Wrinkling prediction, formation and evolution in thin films adhering on polymeric substrata

Abstract Wrinkling has recently attracted an increasing interest by suggesting a number of unforeseeable applications in many emerging material science and engineering fields. If guided and somehow designed, wrinkles could be in fact used as an alternative printing way for realizing complex surface geometries and thus employed as an innovative bottom-up process in the fabrication of nano- and micro-devices. For these reasons, the prediction of wrinkles of films adhering on flat as well as on structured substrata is a challenging task, genesis and development of the phenomenon being not yet completely understood both when thin membranes are coupled with soft supports and in cases where the geometry of the surfaces are characterized by complex three-dimensional profiles. Here we investigate the experimental formation of new intriguing and somehow unforeseeable wrinkled patterns achieved on periodic structures, by showing prediction through a new hybrid analytical-numerical strategy capable to overcome some common obstacles encountered in modeling film wrinkling on flat and 3D-shaped substrata. The proposed approach, which drastically reduces the computational effort, furnishes a helpful way for predicting both qualitative and quantitative results in terms of wrinkling patterns, magnitude and wavelength, by also allowing to follow the onset of film instabilities and the progressive evolution of the phenomenon until its final stage.

[1]  Hongbin Yu,et al.  Micro-strain sensing using wrinkled stiff thin films on soft substrates as tunable optical grating. , 2013, Optics express.

[2]  Francesco Merola,et al.  Characterization of Bessel beams generated by polymeric microaxicons , 2012 .

[3]  P. Reis,et al.  Buckling patterns in biaxially pre-stretched bilayer shells: wrinkles, creases, folds and fracture-like ridges. , 2017, Soft matter.

[4]  Horst-Günter Rubahn,et al.  Effect of Deposition Rate on Structure and Surface Morphology of Thin Evaporated Al Films on Dielectrics and Semiconductors , 2012 .

[5]  M. Worgull,et al.  Bio-inspired hierarchical micro- and nano-wrinkles obtained via mechanically directed self-assembly on shape-memory polymers. , 2017, Soft matter.

[6]  Soon Moon Jeong,et al.  Light extraction from organic light-emitting diodes enhanced by spontaneously formed buckles , 2010 .

[7]  A. Nogales,et al.  Wrinkling and Folding on Patched Elastic Surfaces: Modulation of the Chemistry and Pattern Size of Microwrinkled Surfaces. , 2017, ACS applied materials & interfaces.

[8]  Aditya Banerji,et al.  Programming Feature Size in the Thermal Wrinkling of Metal Polymer Bilayer by Modulating Substrate Viscoelasticity. , 2017, ACS applied materials & interfaces.

[9]  Barbara Mazzolai,et al.  Two-photon polymerization of sub-micrometric patterned surfaces: investigation of cell-substrate interactions and improved differentiation of neuron-like cells. , 2013, ACS applied materials & interfaces.

[10]  H. Deyhle,et al.  Gold Layers on Elastomers near the Critical Stress Regime , 2017 .

[11]  Wei Hong,et al.  Evolution of wrinkles in hard films on soft substrates. , 2004, Physical review. E, Statistical, nonlinear, and soft matter physics.

[12]  George M. Whitesides,et al.  Ordering of Spontaneously Formed Buckles on Planar Surfaces , 2000 .

[13]  P. Yoo,et al.  Morphological Diagram for Metal/Polymer Bilayer Wrinkling: Influence of Thermomechanical Properties of Polymer Layer , 2005 .

[14]  Quantitative predictions of diverse wrinkling patterns in film/substrate systems , 2017, Scientific Reports.

[15]  P. Ferraro,et al.  A skin-over-liquid platform with compliant microbumps actuated by pyro-EHD pressure , 2019, NPG Asia Materials.

[16]  Chang Su Kim,et al.  Effects of the Wrinkle Structure and Flat Structure Formed During Static Low-Temperature Annealing of ZnO on the Performance of Inverted Polymer Solar Cells , 2017 .

[17]  K. Bertoldi,et al.  Bloch wave approach for the analysis of sequential bifurcations in bilayer structures , 2015, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[18]  B. Audoly Localized buckling of a floating elastica. , 2011, Physical review. E, Statistical, nonlinear, and soft matter physics.

