Fire stability of glass-fibre sandwich panels: The influence of core materials and flame retardants

Abstract Fire resistance has become a key property for structural lightweight sandwich components in aviation, shipping, railway vehicles, and construction. The development of future composite materials and components demands adequate test procedures for simultaneous application of compression and fully developed fire. Therefore an intermediate-scale approach (specimen size = 500 mm × 500 mm) is applied with compressive loads (up to 1 MN) and direct application of a burner to one side of the specimens, as established in aviation for severe burn-through tests. The influence of different core structures (polyvinylchloride foam, polyisocyanorate foam reinforced by stitched glass bridges, and balsa wood) was investigated for glass-fibre-reinforced sandwich specimens with and without flame retardants applied on the fabrics, in the matrix, and on surface for each specimen at the same time. Times to failure were increased up to a factor of 4. The intumescent coating prolongs the time to failure significantly. What is more, using the intrinsic potential of the front skin together with the core to protect a load bearing back skin in sandwich panels, the design of the core – here using the wood core – is the most promising approach.

[1]  J. V. Bausano,et al.  Mechanistic Approach to Structural Fire Modeling of Composites , 2011 .

[2]  H. Vandersall,et al.  Intumescent coating system, their development and chemistry , 1971 .

[3]  A. Mouritz,et al.  Modelling the tension and compression strengths of polymer laminates in fire , 2007 .

[4]  J. Quintiere,et al.  Predicting the burning of wood using an integral model , 2000 .

[5]  H. Schürmann,et al.  FAILURE ANALYSIS OF FRP LAMINATES BY MEANS OF PHYSICALLY BASED PHENOMENOLOGICAL MODELS , 1998 .

[6]  R. Asaro,et al.  Skin wrinkling of sandwich polymer matrix composite panels subjected to fire exposure , 2012 .

[7]  Usman Sorathia,et al.  Improved fire safety of composites for naval applications , 1992 .

[8]  M. Döring,et al.  Flame Retardancy of Polymers: The Role of Specific Reactions in the Condensed Phase , 2016 .

[9]  E. Kandare,et al.  Tension modelling and testing of sandwich composites in fire , 2014 .

[10]  Fernando A. Branco,et al.  Fire protection systems for building floors made of pultruded GFRP profiles: Part 1: Experimental investigations , 2010 .

[11]  B. Lattimer,et al.  Compressive failure of composite plates during one-sided heating , 2011 .

[12]  Z. Mathys,et al.  Modelling residual mechanical properties of polymer composites after fire , 2003 .

[13]  W. Cantwell,et al.  A study of skin-core adhesion in glass fibre reinforced sandwich materials , 1996 .

[14]  A. Gibson,et al.  Integrity of composite aircraft fuselage materials under crash fire conditions , 2009 .

[15]  Bernhard Schartel,et al.  Development of fire‐retarded materials—Interpretation of cone calorimeter data , 2007 .

[16]  N. J. Hoff,et al.  The Buckling of Sandwich-Type Panels , 1945 .

[17]  Sophie Duquesne,et al.  Intumescent paints: fire protective coatings for metallic substrates , 2004 .

[18]  Morten Grønli,et al.  Mathematical Model for Wood PyrolysisComparison of Experimental Measurements with Model Predictions , 2000 .

[19]  A. Mouritz,et al.  Influence of water content on failure of phenolic composites in fire , 2008 .

[20]  A. G. Gibson,et al.  Fire performance of composite panels for large marine structures , 1995 .

[21]  Bernhard Schartel,et al.  Novel DOPO-based flame retardants in high-performance carbon fibre epoxy composites for aviation , 2011 .

[22]  A. Gibson,et al.  Modeling Compressive Skin Failure of Sandwich Composites in Fire , 2008 .

[23]  E. Hugi,et al.  Experimental study on the concept of liquid cooling for improving fire resistance of FRP structures for construction , 2005 .

[24]  Leif A. Carlsson,et al.  Experimental Investigation of Compression Failure Mechanisms of Composite Faced Foam Core Sandwich Specimens , 2004 .

[25]  A. Mouritz,et al.  Compression Failure of Carbon Fiber-Epoxy Laminates in Fire , 2010 .

[26]  Bernhard Schartel,et al.  Phosphorus-based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development? , 2010, Materials.

[27]  C. P. Gardiner,et al.  Compression properties of fire-damaged polymer sandwich composites , 2002 .

[28]  S. Meckbach,et al.  Neue Bruchkriterien und Festigkeitsnachweise für unidirektionalen Faserkunststoffverbund unter mehrachsiger Beanspruchung -Modellbildung und Experimente , 1997 .

[29]  George A. Kardomateas,et al.  Structural and Failure Mechanics of Sandwich Composites , 2011 .

[30]  A. Mouritz,et al.  Fire Properties of Polymer Composite Materials , 2006 .

[31]  Composite life under sustained compression and one sided simulated fire exposure: Characterization and prediction , 2006 .

[32]  Bernardo Zuccarello,et al.  Experimental and numerical evaluation of the mechanical behaviour of GFRP sandwich panels , 2007 .

[33]  B. Schartel,et al.  Protecting the structural integrity of composites in fire: Intumescent coatings in the intermediate scale , 2015 .

[34]  A. Gibson,et al.  Modeling composite high temperature behavior and fire response under load , 2012 .

[35]  P. T. Summers,et al.  Predicting Compression Failure of Fiber-reinforced Polymer Laminates during Fire , 2010 .

[36]  V. Altstädt,et al.  Competition in aluminium phosphinate-based halogen-free flame retardancy of poly(butylene terephthalate) and its glass-fibre composites , 2014 .

[37]  H. Schürmann Konstruieren mit Faser-Kunststoff-Verbunden , 2005 .

[38]  Edward D. Weil,et al.  Fire-Protective and Flame-Retardant Coatings - A State-of-the-Art Review , 2011 .

[39]  Jack C. Roberts,et al.  Buckling, collapse and failure analysis of FRP sandwich panels ☆ , 2002 .

[40]  Brian Y. Lattimer,et al.  Structural response of FRP composites during fire , 2009 .

[41]  B. Schartel,et al.  Structural integrity of sandwich structures in fire: an intermediate-scale approach , 2013 .

[42]  Martin Knops,et al.  Analysis of Failure in Fiber Polymer Laminates: The Theory of Alfred Puck , 2008 .