyperfine Structure in the Rotational Spectrum of CH3NC , 1972 .

[558]  Anthony J. Remijan,et al.  Detection of Acetamide (CH3CONH2): The Largest Interstellar Molecule with a Peptide Bond , 2006 .

[559]  Alexander G. G. M. Tielens,et al.  Interstellar Polycyclic Aromatic Hydrocarbon Molecules , 2008 .

[560]  FOURIER TRANSFORM FAR-INFRARED SPECTROSCOPY OF THE SH RADICAL , 1995 .

[561]  L. Ziurys,et al.  CARBON ISOTOPE FRACTIONATION AND DEPLETION IN TMC1 , 2012, 1201.0696.

[562]  Michael C. McCarthy,et al.  Detection of the Carbon Chain Negative Ion C8H– in TMC-1 , 2007 .

[563]  W. Irvine,et al.  Searches for new interstellar molecules, including a tentative detection of aziridine and a possible detection of propenal. , 2001, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[564]  Oka,et al.  Experimental determination of the ground-state inversion splitting in H3O+ , 1985, Physical review letters.

[565]  R. Puetter,et al.  The 4-8 micron spectrum of the infrared source W33 A , 1979 .

[566]  Eric Herbst,et al.  trans-Ethyl Methyl Ether: Assignments and Predictions up to 400 GHz for the Vibrational-Torsional Ground State , 2003 .

[567]  L. Rickard,et al.  Observations of extragalactic molecules. II - HCN and CS , 1977 .

[568]  T. Henning,et al.  CHEMISTRY IN DISKS. III. PHOTOCHEMISTRY AND X-RAY DRIVEN CHEMISTRY PROBED BY THE ETHYNYL RADICAL (CCH) IN DM Tau, LkCa 15, AND MWC 480 , 2010, 1003.5793.

[569]  A 2 mm spectral line survey of the starburst galaxy NGC 253 , 2006, astro-ph/0602360.

[570]  K. Kawaguchi,et al.  Detection of a new circumstellar carbon chain molecule, C4Si , 1989 .

[571]  E. Herbst,et al.  The molecular chemistry of diffuse and translucent clouds in the line-of-sight to Sgr B2: Absorption by simple organic and inorganic molecules in the GBT PRIMOS survey , 2017, 1708.03432.

[572]  È. Roueff,et al.  Discovery of the Ubiquitous Cation NS+ in Space Confirmed by Laboratory Spectroscopy , 2018, The astrophysical journal. Letters.

[573]  G. Blake,et al.  THE SEARCH FOR A COMPLEX MOLECULE IN A SELECTED HOT CORE REGION: A RIGOROUS ATTEMPT TO CONFIRM TRANS-ETHYL METHYL ETHER TOWARD W51 e1/e2 , 2014, 1411.2627.

[574]  M. Rieke,et al.  Clear and Cloudy Exoplanet Forecasts for JWST: Maps, Retrieved Composition, and Constraints on Formation with MIRI and NIRCam , 2018, The Astronomical Journal.

[575]  L. Aller PHOTOELECTRIC SPECTROPHOTOMETRY OF eta CARINAE. , 1966, Proceedings of the National Academy of Sciences of the United States of America.

[576]  Geoffrey A. Blake,et al.  Molecular line survey of Orion A from 215 to 247 GHz , 1985 .

[577]  K. Öberg,et al.  DETECTION OF N2D+ IN A PROTOPLANETARY DISK , 2015, 1508.03637.

[578]  A. E. Lilley,et al.  Detection of interstellar trans-ethyl alcohol , 1975 .

[579]  Widespread HCO Emission in the Nuclear Starburst of M82 , 2002, astro-ph/0207313.

[580]  W. Wolff,et al.  Non-thermal ion desorption from an acetonitrile (CH3CN) astrophysical ice analogue studied by electron stimulated ion desorption. , 2015, Physical chemistry chemical physics : PCCP.

[581]  D. Queloz,et al.  A global analysis of Spitzer and new HARPS data confirms the loneliness and metal-richness of GJ 436 b , 2014, 1409.4038.

[582]  J. Cernicharo,et al.  Discovery of interstellar ketenyl (HCCO), a surprisingly abundant radical. , 2015, Astronomy and astrophysics.

[583]  A. Apponi,et al.  The Radio Spectra of SiCCH, SiCN, and SiNC , 2000, The Astrophysical journal.

[584]  K. M. Baird,et al.  A Laboratory Determination of the Frequency of the 10-CENTIMETER Radio Line of CH by Optical Measurements , 1971 .

