Combating global warming via non-fossil fuel energy options

Non-fossil fuel energy options can help reduce or eliminate the emissions of greenhouse gases and are needed to combat climate change. Three distinct ways in which non-fossil fuel options can be used in society are examined here: the capture/production of non-fossil fuel energy sources, their conversion into appropriate energy carriers and increased efficiency throughout the life cycle. Non-fossil fuel energy sources are insufficient to avoid global warming in that they are not necessarily readily utilisable in their natural forms. Hydrogen energy systems are needed to facilitate the use of non-fossil fuels by converting them to two main classes of energy carriers: hydrogen (and hydrogen-derived fuels) and electricity. High efficiency is needed to allow the greatest benefits to be attained from energy options in terms of climate change and other factors. A case study is considered involving the production of hydrogen from non-fossil energy sources via thermochemical water decomposition. Thermochemical water decomposition provides a realistic future non-fossil fuel energy option, which can be driven by non-fossil energy sources (particularly nuclear or solar energy) and help combat global warming.

[1]  Marc A. Rosen,et al.  Exergetic evaluation of the renewability of a biofuel , 2001 .

[2]  S. S. Penner,et al.  Steps toward the hydrogen economy , 2006 .

[3]  G. E. Beghi,et al.  A decade of research on thermochemical hydrogen at the Joint Research Centre, Ispra , 1986 .

[4]  Ibrahim Dincer,et al.  Exergy: Energy, Environment and Sustainable Development , 2007 .

[5]  I. Dincer,et al.  Greenhouse gas emissions reduction by use of wind and solar energies for hydrogen and electricity production: Economic factors , 2007 .

[6]  Ibrahim Dincer,et al.  Economic and environmental comparison of conventional, hybrid, electric and hydrogen fuel cell vehicles , 2006 .

[7]  W. Eisermann,et al.  An exergetic/energetic/economic analysis of three hydrogen production processes - Electrolysis, hybrid, and thermochemical , 1981 .

[8]  V. M. Brodyansky,et al.  The Efficiency of Industrial Processes: Exergy Analysis and Optimization , 1994 .

[9]  Raúl E. Chao,et al.  Thermochemical Hydrogen Production. An Assessment of Nonideal Cycles , 1975 .

[10]  A. Hammache,et al.  A new process for oxygen generation step for the hydrogen producing sulphur-iodine thermochemical cycle , 1994 .

[11]  G. Marbán,et al.  Towards the hydrogen economy , 2007 .

[12]  Ibrahim Dincer,et al.  Exergetic life cycle assessment of hydrogen production from renewables , 2007 .

[13]  Michele A. Lewis,et al.  Study of the Hybrid CU-CL Cycle for Nuclear Hydrogen Production , 2006 .

[14]  Mujid S. Kazimi,et al.  Efficiency of hydrogen production systems using alternative nuclear energy technologies , 2006 .

[15]  A. Bejan,et al.  Thermal Energy Storage: Systems and Applications , 2002 .

[16]  M. S. Casper,et al.  Hydrogen manufacture by electrolysis, thermal decomposition, and unusual techniques , 1978 .

[17]  M. J. Moran,et al.  Exergy Analysis: Principles and Practice , 1994 .

[18]  G. E. Besenbruch,et al.  Preliminary results from bench-scale testing of a sulfur-iodine thermochemical water-splitting cycle , 1980 .

[19]  J. Funk Thermochemical hydrogen production: past and present , 2001 .

[20]  Chu-Sik Park,et al.  Hydrogen Reduction and Subsequent Water Splitting of Zr-Added CeO2 , 2007 .

[21]  Jean-Marc Borgard,et al.  Upper bound and best estimate of the efficiency of the iodine sulphur cycle , 2005 .

[22]  S. Jørgensen,et al.  Towards A Thermodynamic Theory For Ecological Systems , 2004 .

[23]  Mei Gong,et al.  On exergy and sustainable development—Part 1: Conditions and concepts , 2001 .

[24]  Marc A. Rosen,et al.  Thermodynamic comparison of hydrogen production processes , 1996 .

[25]  Enrico Sciubba,et al.  From Engineering Economics to Extended Exergy Accounting: A Possible Path from Monetary to Resource‐Based Costing , 2004 .

[26]  James E. Funk,et al.  Thermochemical production of hydrogen via multistage water splitting processes , 1976 .

[27]  K. F. Knoche,et al.  Second law and cost analysis of the oxygen generation step of the General Atomic sulfur-iodine cycle , 1984 .

