Discriminating gasoline fuel contamination in engine oil by terahertz time-domain spectroscopy

Abstract Gasoline engine oil (SAE 5W20) was contaminated with four levels (0%, 4%, 8% and 12%) of gasoline fuel and submitted to terahertz time-domain spectroscopy (THz-TDS). Three sampling methods were used to compare measurement variations. For all sampling methods, refractive index decreased with increased fuel contamination and absorption coefficient increased with increased fuel contamination. Absorption coefficients were significantly different for each fuel contamination level for each sampling method across the entire 0.5–2.5 THz range. The frequency of 0.5 THz produced the best model of absorption coefficient predicting fuel contamination with a root-mean-square error of 0.21% points. THz-TDS demonstrated high potential for estimating gasoline fuel contamination in gasoline engine oil.

[1]  Kun Zhao,et al.  The spectral analysis of fuel oils using terahertz radiation and chemometric methods , 2016 .

[2]  Dimitrios Peroulis,et al.  High temperature dynamic viscosity sensor for engine oil applications , 2012 .

[3]  Tsuyoshi Murata,et al.  {m , 1934, ACML.

[4]  Shirley E. Schwartz,et al.  The Effects of Trip Length and Oil Type (Synthetic Versus Mineral Oil) on Engine Damage and Engine-Oil Degradation in a Driving Test of a Vehicle with a 5.7L V-8 Engine , 1993 .

[5]  Bin Chen,et al.  Impact of Fuel Injection on Dilution of Engine Crankcase Oil for Turbocharged Gasoline Direct-Injection Engines , 2015 .

[6]  Qingli Zhou,et al.  Optical property and spectroscopy studies on the selected lubricating oil in the terahertz range , 2009 .

[7]  E. Richard Booser,et al.  CRC Handbook of Lubrication and Tribology, Volume III: Monitoring, Materials, Synthetic Lubricants, and Applications, Volume III , 1994 .

[8]  Dennis G. Watson,et al.  Distinguishing Gasoline Engine Oils of Different Viscosities Using Terahertz Time-Domain Spectroscopy , 2015 .

[9]  Jiang Zhe,et al.  An integrated lubricant oil conditioning sensor using signal multiplexing , 2014 .

[10]  P. Davidovits Friction , 2019, Physics in Biology and Medicine.

[11]  Masahiko Tani,et al.  Investigation of inflammable liquids by terahertz spectroscopy , 2005 .

[12]  Ronei J. Poppi,et al.  Application of mid infrared spectroscopy and iPLS for the quantification of contaminants in lubricating oil , 2005 .

[13]  A. Markelz,et al.  Terahertz Spectroscopy of Liquids and Biomolecules , 2012 .

[14]  Hakan Altan,et al.  Dielectric properties of ethanol and gasoline mixtures by terahertz spectroscopy and an effective method for determination of ethanol content of gasoline. , 2014, The journal of physical chemistry. A.

[15]  Oleg Kolosov,et al.  New Solid State Oil Condition Sensor for Real Time Engine Oil Condition Monitoring , 2006 .

[16]  Horst Mannebach,et al.  A Novel Approach to Predictive Maintenance: A Portable, Multi-Component MEMS Sensor for On-Line Monitoring of Fluid Condition in Hydraulic and Lubricating Systems , 2006 .

[17]  B. Jakoby,et al.  An automotive engine oil viscosity sensor , 2003 .

[18]  Yunqing Chen,et al.  THz wave sensing for petroleum industrial applications , 2007 .

[19]  M. Koch,et al.  Terahertz spectroscopy and imaging – Modern techniques and applications , 2011 .

[20]  Robert E. Miles,et al.  Terahertz Time-Domain Spectroscopy for Material Characterization , 2007, Proceedings of the IEEE.

[21]  Rima Bao,et al.  Predicting Cold Flow Properties of Diesel by Terahertz Time-Domain Spectroscopy , 2012 .

[22]  Ryan J. Clark,et al.  Assessment of the Properties of Internal Combustion Engine Lubricants Using an Onboard Sensor , 2012 .

[23]  Seok-Gy Jeon,et al.  Analysis of Petroleum Products and Their Mixtures by Using Terahertz Time Domain Spectroscopy , 2008 .

[24]  S. Schwartz A Comparison of Engine Oil Viscosity, Emulsion Formation, and Chemical Changes for M85 and Gasoline-Fueled Vehicles in Short-Trip Service , 1992 .

[25]  Hakan Altan,et al.  Dielectric Properties of Diesel and Gasoline by Terahertz Spectroscopy , 2014 .

[26]  Olaf Lüdtke,et al.  Multiparameter Oil Condition Sensor Based on the Tuning Fork Principle , 2007 .

[27]  Cunlin Zhang,et al.  Quantitative Analysis for Monitoring Formulation of Lubricating Oil Using Terahertz Time-Domain Transmission Spectroscopy , 2012 .

[28]  Yosuke Okuyama,et al.  Development of Engine Oil Deterioration Monitoring System Using Estimation Method of Oxidation Induction Time , 2007 .

[29]  A. Semnani,et al.  Expression of Concern Expression of Concern on “ Monitoring of the Physical and Chemical Properties of a Gasoline Engine Oil during Its Usage , 2019 .

[30]  Dennis G. Watson,et al.  Using Terahertz Time-Domain Spectroscopy to Discriminate among Water Contamination Levels in Diesel Engine Oil , 2016 .

[31]  Y. Murakami,et al.  Analysis of Mechanism Intermixing Combustion Products in Engine Oil : Quantity and Composition of Unburned Gasoline in Engine Oil and Crankcase Gas , 1991 .

[32]  Ning Wang,et al.  Terahertz (THz) Applications in Food and Agriculture: A Review , 2013 .

[33]  R. E. Miles,et al.  Terahertz Transmission Spectroscopy of Nonpolar Materials and Relationship with Composition and Properties , 2004, Infrared and Millimeter Waves, Conference Digest of the 2004 Joint 29th International Conference on 2004 and 12th International Conference on Terahertz Electronics, 2004..