Influence of Impressed Current on the Initiation of Damage in Reinforced Mortar Due to Corrosion of Embedded Steel

Abstract Corrosion of steel in cementitious material is a slow process. Therefore in this study, accelerated corrosion tests were carried out by impressing current between steel embedded in mortar and a counter-electrode to study the process of corrosion leading to cracking in mortar. The specimens, which were made of mortar reinforced with steel, were immersed in solutions which contained or did not contain chlorides. Critical times with respect to the onset of corrosion can be defined in various ways by using either steel half-cell potential, or potential drop between embedded steel and a counter-electrode, or expansion of the mortar specimen. These parameters give quite similar critical times and are related to the development of corrosion products and microcracking. The results obtained provide information on corrosion kinetics of embedded steel when corrosion is accelerated by impressed current and show the similarities to natural corrosion pattern when solutions contain chlorides.

[1]  Y. Berthaud,et al.  Numerical simulation of potential distribution due to the corrosion of reinforcement in concrete structures , 2005 .

[2]  Philippe Dillmann,et al.  Long-term corrosion resistance of metallic reinforcements in concrete—a study of corrosion mechanisms based on archaeological artefacts , 2005 .

[3]  Ilie Petre-Lazar Évaluation du comportement en service des ouvragesen béton armé soumis à la corrosion des aciers, outil d'aide à ladécision , 2001 .

[4]  M. Pourbaix Thermodynamics and corrosion , 1990 .

[5]  Abdelkarim Aït-Mokhtar,et al.  Corrosion by chlorides in reinforced concrete: Determination of chloride concentration threshold by impedance spectroscopy , 2004 .

[6]  A. Limam,et al.  STUDY AND CHARACTERIZATION BY ACOUSTIC EMISSION AND ELECTROCHEMICAL MEASUREMENTS OF CONCRETE DETERIORATION CAUSED BY REINFORCEMENT STEEL CORROSION , 2003 .

[7]  Raoul François,et al.  Effect of microcracking and cracking on the development of corrosion in reinforced concrete members , 1999 .

[8]  U. Schwertmann,et al.  Iron Oxides in the Laboratory: Preparation and Characterization , 1991 .

[9]  Khaled Soudki,et al.  Effectiveness of Impressed Current Technique to Simulate Corrosion of Steel Reinforcement in Concrete , 2003 .

[10]  C. Andrade,et al.  Some questions on the corrosion of steel in concrete—Part I: when, how and how much steel corrodes , 1996 .

[11]  J. G. Cabrera,et al.  Deterioration of concrete due to reinforcement steel corrosion , 1996 .

[12]  O. Poupard,et al.  Corrosion damage diagnosis of a reinforced concrete beam after 40 years natural exposure in marine environment , 2006 .

[13]  W. Prince,et al.  Mechanisms involved in the accelerated test of chloride permeability , 1999 .

[14]  K. Sagoe-Crentsil,et al.  "GREEN RUST", IRON SOLUBILITY AND THE ROLE OF CHLORIDE IN THE CORROSION OF STEEL AT HIGH PH , 1993 .

[15]  Richard E. Weyers,et al.  MODELING THE TIME-TO-CORROSION CRACKING IN CHLORIDE CONTAMINATED REINFORCED CONCRETE STRUCTURES , 1998 .

[16]  Carolyn M. Hansson,et al.  The effect of the electrochemical chloride extraction treatment on steel-reinforced mortar Part II: Microstructural characterization , 1999 .

[17]  S. Jang,et al.  Experimental investigation of the threshold chloride concentration for corrosion initiation in reinforced concrete structures , 2003 .

[18]  Cruz Alonso,et al.  Cover cracking as a function of bar corrosion: Part I-Experimental test , 1993 .

[19]  Sebastián Feliu,et al.  Initial steps of corrosion in the steel/Ca(OH)2 + Cl− system: The role of heterogeneities on the steel surface and oxygen supply , 1993 .

[20]  S. Caré Influence of aggregates on chloride diffusion coefficient into mortar , 2003 .

[21]  Pd Cady,et al.  Chloride Penetration and the Deterioration of Concrete Bridge Decks , 1983 .

[22]  Paulo J.M. Monteiro,et al.  Stress analysis of expansive reactions in concrete , 2000 .

[23]  C. Andrade,et al.  Factors controlling cracking of concrete affected by reinforcement corrosion , 1998 .

[24]  Quang Thanh Nguyen Etudes expérimentale et théorique de l'effet de la corrosion sur la fissuration du béton et le comportement global des structures en béton armé , 2006 .

[25]  K. K. Sagoe-Crentsil,et al.  Steel in concrete: part I: a review of the electrochemical and thermodynamic aspects , 1989 .

[26]  Y. Ballim,et al.  Reinforcement corrosion and the deflection of RC beams––an experimental critique of current test methods , 2003 .

[27]  J. Ollivier,et al.  Aspects électrochimiques de l'essai accéléré de perméabilité aux ions chlorures , 1999 .

[28]  K. Lundgren,et al.  Corrosion influence on bond in reinforced concrete , 2004 .