[28]  E. I. Yantovskii Energy and exergy currents : an introduction to exergonomics , 1994 .

[29]  Agence pour l'Energie Nucléaire Nuclear Production of Hydrogen , 2004 .

[30]  Gilles Flamant,et al.  Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy , 2006 .

[31]  S. Yalçin,et al.  A review of nuclear hydrogen production , 1989 .

[32]  K. F. Knoche,et al.  Thermochemical production of hydrogen by a vanadium/chlorine cycle. Part 1: An energy and exergy analysis of the process , 1984 .

[33]  Marc A. Rosen,et al.  Application of temperature-distribution models to evaluate the energy and exergy of stratified thermal storages , 2006 .

[34]  Marc A. Rosen,et al.  Second‐law analysis: approaches and implications , 1999 .

[35]  B. Yildiz,et al.  US work on technical and economic aspects of electrolytic, thermochemical, and hybrid processes for hydrogen production at temperatures below 550°C , 2006 .

[36]  Ibrahim Dincer,et al.  Efficiency analysis of a cogeneration and district energy system , 2005 .

[37]  T. Sigfusson,et al.  Pathways to hydrogen as an energy carrier , 2007, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[38]  Catherine P. Koshland,et al.  Two aspects of consumption: using an exergy-based measure of degradation to advance the theory and implementation of industrial ecology , 1997 .

[39]  S. Dunn Hydrogen Futures: Toward a Sustainable Energy System , 2001 .

[40]  Maria H. Maack,et al.  Implementing the hydrogen economy , 2006 .

[41]  Frederick J. Barclay,et al.  Combined Power and Process: An Exergy Approach , 1998 .

[42]  C. Forsberg,et al.  LOWERING PEAK TEMPERATURES FOR NUCLEAR THERMOCHEMICAL PRODUCTION OF HYDROGEN , 2004 .

[43]  R. Heijungs,et al.  Environmental life cycle assessment of products , 1992 .

[44]  V. Utgikar,et al.  Life cycle assessment of ISPRA Mark 9 thermochemical cycle for nuclear hydrogen production , 2006 .

[45]  Michele A. Lewis,et al.  Hydrogen production at {lt} 550{degrees}C using a low temperature thermochemical cycle. , 2003 .

[46]  J. Szargut Exergy Method: Technical and Ecological Applications , 2005 .

[47]  A. Steinfeld Solar thermochemical production of hydrogen--a review , 2005 .

[48]  Ibrahim Dincer,et al.  Recent Canadian advances in nuclear-based hydrogen production and the thermochemical Cu–Cl cycle , 2009 .

[49]  C. Bamberger,et al.  Hydrogen production from water by thermochemical cycles; a 1977 update☆ , 1978 .

[50]  V. Utgikar,et al.  Life cycle assessment of high temperature electrolysis for hydrogen production via nuclear energy , 2006 .

[51]  David Anderson,et al.  David Sandborn Scott, Smelling Land: The Hydrogen Defense Against Climate Catastrophe , 2008 .

[52]  Robert E. Uhrig,et al.  Producing hydrogen using nuclear energy , 2008 .

[53]  Atsushi Tsutsumi,et al.  Adiabatic UT-3 thermochemical process for hydrogen production , 1996 .

[54]  Jan Szargut,et al.  Exergy Analysis of Thermal, Chemical, and Metallurgical Processes , 1988 .

[55]  Ibrahim Dincer,et al.  Exergoeconomic analysis of power plants operating on various fuels , 2003 .

[56]  Ibrahim Dincer,et al.  A preliminary life cycle assessment of PEM fuel cell powered automobiles , 2007 .

[57]  Marc A. Rosen,et al.  On the thermodynamic treatment of diffusion-like economic commodity flows , 2006 .

[58]  Ibrahim Dincer,et al.  A study of industrial steam process heating through exergy analysis , 2004 .

[59]  K. R. Schultz,et al.  HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING THERMOCHEMICAL CYCLES AND NUCLEAR POWER , 2002 .

[60]  K. F. Knoche,et al.  Vapor pressures of the system HI/H2O/I2 and H2 , 1986 .

[61]  Enrico Sciubba,et al.  Exergy-based lumped simulation of complex systems: An interactive analysis tool , 2006 .

[62]  E Bilgen,et al.  Exergy and engineering analyses of hybrid thermochemical solar hydrogen production , 1992 .

