Electrochemistry and the environment

Advances in electrochemical methods for pollutant remediation, recycling and sensing are reviewed. Additionally, applications of these methods in the drinking water industry, and for disinfection scenarios are discussed. Lastly, new electrode materials for environmental applications are described. In a companion review, photoelectrochemical methods will be discussed.

[1]  Roy L. Wolfe,et al.  Ultraviolet disinfection of potable water. , 1990 .

[2]  I. Rubinstein,et al.  The Effect of Composition of Nafion Deposition Solutions on the Diffusional Properties of the Films , 1993 .

[3]  A. Sammells,et al.  Ambient Temperature Gas Phase CO 2 Reduction to Hydrocarbons at Solid Polymer Electrolyte Cells , 1988 .

[4]  Graeme E. Batley,et al.  Application of polymer-coated glassy carbon electrodes in anodic stripping voltammetry , 1987 .

[5]  T. Seiyama,et al.  Chemical sensor technology , 1988 .

[6]  C. Pulgarin,et al.  Anodic oxidation of phenol for waste water treatment , 1991 .

[7]  Ralph E. White,et al.  Hydrogen Diffusion, Solubility, and Water Uptake in Dow's Short‐Side‐Chain Perfluorocarbon Membranes , 1992 .

[8]  J. Bockris,et al.  Electrochemical Inactivation of Marine Bacteria , 1981 .

[9]  Dennis C. Johnson,et al.  Electrocatalysis of Anodic Oxygen‐Transfer Reactions Fe‐Doped Beta‐Lead Dioxide Electrodeposited on Noble Metals , 1990 .

[10]  Y. Oren,et al.  Removal of chromium from aqueous solutions by treatment with porous carbon electrodes: Electrochemical principles , 1989 .

[11]  A. Fogg,et al.  Flow injection voltammetric determination of nitrate after reduction to nitrite , 1983 .

[12]  F. Walsh,et al.  Electrode materials for electrosynthesis , 1990 .

[13]  H. Yeager,et al.  Perfluorinated Ionomer Membranes , 1982 .

[14]  M. Steinberg,et al.  The Electrochemical Reduction of Carbon Dioxide, Formic Acid, and Formaldehyde , 1977 .

[15]  Norman Hackerman,et al.  The Electroreduction of Carbon Dioxide and Formic Acid on Tin and Indium Electrodes , 1983 .

[16]  A. Fogg,et al.  Sequential flow injection voltammetric determination of phosphate and nitrite by injection of reagents into a sample stream , 1984 .

[17]  F. Beck,et al.  Chromium-titanium-antimony oxide composite anodes: Electro-organic oxidations , 1987 .

[18]  D. Chakraborti,et al.  Determination of arsenite and arsenate by differential pulse polarography , 1984 .

[19]  M. Baizer,et al.  The electrochemistry of biomass and derived materials , 1985 .

[20]  P. Dasgupta,et al.  Amperometric microsensor for water , 1990 .

[21]  Jaromir Růžička,et al.  Flow injection analysis , 1981 .

[22]  L. Bachas,et al.  Anion-Selective Electrodes Based on Electropolymerized Porphyrin Films , 1991 .

[23]  J. Sauvage,et al.  Electrocatalytic reduction of carbon dioxide by nickel cyclam2+ in water: study of the factors affecting the efficiency and the selectivity of the process. , 1986, Journal of the American Chemical Society.

[24]  V. S. Bagotzky,et al.  Electroreduction of carbon dioxide: Part II. The mechanism of reduction in aprotic solvents , 1985 .

[25]  Stanley R. Crouch,et al.  Computer Controlled Bipolar Pulse Conductivity System for Applications in Chemical Rate Determinations , 1978 .

[26]  Norio Miura,et al.  Solid Electrolyte CO2 Sensor Using Binary Carbonate Electrode , 1990 .

[27]  D. Simonsson.  A flow-by packed-bed electrode for removal of metal ions from waste waters , 1984 .

[28]  B. M. Petronio,et al.  Differential pulse polarographic determination of arsenic, selenium and tellurium at mug levels. , 1989, Talanta.

