A support vector regression model for the prediction of total polyaromatic hydrocarbons in soil: an artificial intelligent system for mapping environmental pollution

The significance of total polyaromatic hydrocarbons (TPAH) determination in assessing the carcinogenicity of environmental samples for measuring the level of environmental pollution cannot be overemphasized. Despite the environmental danger of TPAH, its laboratory quantification is laborious, which consumes appreciable time and other valuable resources. This research work develops a computational intelligence-based model for the first time, which directly estimates and quantifies the level of TPAH of any environmental solid samples using total petroleum hydrocarbons descriptor that can be easily determined experimentally. The hyperparameters of the developed support vector regression (SVR)-based model are optimized using manual search (MS) approach and genetic algorithm (GA) search approach with Gaussian and polynomial kernel functions. Experimental validation of the developed model was carried out using samples obtained from the marine sediments of Arabian Gulf Sea. The future generalization and predictive strength of the developed models were assessed using correlation coefficient (CC), root-mean-square error, mean absolute error and mean absolute percentage deviation (MAPD). GA-SVR-Gaussian performs better than MS-SVR and GA-SVR-poly with performance enhancement of 63.89% and 536.32%, respectively, on the basis of MAPD as a performance-measuring parameter, while MS-SVR model performs better than GA-SVR-poly with performance improvement of 288.25% using MAPD to evaluate the model performance. The estimation accuracy and generalization strength of the developed models indicate the potential of the models in measuring the level of environmental pollution of oil-spilled area without experimental stress, while experimental precision is preserved.

[1]  Taoreed O. Owolabi,et al.  Modeling the magnetocaloric effect of manganite using hybrid genetic and support vector regression algorithms , 2019, Physics Letters.

[2]  Vladimir N. Vapnik,et al.  The Nature of Statistical Learning Theory , 2000, Statistics for Engineering and Information Science.

[3]  Gera M Troisi,et al.  Polyaromatic hydrocarbon and PAH metabolite burdens in oiled common guillemots (Uria aalge) stranded on the east coast of England (2001 -2002). , 2006, Environmental science & technology.

[4]  Jing Wang,et al.  PAHs in aquatic sediment in Hangzhou, China: analytical methods, pollution pattern, risk assessment and sources. , 2005, Journal of environmental sciences.

[5]  Jinhua Li,et al.  Determination of 16 polycyclic aromatic hydrocarbons in environmental water samples by solid-phase extraction using multi-walled carbon nanotubes as adsorbent coupled with gas chromatography-mass spectrometry. , 2010, Journal of chromatography. A.

[6]  Gerrit Kateman,et al.  Interpretation of infrared spectra with modular neural-network systems , 1993 .

[7]  L. Baxter Random Fields on a Network: Modeling, Statistics, and Applications , 1996 .

[8]  M. Lotfy,et al.  Assessment of organic pollutants in coastal sediments, UAE , 2008 .

[9]  Sunday O. Olatunji,et al.  Computational intelligence method of determining the energy band gap of doped ZnO semiconductor , 2016 .

[10]  S. Zaidi,et al.  Development of SVR-based model and comparative analysis with MLR and ANN models for predicting the sorption capacity of Cr(VI) , 2017 .

[11]  Surendra M. Gupta,et al.  Support Vector Machines based Modelling of Concrete Strength , 2008 .

[12]  Dragan A. Cirovic,et al.  Feed-forward artificial neural networks : applications to spectroscopy , 1997 .

[13]  Fei Kang,et al.  Structural health monitoring of concrete dams using long-term air temperature for thermal effect simulation , 2019, Engineering Structures.

[14]  Sunday O. Olatunji,et al.  Hybrid chemometric approach for estimating the heat of detonation of aromatic energetic compounds , 2019, Heliyon.

[15]  Sunday Olusanya Olatunji,et al.  Estimation of average surface energies of transition metal nitrides using computational intelligence technique , 2017, Soft Comput..

