Microstructure, Mechanical Properties and Thermal Stability of Ni-Based Single Crystal Superalloys with Low Specific Weight

Ni-based single crystal (SX) superalloy with low specific weight is vital for developing aero engines with a high strength-to-weight ratio. Based on an alloy system with 3 wt.% Re but without W, namely Ni-Co-Cr-Mo-Ta-Re-Al-Ti, a specific weight below 8.4 g/cm3 has been achieved. To reveal the relationship among the composition, mechanical properties, and thermal stability of Ni-based SX superalloys, SXs with desirable microstructures are fabricated. Tensile tests revealed that the SX alloys have comparable strength to commercial second-generation SX CMSX-4 (3 wt.% Re and 6 wt.% W) and Rene′ N5 alloys (3 wt.% Re and 5 wt.% W) above 800 °C. Moreover, the elongation to fracture (EF) below 850 °C (>20%) is better than that of those two commercial SX superalloys. During thermal exposure at 1050 °C for up to 500 h, the topological close-packed (TCP) phase does not appear, indicating excellent phase stability. Decreasing Al concentration increases the resistance of γ′ rafting and replacing 1 wt.% Ti with 3 wt.% Ta is beneficial to the stability of the shape and size of γ′ phase during thermal exposure. The current work might provide scientific insights for developing Ni-based SX superalloys with low specific weight.

[1]  Junxia Lu,et al.  The effect of amorphous coating on high temperature oxidation resistance of Ni-based single crystal superalloy , 2023, Corrosion Science.

[2]  H. Bei,et al.  Effects of Co on Microstructure Evolution of a 4th Generation Nickel-Based Single Crystal Superalloys , 2023, SSRN Electronic Journal.

[3]  H. Su,et al.  Temperature dependence of compressive behavior and deformation microstructure of a Ni-based single crystal superalloy with low stacking fault energy , 2023, Transactions of Nonferrous Metals Society of China.

[4]  H. Bei,et al.  Composition design and microstructure of Ni-based single crystal superalloy with low specific weight—numerical modeling and experimental validation , 2022, Journal of Materials Research.

[5]  K. Zhou,et al.  A novel Re-free Ni-based single-crystal superalloy with enhanced creep resistance and microstructure stability , 2022, Acta Materialia.

[6]  H. Bei,et al.  The effects of key elements Re and Ru on the phase morphologies and microstructure in Ni-based single crystal superalloys , 2022, Journal of Alloys and Compounds.

[7]  Z. Yue,et al.  Microstructure characterization and damage coupled constitutive modeling of nickel-based single-crystal alloy with different orientations , 2022, Materials Science and Engineering: A.

[8]  Ze Zhang,et al.  Microstructural rejuvenation in a Ni-based single crystal superalloy , 2021, Materials Today Nano.

[9]  Ze Zhang,et al.  The dependence of stress and strain rate on the deformation behavior of a Ni‐based single crystal superalloy at 1050°C , 2021, International Journal of Mechanical System Dynamics.

[10]  Q. Feng,et al.  Effect of alloying elements on the coarsening rate of γʹ precipitates in multi-component CoNi-based superalloys with high Cr content , 2021 .

[11]  Q. Ding,et al.  Nano-twin-induced exceptionally superior cryogenic mechanical properties of a Ni-based GH3536 (Hastelloy X) superalloy , 2021 .

[12]  Ze Zhang,et al.  Temperature effects on deformation substructures and mechanisms of a Ni-based single crystal superalloy , 2021 .

[13]  Yi-zhou Zhou,et al.  Creep Properties of a Nickel-Based Single Crystal Superalloy with Low Density , 2021, Metals and Materials International.

[14]  H. Su,et al.  Effect of alloying elements on stacking fault energies of γ and γʹ phases in Ni-based superalloy calculated by first principles , 2020 .

[15]  J. D. Liu,et al.  Effect of Ru on tensile behavior and deformation mechanism of a nickel-based single crystal superalloy , 2020 .

[16]  R. Singer,et al.  Exploring the fundamentals of Ni-based superalloy single crystal (SX) alloy design: Chemical composition vs. microstructure , 2020 .

[17]  Ze Zhang,et al.  Processing, Microstructures and Mechanical Properties of a Ni-Based Single Crystal Superalloy , 2020, Crystals.

[18]  Ze Zhang,et al.  A review of composition evolution in Ni-based single crystal superalloys , 2020 .

[19]  Ze Zhang,et al.  Microstructural evolution and creep mechanisms in Ni-based single crystal superalloys: A review , 2020 .

[20]  Jinhu Liu,et al.  Temperature dependence on tensile deformation mechanisms in a novel Nickel-based single crystal superalloy , 2020 .

[21]  Y. Pei,et al.  Effects of Alloyed Aluminum and Tantalum on the Topological Inversion Behavior of Ni‐Based Single Crystal Superalloys at High Temperature , 2018, Advanced Engineering Materials.

[22]  Xudong Sun,et al.  Temperature dependence of tensile behavior and deformation microstructure of a Re-containing Ni-base single crystal superalloy , 2017 .

[23]  Yong Liu,et al.  Effect of lattice misfit on the evolution of the dislocation structure in Ni-based single crystal superalloys during thermal exposure , 2016 .

[24]  T. Pollock,et al.  Alloy design for aircraft engines. , 2016, Nature materials.

[25]  Z. Yue,et al.  Tensile behavior of nickel-base single-crystal superalloy DD6 , 2015 .

[26]  E. Affeldt,et al.  Quantitative Experimental Determination of the Solid Solution Hardening Potential of Rhenium, Tungsten and Molybdenum in Single Crystal Nickel-Based Superalloys , 2015 .

[27]  Xiao-feng Sun,et al.  Effects of stacking fault energy on the creep behaviors of Ni-base superalloy , 2014 .

[28]  R. Reed,et al.  Alloys-By-Design: Application to nickel-based single crystal superalloys , 2009 .

[29]  R. Ritchie,et al.  Mo‐Si‐B Alloys for Ultrahigh‐Temperature Structural Applications , 2004, Advanced materials.

[30]  B. Bewlay,et al.  A review of very-high-temperature Nb-silicide-based composites , 2003 .

[31]  S. Putatunda,et al.  Tensile behavior of a new single-crystal nickel-based superalloy (CMSX-4) at room and elevated temperatures , 1994, Journal of Materials Engineering and Performance.

[32]  H. Harada,et al.  Design of Ni-Base Superalloys , 1999 .