[29]  Bruce J. Tatarchuk,et al.  Metal‐Carbon Composite Materials from Fiber Precursors I . Preparation of Stainless Steel—Carbon Composite Electrodes , 1990 .

[30]  W. Geiger,et al.  Analytical and mechanistic studies of the electrochemical reduction of biologically active organoarsenic acids , 1978 .

[31]  T. Hori,et al.  Electrolytic reduction of molybdophosphate in aqueous acetonitrile and its application to flow-coulometric determination of orthophosphate. , 1983, Talanta.

[32]  F. Walsh,et al.  Reticulated vitreous carbon cathodes for metal ion removal from process streams Part III: Studies of a single pass reactor , 1993 .

[33]  J. Keller.  Bipolar-pulse conductivity detector for ion chromatography , 1981 .

[34]  R. McCreery,et al.  Doped glassy carbon materials (DGC): Low-temperature synthesis, structure, and catalytic behavior , 1990 .

[35]  D. C. Johnson,et al.  Stripping voltammetry with collection at a rotating ring-disk electrode. , 1973, Talanta.

[36]  C. R. Martin,et al.  Fresh look at transport in perfluorosulfonate ionomers: ultramicroelectrode investigations of Nafion and the Dow ionomers , 1989 .

[37]  R. Dessy,et al.  Potentiometric stripping with matrix exchange techniques in flow injection analysis of heavy metals in groundwaters , 1983 .

[38]  A. Granéli,et al.  Potentiometric stripping analysis , 1976 .

[39]  N. Lewis,et al.  Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine , 1984 .

[40]  Hsuan‐Jung Huang,et al.  Determination of trace elements in sea water by flow-injection anodic stripping voltammetry preceded by immobilized quinolin-8-ol silica gel preconcentration , 1992 .

[41]  D. Ingersoll,et al.  Preparation of doped carbon films , 1991 .

[42]  S. Kapusta,et al.  Carbon Dioxide Reduction at a Metal Phthalocyanine Catalyzed Carbon Electrode , 1984 .

[43]  C. R. Martin,et al.  Luminescence Probe Studies of Nafion Polyelectrolytes , 1984 .

[44]  A. Profumo,et al.  Voltammetric determination of some organic compounds of arsenic reduced at the mercury electrode , 1985 .

[45]  S. Pizzini,et al.  Electrochemical solid-state sensor for SO2 determination in air , 1990 .

[46]  A. Soffer,et al.  The electrodeposition of trace metallic impurities: dependence on the supporting electrolyte concentration—a comparison between bipolar and monopolar porous electrodes , 1987 .

[47]  F. T. Henry,et al.  Determination of arsenic(III), arsenic(V), monomethylarsonate, and dimethylarsinate by differential pulse polarography after separation by ion exchange chromatography , 1980 .

[48]  R. S. Sadana.  Determination of arsenic in the presence of copper by differential pulse cathodic stripping voltammetry at a hanging mercury drop electrode , 1983 .

[49]  S. Uchiyama,et al.  Highly sensitive electrochemical sensor for ozone in water using porous carbon felt electrode , 1993 .

[50]  Hsuan‐Jung Huang,et al.  APPLICATION OF A POLYANILINE-NAFION COMPOSITE ELECTRODE TO THE DETERMINATION OF ALKALI AND ALKALINE EARTH METAL IONS USING FLOW-INJECTION ANALYSIS AND ION CHROMATOGRAPHY , 1991 .

[51]  BARNETT ROSENBERG,et al.  Inhibition of Cell Division in Escherichia coli by Electrolysis Products from a Platinum Electrode , 1965, Nature.

[52]  M. Rice,et al.  Ion exchange and transport of neurotransmitters in nation films on conventional and microelectrode surfaces , 1985 .

[53]  J. Bockris,et al.  Electrochemical Incineration of Wastes , 1989 .

[54]  Zhiqiang Gao,et al.  Differential pulse voltammetric determination of cobalt with a perfluorinated sulfonated polymer-2,2-bipyridyl modified carbon paste electrode , 1991 .

[55]  D. Jagner.  Instrumental approach to potentiometric stripping analysis of some heavy metals , 1978 .