[585]  Michael C. McCarthy,et al.  DETECTION OF E-CYANOMETHANIMINE TOWARD SAGITTARIUS B2(N) IN THE GREEN BANK TELESCOPE PRIMOS SURVEY , 2013 .

[586]  Submillimeter lines from circumstellar disks around pre-main sequence stars , 2001, astro-ph/0108375.

[587]  Nikku Madhusudhan,et al.  Exoplanetary Atmospheres—Chemistry, Formation Conditions, and Habitability , 2016, Space Science Reviews.

[588]  Christine D. Wilson,et al.  OBSERVATIONS OF Arp 220 USING HERSCHEL-SPIRE: AN UNPRECEDENTED VIEW OF THE MOLECULAR GAS IN AN EXTREME STAR FORMATION ENVIRONMENT , 2011, 1106.5054.

[589]  W. S. Adams Some Results with the COUDÉ Spectrograph of the Mount Wilson Observatory. , 1941 .

[590]  E. Herbst,et al.  THE MILLIMETER- AND SUBMILLIMETER-WAVE SPECTRUM OF THE TRANS AND GAUCHE CONFORMERS OF ETHYL FORMATE , 2009 .

[591]  S. Saito,et al.  Submillimeter-Wave Spectra of H2Cl+ and its Isotopic Species: Molecular Structure , 2001 .

[592]  Jacob L. Bean,et al.  A DETECTION OF WATER IN THE TRANSMISSION SPECTRUM OF THE HOT JUPITER WASP-12b AND IMPLICATIONS FOR ITS ATMOSPHERIC COMPOSITION , 2015, 1504.05586.

[593]  R. Linke,et al.  A Survey of the Millimeter-Wave Spectrum of Sagittarius B2 , 1986 .

[594]  W. C. Bowman,et al.  A high C/O ratio and weak thermal inversion in the atmosphere of exoplanet WASP-12b , 2010, Nature.

[595]  A. Apponi,et al.  Astronomical Detection of Rhomboidal SiC3 , 1999 .

[596]  J. Wood,et al.  Combined Infrared and Microwave Determination of Torsional Parameters , 1970 .

[597]  T. Henning,et al.  CHEMISTRY IN DISKS. VII. FIRST DETECTION OF HC3N IN PROTOPLANETARY DISKS , 2012, 1207.2682.

[598]  D. Wooldridge,et al.  Mass Ratio of the Carbon Isotopes from the Spectrum of CN , 1932 .

[599]  R. Brown,et al.  Vibrationally excited CH3CN and HC3N in Orion. , 1983 .

[600]  J. Robinson,et al.  The millimeter-wave spectrum of AlNC: chemical trends in metal isocyanide molecules , 1997 .

[601]  P. Thaddeus,et al.  LABORATORY DETECTION OF HOCN AND TENTATIVE IDENTIFICATION IN Sgr B2 , 2009 .

[602]  D. Lis,et al.  A Line Survey of Orion-KL from 607 to 725 GHz , 2001 .

[603]  R. Curl,et al.  The microwave and far-infrared spectra of the SiH radical , 1985 .

[604]  J. Kauppinen,et al.  Infrared spectrum of CO2 in the region of the bending fundamental ν2 , 1980 .

[605]  Adwin Boogert,et al.  Observations of the Icy Universe , 2015, 1501.05317.

[606]  S. Charnley,et al.  Deep K-band Observations of TMC-1 with the Green Bank Telescope: Detection of HC7O, Nondetection of HC11N, and a Search for New Organic Molecules , 2017, 1710.10178.

[607]  S. Beckwith,et al.  Kinematics of the Circumstellar Gas of HL Tauri and R Monocerotis , 1987 .

[608]  P. Bernath,et al.  Spectra of Atoms and Molecules , 1996 .

[609]  A. Fayt,et al.  The absorption of ethylene in the 10- mu m region , 1980 .

[610]  M. Gerin,et al.  Detection of extragalactic argonium, ArH + , toward PKS 1830-211 , 2015, 1509.06917.

[611]  W. Irvine,et al.  Detection of Interstellar Ethylene Oxide (c-C2H4O) , 1997, The Astrophysical journal.

[612]  Richard D. Suenram,et al.  Laboratory measurement of the 1(01)-0(00) transition and electric dipole moment of SiC sub 2. [In interstellar space] , 1989 .

[613]  P. Thaddeus,et al.  Tentative detection of the C/sub 3/N radical , 1977 .

[614]  J. Najita,et al.  Organic Molecules and Water in the Planet Formation Region of Young Circumstellar Disks , 2008, Science.

[615]  Juan Carlos Cortés López,et al.  Millimeter-wave spectrum of cyclopropenone, C3H2O , 1990 .

