Earth abundant, non-toxic, 3D printed Cu2−xS with high thermoelectric figure of merit

Bulk non-toxic and Earth abundant Cu2−xS is pseudo-3D printed in a low-cost method yielding ZT values of up to 0.63.

[1]  A. Powell Recent developments in Earth-abundant copper-sulfide thermoelectric materials , 2019, Journal of Applied Physics.

[2]  Matthew J. Carnie,et al.  3D Printed SnSe Thermoelectric Generators with High Figure of Merit , 2019, Advanced Energy Materials.

[3]  Kexiang Zhang,et al.  Facile synthesis and thermoelectric properties of Cu1.96S compounds , 2018, Journal of Solid State Chemistry.

[4]  Matthew J. Carnie,et al.  Thin Film Tin Selenide (SnSe) Thermoelectric Generators Exhibiting Ultralow Thermal Conductivity , 2018, Advanced materials.

[5]  Min Ho Lee,et al.  3D printing of shape-conformable thermoelectric materials using all-inorganic Bi2Te3-based inks , 2018 .

[6]  M. Kanatzidis,et al.  High-Performance PbTe Thermoelectric Films by Scalable and Low-Cost Printing , 2018 .

[7]  M. Rabinal,et al.  Large-scale synthesis of copper sulfide by using elemental sources via simple chemical route. , 2017, Ultrasonics sonochemistry.

[8]  Jun Pei,et al.  CuxS superionic compounds: Electronic structure and thermoelectric performance enhancement , 2017 .

[9]  Yao Yao,et al.  Thermoelectric performance enhancement of Cu2S by Se doping leading to a simultaneous power factor increase and thermal conductivity reduction , 2017 .

[10]  Yun Tang,et al.  Synthesis and Thermoelectric Properties of Copper Sulfides via Solution Phase Methods and Spark Plasma Sintering , 2017 .

[11]  Chao Wang,et al.  Chemical Precipitation Synthesis and Thermoelectric Properties of Copper Sulfide , 2017, Journal of Electronic Materials.

[12]  S. LeBlanc,et al.  Printed thermoelectric materials and devices: Fabrication techniques, advantages, and challenges , 2017 .

[13]  X. Su,et al.  Mechanochemical synthesis of high thermoelectric performance bulk Cu2X (X = S, Se) materials , 2016 .

[14]  Steve Beeby,et al.  Flexible screen printed thermoelectric generator with enhanced processes and materials , 2016 .

[15]  G. J. Snyder,et al.  High thermoelectric and mechanical performance in highly dense Cu2−xS bulks prepared by a melt-solidification technique , 2015 .

[16]  N. Ahmad,et al.  Thermal decomposition kinetics of sodium carboxymethyl cellulose: Model-free methods , 2014 .

[17]  G. Dennler,et al.  Are Binary Copper Sulfides/Selenides Really New and Promising Thermoelectric Materials? , 2014 .

[18]  G. J. Snyder,et al.  High Thermoelectric Performance in Non‐Toxic Earth‐Abundant Copper Sulfide , 2014, Advanced materials.

[19]  Daoben Zhu,et al.  Inkjet-printed flexible organic thin-film thermoelectric devices based on p- and n-type poly(metal 1,1,2,2-ethenetetrathiolate)s/polymer composites through ball-milling , 2014, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[20]  M. Salavati‐Niasari,et al.  Surfactant-Free Fabrication of Copper Sulfides (CuS, Cu2S) via Hydrothermal Method , 2013, Journal of Cluster Science.

[21]  Yongjun Peng,et al.  The oxidation of copper sulfide minerals during grinding and their interactions with clay particles , 2012 .

[22]  Imrich Chlamtac,et al.  Internet of things: Vision, applications and research challenges , 2012, Ad Hoc Networks.

[23]  Yufeng Zhao,et al.  Crystal and electronic structures of CuxS solar cell absorbers , 2012 .

[24]  Weihua Chen,et al.  Large-scale synthesis and catalysis properties of micro-structured snowflake Cu2S from a single source Cu(II) coordination complex , 2011 .

[25]  Jianbo Wang,et al.  Controllable synthesis of self-assembled Cu2S nanostructures through a template-free polyol process for the degradation of organic pollutant under visible light , 2009 .

[26]  R. Vullers,et al.  Wearable Thermoelectric Generators for Body-Powered Devices , 2009 .

[27]  G. J. Snyder,et al.  Complex thermoelectric materials. , 2008, Nature materials.

[28]  Jeunghee Park,et al.  In-situ growth of copper sulfide nanocrystals on multiwalled carbon nanotubes and their application as novel solar cell and amperometric glucose sensor materials. , 2007, Nano letters.

[29]  R. Rosenberg,et al.  The oxidation states of copper and iron in mineral sulfides, and the oxides formed on initial exposure of chalcopyrite and bornite to air , 2006 .

[30]  Gangshan Wu,et al.  Large-scale synthesis and self-assembly of monodisperse hexagon Cu2S nanoplates. , 2005, Langmuir : the ACS journal of surfaces and colloids.

[31]  M. Mori,et al.  Valence band photoemission study of the copper chalcogenide compounds, Cu2S, Cu2Se and Cu2Te , 2003 .

[32]  U. Tinggi Essentiality and toxicity of selenium and its status in Australia: a review. , 2003, Toxicology letters.

[33]  Pradyot Patnaik,et al.  Handbook of Inorganic Chemicals , 1997 .

[34]  I. Nakai,et al.  X-ray photoelectron spectroscopic study of copper minerals , 1976 .

[35]  L. Stil’bans,et al.  Physical problems of thermoelectricity , 1959 .

[36]  D. A. Wright Thermoelectric Properties of Bismuth Telluride and its Alloys , 1958, Nature.

[37]  A. Smakula,et al.  Precision Density Determination of Large Single Crystals by Hydrostatic Weighing , 1955 .

[38]  A. L. Patterson The Scherrer Formula for X-Ray Particle Size Determination , 1939 .