Luminescent properties of Sr2SiO4: Eu2+ nanorods for near-UV white LED

Abstract Sr 2 SiO 4 : Eu 2+ phosphor was prepared by a modified sol–gel method. The structure and the composition of the phosphor nanorods were characterized by powder X-ray diffraction (XRD) and energy dispersion spectrum (EDS). Field-emission scanning electron microscopy (FE-SEM) and photo-luminescent spectra were used to characterize the shape and the luminescent properties of phosphor particles. One-dimensional Sr 2 SiO 4 : Eu 2+ nanorods were obtained, which shows intense blue–green emission under the excitation of near ultraviolet (n-UV) light (275–425 nm). It indicates that Sr 2 SiO 4 : Eu 2+ phosphors are promising blue-green candidates for the n-UV white LEDs.

[1]  S. Moharil,et al.  Luminescence of some Eu2+ activated bromides , 2009 .

[2]  G. Blasse,et al.  Optical properties of Eu2+-activated orthosilicates and orthophosphates , 1997 .

[3]  U. Varadaraju,et al.  White-Light Generation in Sr2SiO4 : Eu2 + , Ce3 + under Near-UV Excitation A Novel Phosphor for Solid-State Lighting , 2005 .

[4]  Chongfeng Guo,et al.  A promising red-emitting phosphor for white light emitting diodes prepared by sol–gel method , 2008 .

[5]  Sheng-ping Guo,et al.  A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light. , 2009, Journal of the American Chemical Society.

[6]  Naoto Hirosaki,et al.  White light-emitting diodes (LEDs) using (oxy)nitride phosphors , 2008 .

[7]  W. Stöber,et al.  Controlled growth of monodisperse silica spheres in the micron size range , 1968 .

[8]  R. P. Rao Preparation and Characterization of Fine‐Grain Yttrium‐Based Phosphors by Sol‐Gel Process , 1996 .

[9]  Jongsu Kim,et al.  Eu2+-Mn2+ energy transfer in white-light-emitting T-phase (Ba,Ca)2SiO4:Eu2+, Mn2+ phosphor , 2010 .

[10]  K. Machida,et al.  Characterization and luminescence properties of Sr2Si5N8:Eu2+ phosphor for white light-emitting-diode illumination , 2006 .

[11]  Q. Zhang,et al.  Bluish-green color emitting Ba2Si3O8:Eu2+ ceramic phosphors for white light-emitting diodes. , 2009, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[12]  S. Yao,et al.  A promising blue-green emitting phosphor for white light-emitting diodes prepared by sol-gel method , 2010 .

[13]  F. Jermann,et al.  Phosphors for solid state lighting , 2008, SPIE OPTO.

[14]  Xiaojun Wang,et al.  A green-yellow emitting β-Sr2SiO4:Eu2+ phosphor for near ultraviolet chip white-light-emitting diode , 2008 .

[15]  H. Tam,et al.  Near-ultraviolet light excited deep blue-emitting phosphor for solid state lighting , 2009 .

[16]  H. Park,et al.  Emission color variation of M2SiO4:Eu2+ (M=Ba, Sr, Ca) phosphors for light-emitting diode , 2005 .

[17]  Jong Kyu Kim,et al.  Solid-State Light Sources Getting Smart , 2005, Science.

[18]  M. Y. Tsai,et al.  Preparation of Eu-activated strontium orthosilicate (Sr1.95SiO4:Eu0.05) phosphor by a sol–gel method and its luminescent properties , 2009 .

[19]  Jiaguo Wang,et al.  Luminescent properties of Sr2P2O7:Eu,Mn phosphor under near UV excitation , 2008 .

[20]  K. Sohn,et al.  Energy Transfer Between Activators at Different Crystallographic Sites , 2009 .