[616]  R. Loomis,et al.  CYANIDE PHOTOCHEMISTRY AND NITROGEN FRACTIONATION IN THE MWC 480 DISK , 2015, 1511.03313.

[617]  T. Crawford,et al.  HIGH-ACCURACY QUARTIC FORCE FIELD CALCULATIONS FOR THE SPECTROSCOPIC CONSTANTS AND VIBRATIONAL FREQUENCIES OF 11A′ l-C3H−: A POSSIBLE LINK TO LINES OBSERVED IN THE HORSEHEAD NEBULA PHOTODISSOCIATION REGION , 2013, 1306.3963.

[618]  Howard A. Smith,et al.  The Far-Infrared Spectrum of Arp 220 , 2004, astro-ph/0406427.

[619]  J. M. Hollis,et al.  Green Bank Telescope Observations of Interstellar Glycolaldehyde: Low-Temperature Sugar , 2004 .

[620]  W. Goss A New Determination of the Frequency of the Interstellar Radio Line of CH , 1966 .

[621]  G. Winnewisser,et al.  The Rotational Spectrum of SH and SD , 1996 .

[622]  D. Buhl,et al.  Observations of Radio Emission from Interstellar Hydrogen Cyanide , 1971 .

[623]  J. M. Hollis,et al.  New Detections of Interstellar HNO at 2 and 1.2 Millimeters: More N-O Bonds , 1994 .

[624]  M. Bogey,et al.  Millimeter and submillimeter wave spectrum of HCNH , 1985 .

[625]  J. Cernicharo,et al.  IDENTIFICATION OF KCN IN IRC+10216: EVIDENCE FOR SELECTIVE CYANIDE CHEMISTRY , 2010 .

[626]  Geoffrey A. Blake,et al.  Discovery of the interstellar chiral molecule propylene oxide (CH3CHCH2O) , 2016, Science.

[627]  C. Costain,et al.  The microwave spectra of cyanamide: Conclusions from ųa transitions , 1972 .

[628]  V. Laurie Microwave Spectrum and Internal Rotation of Ethyl Cyanide , 1959 .

[629]  M. Hayashi,et al.  Observations of 11 protostellar sources in Taurus with Nobeyama millimeter array - Growth of circumstellar disks , 1991 .

[630]  M. Anderson,et al.  The millimeter and submillimeter rotational spectrum of the MgCN radical (X [SUP]2[/SUP] Sigma(+)) , 1994 .

[631]  France.,et al.  Organic molecules in the Galactic center - Hot core chemistry without hot cores , 2006, astro-ph/0605031.

[632]  D. Buhl,et al.  Radio detection of interstellar sulfur dioxide. , 1975 .

[633]  J. Muenter,et al.  Electric Dipole Moment of SiO and GeO , 1970 .

[634]  J. Cernicharo,et al.  Astonomical and laboratory detection of the SiC radical , 1989 .

[635]  N. Scoville,et al.  Vibrationally excited carbon monoxide in IRC+10216 , 1978 .

[636]  B. Parise,et al.  Detection of the hydroperoxyl radical HO2 toward rho Ophiuchi A , 2012 .

[637]  L. Ziurys,et al.  HCNH+: a new interstellar molecular ion. , 1986, The Astrophysical journal.

[638]  G. Poletto,et al.  TheA2Π andX2Σ states of the CN molecule from the berkeley analysis of the CN red system , 1965 .

[639]  J. M. Hollis,et al.  Interstellar Glycolaldehyde: The First Sugar , 2000 .

[640]  R. Linke,et al.  Identification of the SiCC radical toward IC +10216 - The first molecular ring in an astronomical source , 1984 .

[641]  P. Friberg,et al.  Astronomical identification of the C3H radical. , 1985, The Astrophysical journal.

[642]  W. Welch,et al.  Detection of Water in Interstellar Regions by its Microwave Radiation , 1969, Nature.

[643]  S. Saito Laboratory Observations of the 1_{01}<-0_{00} Transitions for the HCO and DCO Free Radicals by Microwave Spectroscopy , 1972 .

[644]  B. Turner U93.174: A new interstellar line with quadrupole hyperfine splitting , 1974 .

[645]  A. Charo,et al.  The millimeter and submillimeter spectrum of HO2: The effects of unpaired electronic spin in a light asymmetric rotor , 1982 .

[646]  È. Roueff,et al.  Discovery of the elusive radical NCO and confirmation of H2NCO+ in space. , 2018, Astronomy and astrophysics.

[647]  R. Wilson,et al.  Detection of interstellar carbonyl sulfide , 1971 .