[19]  O. Matar,et al.  Sub-100 nm wrinkling of polydimethylsiloxane by double frontal oxidation. , 2017, Nanoscale.

[20]  T. Witten,et al.  Wrinkle to fold transition: influence of the substrate response , 2013 .

[21]  Teri W. Odom,et al.  Multiscale, Hierarchical Patterning of Graphene by Conformal Wrinkling. , 2016, Nano letters.

[22]  D. Satapathy,et al.  Wrinkle and crack-dependent charge transport in a uniaxially strained conducting polymer film on a flexible substrate. , 2017, Soft matter.

[23]  D. Fabrègue,et al.  Towards behavior by design: A case study on corrugated architectures , 2019, Materials & Design.

[24]  Jie Yin,et al.  Deterministic Order in Surface Micro‐Topologies through Sequential Wrinkling , 2012, Advanced materials.

[25]  Lihua Jin,et al.  The role of substrate pre-stretch in post-wrinkling bifurcations. , 2014, Soft matter.

[26]  Xi-Qiao Feng,et al.  Effects of tension–compression asymmetry on the surface wrinkling of film–substrate systems , 2016 .

[27]  P. K. Roy,et al.  Wrinkled 2D Materials: A Versatile Platform for Low‐Threshold Stretchable Random Lasers , 2017, Advanced materials.

[28]  Jeong-Yun Sun,et al.  Folding wrinkles of a thin stiff layer on a soft substrate , 2011, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[29]  Zhi-qian Zhang,et al.  Dynamic pattern of wrinkles in a dielectric elastomer. , 2017, Soft matter.

[30]  J. Hutchinson The role of nonlinear substrate elasticity in the wrinkling of thin films , 2013, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[31]  Novel room-temperature first-level packaging process for microscale devices , 2005 .

[32]  Yonggang Huang,et al.  Stretchable and Foldable Silicon Integrated Circuits , 2008, Science.

[33]  Heejeong Jeong,et al.  Flexible piezocapacitive sensors based on wrinkled microstructures: toward low-cost fabrication of pressure sensors over large areas , 2017 .

[34]  George M. Whitesides,et al.  Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer , 1998, Nature.

[35]  Christopher M. Stafford,et al.  Surface Wrinkling: A Versatile Platform for Measuring Thin‐Film Properties , 2011, Advanced materials.

[36]  Yasuaki Tokudome,et al.  Thermoresponsive Wrinkles on Hydrogels for Soft Actuators , 2016 .

[37]  Gerhard A. Holzapfel,et al.  Nonlinear Solid Mechanics: A Continuum Approach for Engineering Science , 2000 .

[38]  Yanping Cao,et al.  Wrinkling Phenomena in Neo-Hookean Film/Substrate Bilayers , 2012 .

[39]  M. Potier-Ferry,et al.  Post-buckling evolution of wavy patterns in trapezoidal film/substrate bilayers , 2017 .

[40]  P. Ferraro,et al.  Direct self-assembling and patterning of semiconductor quantum dots on transferable elastomer layer , 2017 .

[41]  Francesco Merola,et al.  Multi-imaging capabilities of a 2D diffraction grating in combination with digital holography. , 2010, Optics letters.

[42]  Yanping Cao,et al.  Controlled free edge effects in surface wrinkling via combination of external straining and selective O2 plasma exposure. , 2013, Langmuir : the ACS journal of surfaces and colloids.

[43]  Pietro Ferraro,et al.  Twofold Self-Assembling of Nanocrystals Into Nanocomposite Polymer , 2016, IEEE Journal of Selected Topics in Quantum Electronics.

[44]  Francesco Merola,et al.  Self-patterning of a polydimethylsiloxane microlens array on functionalized substrates and characterization by digital holography , 2009 .

[45]  John A Rogers,et al.  Controlled buckling of semiconductor nanoribbons for stretchable electronics , 2006, Nature nanotechnology.

[46]  J. Hutchinson,et al.  Herringbone Buckling Patterns of Compressed Thin Films on Compliant Substrates , 2004 .

[47]  P. Ferraro,et al.  Quick liquid packaging: Encasing water silhouettes by three-dimensional polymer membranes , 2019, Science Advances.

[48]  P. Ferraro,et al.  Twice electric field poling for engineering multiperiodic Hex-PPLN microstructures , 2017 .

