Adsorption of Pb(II) from aqueous solutions using activated carbon developed from Apricot stone

article i nfo Low-cost activated carbon was prepared from Apricot stone material by chemical activation with sulphuric acid for the adsorption of Pb(II) from dilute aqueous solution. The activated carbon developed shows substantial capacity to adsorb Pb(II) from dilute aqueous solutions. The parameters studied include physical and chemical properties of adsorbent, pH, adsorbent dose, contact time and initial concentrations. The percent removal increased with pH from 1.5 to 5. The optimum pH required for maximum adsorption was found to be 6.0. Adsorption kinetics data were modeled using the pseudo-first and pseudo-second-order models. The results indicate that the second-order model best describes adsorption kinetic data. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models. The estimated maximum capacities of lead ions adsorbed by Apricot stone activated with sulphuric acid were 21.38 mg g �1 . The adsorbent derived from this material is expected to be an economical product for metal ion remediation from water and wastewater. © 2011 Elsevier B.V. All rights reserved.

[1]  H. C. Bruun Hansen,et al.  Sorption of zinc and lead on coir. , 2007, Bioresource technology.

[2]  A. F. A Text-Book of Physical Chemistry , 1935, Nature.

[3]  C. R. Mohanty,et al.  Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind wood activated with sulphuric acid. , 2008, Journal of hazardous materials.

[4]  Cathy Theresa Thomas Trace elements. , 2013, Lancet.

[5]  R. Mark Bricka,et al.  A review of potentially low-cost sorbents for heavy metals , 1999 .

[6]  K. Low,et al.  Sorption of copper by dye-treated oil-palm fibres , 1993 .

[7]  A. Ahmad,et al.  Oryza sativa L. husk as heavy metal adsorbent: optimization with lead as model solution. , 2006, Bioresource technology.

[8]  Thomas W. Weber,et al.  Pore and solid diffusion models for fixed-bed adsorbers , 1974 .

[9]  A. Martell,et al.  Environmental inorganic chemistry , 1985 .

[10]  Gordon McKay,et al.  ADSORPTION OF DYES ON CHITIN , 1982 .

[11]  M. Ajmal,et al.  Role of sawdust in the removal of copper(II) from industrial wastes , 1998 .

[12]  N. Chandra,et al.  Kinetics and Isotherms for Aqueous Lead Adsorption by Natural Minerals , 2000 .

[13]  S. Al-Asheh,et al.  BINARY METAL SORPTION BY PINE BARK : STUDY OF EQUILIBRIA AND MECHANISMS , 1998 .

[14]  Y. Yürüm,et al.  Cation exchange properties of low rank Turkish coals: removal of Hg, Cd and Pb from waste water , 2000 .

[15]  Jo‐Shu Chang,et al.  Biosorption of lead, copper and cadmium by biomass of Pseudomonas aeruginosa PU21 , 1997 .

[16]  W. Höll,et al.  Description of sorption equilibria for ions onto activated carbon using the surface complexation theory , 1997 .

[17]  Y. Ho,et al.  Pseudo-second order model for sorption processes , 1999 .

[18]  V. Gupta,et al.  Process development for the removal of lead and chromium from aqueous solutions using red mud--an aluminium industry waste. , 2001, Water research.

[19]  M. Schiavello Photocatalysis and Environment , 1988 .

[20]  F. Okieimen,et al.  Binding of cadmium, copper, and lead ions by modified cellulosic materials , 1985, Bulletin of environmental contamination and toxicology.

[21]  G. Mckay,et al.  Adsorption of dyes on chitin. I. Equilibrium studies , 1982 .

[22]  Vincent Gloaguen,et al.  Removal of heavy metal ions from aqueous solution by modified barks , 1997 .

[23]  M. Petrangeli Papini,et al.  Kaolinite sorption of Cd, Ni and Cu from landfill leachates: influence of leachate composition. , 2001, Water science and technology : a journal of the International Association on Water Pollution Research.

[24]  M. Pazirandeh,et al.  Comparison of Ion-Exchange Resins and Biosorbents for the Removal of Heavy Metals from Plating Factory Wastewater , 1997 .

[25]  S. Shukla,et al.  The removal of heavy metals from aqueous solutions by sawdust adsorption--removal of lead and comparison of its adsorption with copper. , 2001, Journal of hazardous materials.

[26]  Gordon McKay,et al.  The Sorption of Lead(II) Ions on Peat , 1999 .

[27]  Z. Baysal,et al.  Removal of Pb(II) from wastewater using wheat bran. , 2006, Journal of environmental management.

[28]  Heechan Cho,et al.  A study on removal characteristics of heavy metals from aqueous solution by fly ash. , 2005, Journal of hazardous materials.

[29]  D. Hawker,et al.  Effects of pH and Salinity on Copper, Lead, and Zinc Sorption Rates in Sediments from Moreton Bay, Australia , 2004, Bulletin of environmental contamination and toxicology.

[30]  William E Lee,et al.  Interactions of aqueous Cu2+, Zn2+ and Pb2+ ions with crushed concrete fines. , 2005, Journal of hazardous materials.

[31]  Y. Bulut,et al.  Removal of heavy metal ions by modified sawdust of walnut , 2003 .