[16]  Junjie Li,et al.  Slope reliability analysis using surrogate models via new support vector machines with swarm intelligence , 2016 .

[17]  Sunday O. Olatunji,et al.  Estimation of Superconducting Transition Temperature TC for Superconductors of the Doped MgB2 System from the Crystal Lattice Parameters Using Support Vector Regression , 2015 .

[18]  Peter Stubbs,et al.  The effect of unilateral blood flow restriction on temporal and spatial gait parameters , 2019, Heliyon.

[19]  Dan Boneh,et al.  On genetic algorithms , 1995, COLT '95.

[20]  Abdulazeez Abdulraheem,et al.  A hybrid particle swarm optimization and support vector regression model for modelling permeability prediction of hydrocarbon reservoir , 2017 .

[21]  Yadollah Yamini,et al.  Headspace solvent microextraction and gas chromatographic determination of some polycyclic aromatic hydrocarbons in water samples , 2003 .

[22]  S. Ohnishi,et al.  Double base lesions of DNA by a metabolite of carcinogenic benzo[a]pyrene. , 2002, Biochemical and biophysical research communications.

[23]  Taoreed O. Owolabi,et al.  Determination of the Velocity of Detonation of Primary Explosives Using Genetically Optimized Support Vector Regression , 2019, Propellants, Explosives, Pyrotechnics.

[24]  Joan Colman,et al.  Toxicological profile for total petroleum hydrocarbons (TPH) , 1999 .

[25]  S. Zaidi,et al.  Support Vector Regression Prediction and Analysis of the Copper (II) Biosorption Efficiency , 2017 .

[26]  Abdullah Alqahtani,et al.  Incorporation of GSA in SBLLM-based neural network for enhanced estimation of magnetic ordering temperature of manganite , 2017, J. Intell. Fuzzy Syst..

[27]  W. J. Walker,et al.  Total organic carbon as a screening method for petroleum hydrocarbons , 1999 .

[28]  Dan Cornford,et al.  Optimal design for correlated processes with input-dependent noise , 2014, Comput. Stat. Data Anal..

[29]  Jia Cao,et al.  Multiwalled carbon nanotubes as adsorbents of solid-phase extraction for determination of polycyclic aromatic hydrocarbons in environmental waters coupled with high-performance liquid chromatography. , 2007, Journal of chromatography. A.

[30]  Goldberg,et al.  Genetic algorithms , 1993, Robust Control Systems with Genetic Algorithms.

[31]  Taoreed O. Owolabi,et al.  Development of hybrid extreme learning machine based chemo-metrics for precise quantitative analysis of LIBS spectra using internal reference pre-processing method. , 2018, Analytica chimica acta.

[32]  J. Simal-Gándara,et al.  Stirring bar sorptive extraction in the determination of PAHs in drinking waters. , 2004, Water research.

[33]  M. Ganjali,et al.  Investigation of different linear and nonlinear chemometric methods for modeling of retention index of essential oil components: concerns to support vector machine. , 2009, Journal of hazardous materials.

[34]  Stefano Covino,et al.  An efficient PAH-degrading Lentinus (Panus) tigrinus strain: effect of inoculum formulation and pollutant bioavailability in solid matrices. , 2010, Journal of hazardous materials.

[35]  Sunday Olusanya Olatunji,et al.  Application of computational intelligence technique for estimating superconducting transition temperature of YBCO superconductors , 2016, Appl. Soft Comput..

[36]  Sunday Olusanya Olatunji,et al.  Estimation of physical, mechanical and hydrological properties of permeable concrete using computational intelligence approach , 2016, Appl. Soft Comput..

[37]  Sunday Olusanya Olatunji,et al.  Estimation of surface energies of hexagonal close packed metals using computational intelligence technique , 2015, Appl. Soft Comput..

[38]  Mehdi Jalali-Heravi,et al.  Neural Networks in Analytical Chemistry , 2009, Artificial Neural Networks.