[49]  Wei Chen,et al.  Modulating electronic transport properties of MoS2 field effect transistor by surface overlayers , 2013 .

[50]  Francesco Merola,et al.  Reversible Fragmentation and Self‐Assembling of Nematic Liquid Crystal Droplets on Functionalized Pyroelectric Substrates , 2012 .

[51]  S. Timoshenko Theory of Elastic Stability , 1936 .

[52]  Brandon C. Andow,et al.  Controlled Crumpling of Graphene Oxide Films for Tunable Optical Transmittance , 2015, Advanced materials.

[53]  K. Suh,et al.  Physical Self-Assembly of Microstructures by Anisotropic Buckling , 2002 .

[54]  A. Böker,et al.  Wetting Phenomena on (Gradient) Wrinkle Substrates. , 2016, Langmuir : the ACS journal of surfaces and colloids.

[55]  G. Mensitieri,et al.  Delamination onset and design criteria of multilayer flexible packaging under high pressure treatments , 2014 .

[56]  Kevin Kit Parker,et al.  Hierarchical wrinkling patterns , 2010 .

[57]  Woo-Bin Jung,et al.  Universal Method for Creating Hierarchical Wrinkles on Thin-Film Surfaces. , 2018, ACS applied materials & interfaces.

[58]  Salim Belouettar,et al.  3D finite element modeling for instabilities in thin films on soft substrates , 2014 .

[59]  Xi-Qiao Feng,et al.  Towards a quantitative understanding of period-doubling wrinkling patterns occurring in film/substrate bilayer systems , 2015, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[60]  Nicolas C. Pégard,et al.  Wrinkles and deep folds as photonic structures in photovoltaics , 2012, Nature Photonics.

[61]  Ying Li Reversible wrinkles of monolayer graphene on a polymer substrate: toward stretchable and flexible electronics. , 2016, Soft matter.

[62]  B. Xu,et al.  Spatially Configuring Wrinkle Pattern and Multiscale Surface Evolution with Structural Confinement , 2018 .

[63]  Jie Yin,et al.  Buckling patterns of thin films on curved compliant substrates with applications to morphogenesis and three-dimensional micro-fabrication , 2010 .

[64]  Mengdi Han,et al.  Single-Step Fluorocarbon Plasma Treatment-Induced Wrinkle Structure for High-Performance Triboelectric Nanogenerator. , 2016, Small.

[65]  Pietro Ferraro,et al.  Electrohydrodynamic Assembly of Multiscale PDMS Microlens Arrays , 2015, IEEE Journal of Selected Topics in Quantum Electronics.

[66]  Yanping Cao,et al.  Localized ridge wrinkling of stiff films on compliant substrates , 2012 .

[67]  J. Köhler,et al.  Surface Wrinkling and Porosity of Polymer Particles toward Biological and Biomedical Applications , 2017 .

[68]  G. Yi,et al.  Competitive concurrence of surface wrinkling and dewetting of liquid crystalline polymer films on non-wettable substrates. , 2017, Soft matter.

[69]  Zhigang Suo,et al.  Periodic patterns and energy states of buckled films on compliant substrates , 2011 .

[70]  Yanping Cao,et al.  Tuning and Erasing Surface Wrinkles by Reversible Visible-Light-Induced Photoisomerization. , 2016, Angewandte Chemie.

[71]  P. Steeneken,et al.  Voltage‐Controlled Surface Wrinkling of Elastomeric Coatings , 2013, Advanced materials.

[72]  Guoan Zheng,et al.  Moisture‐Responsive Wrinkling Surfaces with Tunable Dynamics , 2017, Advanced materials.

[73]  Teri W. Odom,et al.  Controlled Three-Dimensional Hierarchical Structuring by Memory-Based, Sequential Wrinkling. , 2015, Nano letters.

[74]  C. Galiotis,et al.  Wrinkling formation in simply-supported graphenes under tension and compression loadings. , 2017, Nanoscale.

[75]  Hong-Gyu Park,et al.  Tailoring the Orientation and Periodicity of Wrinkles Using Ion-Beam Bombardment. , 2016, Langmuir : the ACS journal of surfaces and colloids.

[76]  Xi-Qiao Feng,et al.  Curvature induced hierarchical wrinkling patterns in soft bilayers. , 2016, Soft matter.