On the Reuse of SLS Polyamide 12 Powder

In the Selective Laser Sintering (SLS) technique, the great majority of the powder involved is not included in the final printed parts, being just used as a support material. However, the quality of this powder is negatively affected during the process since it is subjected to high temperatures (close to its melting temperature) during a long time, i.e., the printing cycle time, especially in the neighborhood of the printed part contour. This type of powder is relatively expensive and large amounts of used powder result after each printing cycle. The present paper focuses on the reuse of Polyamide 12 (PA 12) powder. For this sake, the same PA 12 powder was used in consecutive printing cycles. After each cycle, the remaining non-used powder was milled and filtered before subsequent use. Properties of the powder and corresponding prints were characterized in each cycle, using differential scanning calorimetry (DSC), scanning electron microscopy (SEM), computed tomography (CT), and tensile tests. It was concluded that subjecting the same powder to multiple SLS printing cycles affects the properties of the printed parts essentially regarding their morphology (voids content), mechanical properties reproducibility, and aesthetical aspect. However, post-processing treatment of the powder enabled to maintain the mechanical performance of the prints during the first six printing cycles without the need to add virgin powder.

[1]  M. Zmudzinska,et al.  Mechanical and Structural Evaluation of the PA12 Desktop Selective Laser Sintering Printed Parts Regarding Printing Strategy , 2021, 3D printing and additive manufacturing.

[2]  A. Pontes,et al.  Prediction of SLS parts properties using reprocessing powder , 2021 .

[3]  J. Vohlídal Polymer degradation: a short review , 2020, Chemistry Teacher International.

[4]  M. Maringa,et al.  A Review of Methods Used to Reduce the Effects of High Temperature Associated with Polyamide 12 and Polypropylene Laser Sintering , 2020 .

[5]  O. Carneiro,et al.  A study on extruded filament bonding in fused filament fabrication , 2019, Rapid Prototyping Journal.

[6]  A. Kulkarni,et al.  Current Status of Methods Used In Degradation of Polymers: A Review , 2018 .

[7]  Mohsen Attaran,et al.  The rise of 3-D printing: The advantages of additive manufacturing over traditional manufacturing , 2017 .

[8]  J. Kruth,et al.  Effect of PA12 powder reuse on coalescence behaviour and microstructure of SLS parts , 2017 .

[9]  Sanat Agrawal,et al.  Selection of selective laser sintering materials for different applications , 2015 .

[10]  J. Wortberg,et al.  Effects of laser sintering processing time and temperature on changes in polyamide 12 powder particle size, shape and distribution , 2014 .

[11]  D. Drummer,et al.  Influence of degradation behavior of polyamide 12 powders in laser sintering process on produced parts , 2014 .

[12]  Diana A. Lados,et al.  Additive Manufacturing: Making Imagination the Major Limitation , 2014 .

[13]  Gottfried W. Ehrenstein,et al.  Resistance and Stability of Polymers , 2013 .

[14]  Robert Bogue,et al.  3D printing: the dawn of a new era in manufacturing? , 2013 .

[15]  R. Hague,et al.  Effect of long-term ageing on the tensile properties of a polyamide 12 laser sintering material , 2010 .

[16]  Lihua Zhao,et al.  Influence of process parameters on part shrinkage in SLS , 2007 .

[17]  J. Kruth,et al.  Benchmarking of different SLS/SLM processes as Rapid Manufacturing techniques , 2005 .

[18]  Sanjay Kumar Selective laser sintering: A qualitative and objective approach , 2003 .

[19]  Duc Truong Pham,et al.  Selective laser sintering: Applications and technological capabilities , 1999 .

[20]  Rémy Glardon,et al.  Direct rapid tooling: a review of current research , 1998 .

[21]  A. Cunha,et al.  An algorithm for predicting the properties of products incorporating recycled polymers , 1996 .

[22]  C. K. Chiklis,et al.  Effects of thermal exposure on the physicochemical properties of polyamides , 1965 .

[23]  D. Drummer,et al.  Aging effects of polyamide 12 in selective laser sintering: Molecular weight distribution and thermal properties , 2019, Additive Manufacturing.

[24]  E. Bain Polymer Powder Bed Fusion Additive Manufacturing: Recent Developments in Materials, Processes, and Applications , 2019, ACS Symposium Series.

[25]  Ming-Chuan Leu,et al.  Progress in Additive Manufacturing and Rapid Prototyping , 1998 .