Extrusion of chalcogenide glass preforms and drawing to multimode optical fibers

Abstract We report on viscosity of a Ge 17 As 18 Se 65 glass over the temperature range of 280–420 °C and the successful co-extrusion and fiber-drawing of two chalcogenide glass boules to form a core/clad. pair. The co-extrusion produces a preform with optimum diameter stability and core/clad. glass ratio, and minimum defects at the core/clad. interface in the middle 120–200 mm region of a 270 mm long preform. Core/clad. fiber is drawn successfully from the extruded preform. An optical loss of 1.7 dB m −1 at 1666 cm −1 (6.0 μm) and 6.7 dB m −1 at 6649 cm −1 (1.55 μm) is reported.

[1]  N. J. Pitt,et al.  Telluride Glass Fibres for Transmission in the 8-12 micrometres Waveband , 1986, Photonics West - Lasers and Applications in Science and Engineering.

[2]  J. A. Savage,et al.  Chalcogenide glasses transmitting in the infrared between 1 and 20 μ — a state of the art review , 1965 .

[3]  G. Fulcher,et al.  ANALYSIS OF RECENT MEASUREMENTS OF THE VISCOSITY OF GLASSES , 1925 .

[4]  Takashi Yamagishi,et al.  Optical and thermal properties of chalcogenide Ge-As-Se-Te glasses for IR fibers , 1987 .

[5]  Olivier Sire,et al.  IR optical fiber sensor for biomedical applications , 2003 .

[6]  J. M. Parker,et al.  Fluoride Glass Optical Fibres , 1990 .

[7]  P. R. Webber Some physical properties of Ge_As_Se infrared optical glasses , 1976 .

[8]  A. Seddon,et al.  Effects of Oxide Content on the Glass-Forming Ability of the Ga2S3-Na2S System , 1998 .

[9]  David N. Payne,et al.  Gallium lanthanum sulphide optical fibre for active and passive applications , 1996 .

[10]  Alexis G. Clare,et al.  Laboratory preparation of highly pure As2Se3 glass , 1995 .

[11]  Toshiharu Yamashita,et al.  Low‐loss chalcogenide glass fiber with core‐cladding structure , 1988 .

[12]  M. Churbanov,et al.  High-purity chalcogenide glasses as materials for fiber optics , 1995 .

[13]  Jean-Luc Adam,et al.  A new approach of preform fabrication for chalcogenide fibers , 2003 .

[14]  Jasbinder S. Sanghera,et al.  Active and passive chalcogenide glass optical fibers for IR applications: a review , 1999 .

[15]  Abdolnasser Zakery,et al.  Optical properties and applications of chalcogenide glasses: a review , 2003 .

[16]  David Furniss,et al.  Towards monomode proportioned fibreoptic preforms by extrusion , 1999 .

[17]  Xiujian Zhao,et al.  Femtosecond optical Kerr effect study of Ge(10)AS(40)S(30)Se(20) film , 2005 .

[18]  A. Varshneya,et al.  Modified preparation procedure for laboratory melting of multicomponent chalcogenide glasses , 1992 .

[19]  Jacques Lucas,et al.  Infrared chalcogen glasses: chemical polishing and fibre remote spectroscopy , 2001 .

[20]  Bruno Bureau,et al.  Development of a chalcogenide glass fiber device for in situ pollutant detection , 2003 .