[63]  Charles W. Forsberg,et al.  Hydrogen, nuclear energy, and the advanced high-temperature reactor , 2003 .

[64]  M. Rosen Energy and exergy analyses of electrolytic hydrogen production , 1995 .

[65]  Marc A. Rosen,et al.  Energy- and exergy-based comparison of coal-fired and nuclear steam power plants , 2001 .

[66]  M. A. Rosen,et al.  Relation between the exergy of waste emissions and measures of environmental impact , 1998 .

[67]  Enrico Sciubba,et al.  Exergy as a Direct Measure of Environmental Impact , 1999, Advanced Energy Systems.

[68]  Robert H. Edgerton,et al.  Available Energy and Environmental Economics , 2023 .

[69]  V. Utgikar,et al.  Transition to hydrogen economy in the United States: A 2006 status report , 2007 .

[70]  Ibrahim Dincer,et al.  Preliminary life cycle assessment of nuclear-based hydrogen production using thermochemical water decomposition , 2008 .

[71]  Giovanni Cerri,et al.  HYTHEC: An EC funded search for a long term massive hydrogen production route using solar and nuclear technologies , 2007 .

[72]  Michele A. Lewis,et al.  Hydrogen Production at <550°C Using a Low Temperature Thermochemical Cycle , 2004 .

[73]  Ibrahim Dincer,et al.  Technical, environmental and exergetic aspects of hydrogen energy systems , 2002 .

[74]  Marc A. Rosen,et al.  Energy and exergy analyses of PFBC power plants , 1995 .

[75]  A. Steinfeld Solar hydrogen production via a two-step water-splitting thermochemical cycle based on Zn/ZnO redox reactions , 2002 .

[76]  Thorsteinn I. Sigfusson,et al.  Iceland : a future hydrogen economy , 2000 .

[77]  Frederick J. Barclay,et al.  Fuel Cells, Engines and Hydrogen: An Exergy Approach , 2006 .

[78]  Edgar G. Hertwich,et al.  Fission or Fossil: Life Cycle Assessment of Hydrogen Production , 2006, Proceedings of the IEEE.

[79]  Enrico Sciubba,et al.  A Brief Review of Methods for the Design and Synthesis Optimization of Energy Systems , 2002 .

[80]  Ibrahim Dincer,et al.  Exergy-cost-energy-mass analysis of thermal systems and processes , 2003 .

[81]  M. A. Rosen,et al.  An energy-exergy analysis of the Koppers-Totzek process for producing hydrogen from coal☆ , 1987 .

[82]  R. W. K. Allen,et al.  Limiting thermodynamic efficiencies of thermochemical cycles used for hydrogen generation , 2006 .

[83]  Ibrahim Dincer,et al.  Exergy analysis of waste emissions , 1999 .

[84]  Ibrahim Dincer,et al.  On exergy and environmental impact , 1997 .

[85]  Marc A. Rosen,et al.  The economic order quantity repair and waste disposal model with entropy cost , 2008, Eur. J. Oper. Res..

[86]  Hedzer J. van der Kooi,et al.  Exergy Sustainability Indicators as a Tool in Industrial Ecology , 2007 .

[87]  Ibrahim Dincer,et al.  Role of exergy in increasing efficiency and sustainability and reducing environmental impact , 2008 .

[88]  Jean-Michel Hartmann,et al.  Total and partial pressure measurements for the sulphur–iodine thermochemical cycle , 2007 .

[89]  Fritz Gautschi,et al.  The hydrogen reaction , 2005 .

[90]  Marc A. Rosen,et al.  Comparative efficiency assessments for a range of hydrogen production processes , 1998 .

[91]  Cesare Marchetti,et al.  Long-term global vision of nuclear-produced hydrogen , 2006 .

[92]  M. A. Rosen,et al.  Thermodynamic investigation of hydrogen production by steam-methane reforming , 1991 .

[93]  Robert U. Ayres,et al.  EXERGY, WASTE ACCOUNTING, AND LIFE-CYCLE ANALYSIS , 1998 .

[94]  K. F. Knoche,et al.  Thermochemical water splitting through direct Hi-decomposition from H2O/HI/I2 solutions , 1989 .

[95]  U. Balachandran,et al.  Use of mixed conducting membranes to produce hydrogen by water dissociation , 2004 .

[96]  Manfred Fischedick,et al.  Towards sustainable energy systems: The related role of hydrogen , 2006 .

[97]  Stefan Baumgärtner,et al.  Necessity and Inefficiency in the Generation of Waste , 2003 .