Plasma-enabled, catalyst-free growth of carbon nanotubes on mechanically-written Si features with arbitrary shape

Abstract Simple, rapid, catalyst-free synthesis of complex patterns of long, vertically aligned multiwalled carbon nanotubes, strictly confined within mechanically-written features on a Si(1 0 0) surface is reported. It is shown that dense arrays of the nanotubes can nucleate and fully fill the features when the low-temperature microwave plasma is in a direct contact with the surface. This eliminates additional nanofabrication steps and inevitable contact losses in applications associated with carbon nanotube patterns.

[1]  Igor Levchenko,et al.  Plasma-assisted self-organized growth of uniform carbon nanocone arrays , 2007 .

[2]  M. Keidar,et al.  Factors affecting the size and deposition rate of the cathode deposit in an anodic arc used to produce carbon nanotubes , 2008 .

[3]  J. Nørskov,et al.  Atomic-scale imaging of carbon nanofibre growth , 2004, Nature.

[4]  Chang Liu,et al.  Metal-catalyst-free growth of single-walled carbon nanotubes. , 2009, Journal of the American Chemical Society.

[5]  V. Palermo,et al.  Formation of nanoclusters on silicon from carbon deposition , 2004 .

[6]  S. Lau,et al.  Room-temperature growth of carbon nanofibers on plastic substrates , 2006 .

[7]  Wei-Hung Chiang,et al.  Linking catalyst composition to chirality distributions of as-grown single-walled carbon nanotubes by tuning Ni(x)Fe(1-x) nanoparticles. , 2009, Nature materials.

[8]  Satoru Suzuki,et al.  Carbon nanotube growth from semiconductor nanoparticles. , 2007, Nano letters.

[9]  S. Xie,et al.  Patterned Carbon Nanotubes with Adjustable Array: A Functional Breath Figure Approach , 2010 .

[10]  U. Gösele,et al.  Incorporation, Diffusion and Agglomeration of Carbon in Silicon , 2001 .

[11]  Davide Mariotti,et al.  The production of self-organized carbon connections between Ag nanoparticles using atmospheric microplasma synthesis , 2009 .

[12]  M. Roukes Nanoelectromechanical Systems , 2000, cond-mat/0008187.

[13]  W I Milne,et al.  Carbon nanotubes integrated in electrically insulated channels for lab-on-a-chip applications. , 2009, Nanotechnology.

[14]  G. Popa,et al.  Mechanism of peptide modification by low-temperature microwave plasma , 2011 .