Neue Beiträge zur Chemie des Mangans: Synthese und Strukturen zweier monomerer MnII1‐Verbindungen und eines hexanuklearen MnII/III1‐Komplexes

New Contributions to the Chemistry of Manganese: Syntheses and Structures of two Monomeric MnII Compounds and a Hexanuclear MnII/III Complex Two novel mononuclear manganese(II) complexes, Mn[OSi(OtBu)3]2·(Py)3 (2) and Mn[PhC6H4C(NSiMe3)2]2·THF (3), and a hexanuclear mixed-valence manganese(II/III) complex Mn6O2(O2CtBu)10·(Py)4 (5) have been prepared, and their structures have been determined by X-ray crystal structure analyses.

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