Study on charge de-trapping and dipolar relaxation properties of epoxy resin from discharging current measurements

The behavior of polar polymeric dielectrics at high electric fields is controlled by several factors. Among them, dipolar polarization and trapping and de-trapping of space charge are very important, as they are related to the microstructural properties of the material. From the point of insulation diagnostics, it will be highly beneficial if these two are properly identified from material characteristics, as they can reveal a lot about the aging condition of the material. This study aims to characterize the behavior of dipoles and space charge in a polar dielectric from discharge current measurements. Epoxy resin, a widely used dielectric in high voltage system is chosen as the material of interest. Thin epoxy resin samples are stressed at different electric fields for a fixed time period. Then they are discharged to ground and the discharging current is recorded upto a time period of 10000s. The applied electric field was varied from 2kV/mm to 20 kV/mm during electrical stressing of the samples. The discharging current measurements were performed at two temperatures, 25°C and 50°C on same set of specimens. In this paper an attempt has been made to separate the space charge by correlating frequency domain to time domain measurements using Hamon approximation. It was observed that the charge de-trapping phenomena considerably affects the discharging currents when the samples were previously stressed at high fields (10 kV/mm and 20 kV/mm). The distribution of trapped charge along trap depth was also investigated. It was found, that at high electric stress (20 kV/mm), the trapped charge distribution is exponential in nature at the investigated trap depth range.

[1]  N. Haque,et al.  Studies of the effect of temperature on the charge trapping and de-trapping processes of polymeric insulators through depolarization current measurements , 2017, IEEE Transactions on Dielectrics and Electrical Insulation.

[2]  N. Haque,et al.  Investigations on charge trapping and de-trapping properties of polymeric insulators through discharge current measurements , 2017, IEEE Transactions on Dielectrics and Electrical Insulation.

[3]  George Chen,et al.  Determination of threshold electric field for charge injection in polymeric materials , 2015 .

[4]  N. Gupta,et al.  Effect of ageing on space charge distribution in homogeneous and composite dielectrics , 2015, IEEE Transactions on Dielectrics and Electrical Insulation.

[5]  S. Dodd,et al.  Re-examination of the dielectric spectra of epoxy resins: bulk charge transport and interfacial polarization peaks , 2014, IEEE Transactions on Dielectrics and Electrical Insulation.

[6]  F. Rogti,et al.  Effect of temperature on trap depth formation in multi-layer insulation: Low density polyethylene and fluorinated ethylene propylene , 2014 .

[7]  Y. Ohki,et al.  Charge transport and electrode polarization in epoxy resin at high temperatures , 2014 .

[8]  W. Marsden I and J , 2012 .

[9]  Ruijin Liao,et al.  Charge trapping and detrapping in polymeric materials: Trapping parameters , 2011 .

[10]  Zhiqiang Xu,et al.  Charge trapping and detrapping in polymeric materials , 2009 .

[11]  E. David,et al.  Low-frequency dielectric response of epoxy-mica insulated generator bars during multi-stress aging , 2007, IEEE Transactions on Dielectrics and Electrical Insulation.

[12]  V. Griseri,et al.  Decay of space charge in a glassy epoxy resin following voltage removal , 2006, IEEE Transactions on Dielectrics and Electrical Insulation.

[13]  H. Borsi,et al.  Dielectric response studies on insulating system of high voltage rotating machines , 2006, IEEE Transactions on Dielectrics and Electrical Insulation.

[14]  S. Rowe,et al.  Transient and steady-state currents in epoxy resin , 2006 .

[15]  C. Laurent,et al.  Space charge behaviour in an epoxy resin: the influence of fillers, temperature and electrode material , 2005 .

[16]  D. Fabiani,et al.  Relation between space charge accumulation and partial discharge activity in enameled wires under PWM-like voltage waveforms , 2004, IEEE Transactions on Dielectrics and Electrical Insulation.

[17]  W.S. Zaengl,et al.  Applications of dielectric spectroscopy in time and frequency domain for HV power equipment , 2003, IEEE Electrical Insulation Magazine.

[18]  G. Montanari,et al.  Apparent trap-controlled mobility evaluation in insulating polymers through depolarization characteristics derived by space charge measurements , 2003 .

[19]  W. S. Zaengl,et al.  Dielectric spectroscopy in time and frequency domain for HV power equipment. I. Theoretical considerations , 2003 .

[20]  G. Montanari,et al.  A space-charge based method for the estimation of apparent mobility and trap depth as markers for insulation degradation-theoretical basis and experimental validation , 2003 .

[21]  J. Marat-Mendes,et al.  Space-charge-controlled conductivity in low-density polyethylene , 2003 .

[22]  L. Dissado,et al.  Electroluminescence excitation mechanisms in an epoxy resin under divergent and uniform field , 2002 .

[23]  Gianluca Marcelli,et al.  Models of electron trapping and transport in polyethylene: Current–voltage characteristics , 2002 .

[24]  Nicholas Quirke,et al.  Molecular modeling of electron traps in polymer insulators: Chemical defects and impurities , 2001 .

[25]  V. Griseri The effects of high electric fields on an epoxy resin , 2000 .

[26]  Vahe Der Houhanessian,et al.  Measurement and analysis of dielectric response in oil-paper insulation systems , 1998 .

[27]  T. Hideshima,et al.  Dielectric Relaxations in Poly(γ-n-alkyl L-glutamate)s I. Study of the Relaxations above Room Temperature Using the Direct-Current Technique , 1985 .

[28]  D. Das-gupta,et al.  Charging and discharging currents in polyvinylidene fluoride , 1980 .

[29]  G. Sessler Physical principles of electrets , 1980 .

[30]  T. Dakin Application of Epoxy Resins in Electrical Apparatus , 1974, IEEE Transactions on Electrical Insulation.

[31]  R. Lovell. Decaying and steady currents in an epoxy polymer at high electric fields , 1974 .

[32]  B. V. Hamon,et al.  An approximate method for deducing dielectric loss factor from direct-current measurements , 1952 .