Model-based identification and experimental validation of the optimal reaction route for the hydroformylation of 1-dodecene

Previously developed kinetic and dynamic models of the hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system (TMS), consisting of DMF, n-decane, and hydroformylation produ...

[1]  Arno Behr,et al.  Advances in thermomorphic liquid/liquid recycling of homogeneous transition metal catalysts , 2008 .

[2]  B. Subramaniam Gas-expanded liquids for sustainable catalysis and novel materials: Recent advances , 2010 .

[3]  Arno Behr,et al.  Analysis of the reaction network for the Rh-catalyzed hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system , 2013 .

[4]  H. Arellano‐Garcia,et al.  Kinetics of 1-dodecene hydroformylation in a thermomorphic solvent system using a rhodium-biphephos catalyst , 2014 .

[5]  B. Subramaniam Exploiting Neoteric Solvents for Sustainable Catalysis and Reaction Engineering: Opportunities and Challenges , 2010 .

[6]  Arno Behr,et al.  Temperature‐Dependent Multicomponent Solvent Systems – An Alternative Concept for Recycling Homogeneous Catalysts , 2002 .

[7]  A. Sharma,et al.  Hydroformylation of 1-Octene Using [Bmim][PF6]−Decane Biphasic Media and Rhodium Complex Catalyst: Thermodynamic Properties and Kinetic Study , 2010 .

[8]  Kai Sundmacher,et al.  Simultaneous design of the optimal reaction and process concept for multiphase systems , 2014 .

[9]  G. Sadowski,et al.  Liquid–Liquid Equilibria of Systems with Linear Aldehydes. Experimental Data and Modeling with PCP-SAFT , 2012 .

[10]  K. Sundmacher,et al.  Towards a Methodology for the Systematic Analysis and Design of Efficient Chemical Processes - Part 1: From Unit Operations to Elementary Process Function- , 2008 .

[11]  Kai Sundmacher,et al.  Modellbasierte Ermittlung der optimalen Reaktionsführung für integrierte Mehrphasenprozesse , 2014 .

[12]  P. V. Leeuwen,et al.  Phenoxaphosphino‐Modified Xantphos‐Type Ligands in the Rhodium‐Catalysed Hydroformylation of Internal and Terminal Alkenes , 2004 .

[13]  Arno Behr,et al.  Hydroformylation of 1-Dodecene in the Thermomorphic Solvent System Dimethylformamide/Decane. Phase Behavior–Reaction Performance–Catalyst Recycling , 2012 .

[14]  Bahram Moasser,et al.  Mechanistic Aspects of a Highly Regioselective Catalytic Alkene Hydroformylation using a Rhodium Chelating Bis(phosphite) Complex , 1995 .

[15]  Reinhard Schomäcker,et al.  Hydroformylation of 1-dodecene using Rh-TPPTS in a microemulsion , 2002 .

[16]  A. Sharma,et al.  Kinetics of hydroformylation of 1-octene in ionic liquid-organic biphasic media using rhodium sulfoxantphos catalyst , 2011 .

[17]  Kent A. Pennybaker,et al.  Economic and Environmental Impact Analyses of Catalytic Olefin Hydroformylation in CO2-Expanded Liquid (CXL) Media , 2007 .