[56]  L. Treitinger,et al.  Preparation of Fast Detecting SnO2 Gas Sensors , 1980 .

[57]  F. Walsh,et al.  Reticulated vitreous carbon cathodes for metal ion removal from process streams part I: Mass transport studies , 1991 .

[58]  C. R. Martin,et al.  Effect of hydrophobic interactions on the rates of ionic diffusion in nafion films at electrode surfaces , 1983 .

[59]  Thomas F. Fuller,et al.  Experimental Determination of the Transport Number of Water in Nafion 117 Membrane , 1992 .

[60]  C. Pulgarin,et al.  Electrochemical oxidation of phenol for wastewater treatment using SnO2, anodes , 1993 .

[61]  V. S. Bagotzky,et al.  Electroreduction of carbon dioxide: Part III. Adsorption and reduction of CO2 on platinum , 1985 .

[62]  J. Osteryoung,et al.  Arrays of very small voltammetric electrodes based on reticulated vitreous carbon , 1984 .

[63]  B. Beden,et al.  The electrooxidation of CO: a test reaction in electrocatalysis , 1990 .

[64]  R. Alkire,et al.  Two‐Dimensional Current Distribution Within a Packed‐Bed Electrochemical Flow Reactor , 1974 .

[65]  P. Dasgupta,et al.  Electrodialytic eluent generation and suppression. Ultralow bacground conductance suppressed anion chromatography , 1991 .

[66]  K. Stulík,et al.  Electrochemical Detection in Hight-Performance Liquid Chromatography , 1984 .

[67]  Ponisseril Somasundaran,et al.  Pulsed electrogeneration of bubbles for electroflotation , 1991 .

[68]  Norio Miura,et al.  Characteristics and sensing mechanism of SOx sensor using stabilized zirconia and metal sulphate , 1993 .

[69]  S. Yamaguchi,et al.  Hydrogen ion selective microelectrode prepared by modifying an electrode with polymers , 1987 .

[70]  Hiroshi Osanai,et al.  Gas Polarographic Oxygen Sensor Using an Oxygen/Zirconia Electrolyte , 1989 .

[71]  W. C. Bauman,et al.  Novel ion exchange chromatographic method using conductimetric detection , 1975 .

[72]  J. Rusling.  Controlling electrochemical catalysis with surfactant microstructures , 1991 .

[73]  G. Patermarakis,et al.  Disinfection of water by electrochemical treatment , 1990 .

[74]  Rüdiger Kötz,et al.  Electrochemical waste water treatment using high overvoltage anodes Part II: Anode performance and applications , 1991 .

[75]  E. Avci.  Electrolytic recovery of copper from dilute solutions considering environmental measures , 1988 .

[76]  N. Tran,et al.  The Use of the Oxidation of Barium Peroxide in Aqueous Surfactant Systems in the Electrolytic Destruction of Organic Compounds , 1991 .

[77]  E. Wang,et al.  Polyaniline chemically modified electrode for detection of anions in flow-injection analysis and ion chromatography , 1991 .

[78]  M. Yasuda,et al.  On the oxidation of cyanide solutions with lead dioxide coated anode , 1986 .

[79]  G. Wallace,et al.  Preparation and application of conducting polymers containing chemically active counterions for analytical purposes , 1988 .

[80]  M. Hitchman,et al.  Potentiometric determination of proton activities in solutions containing hydrofluoric acid using thermally oxidized iridium electrodes , 1991 .

[81]  K. Scott.  Metal recovery using a moving-bed electrode , 1981 .

[82]  K. C. Hong,et al.  Carbon aerogel composite electrodes , 1993 .

[83]  Y. Oren,et al.  Removal of chromium from aqueous solutions by treatment with fibrous carbon electrodes: column effects , 1991 .

[84]  F. Beck,et al.  Heterogeneous redox catalysis with titanium/chromium(III) oxide + TiO2 composite anodes , 1984 .

[85]  T. Springer,et al.  Water Uptake by and Transport Through Nafion® 117 Membranes , 1993 .

[86]  S. Kuwabata,et al.  Electrochemical fixation of carbon dioxide in oxoglutaric acid using an enzyme as an electrocatalyst , 1989 .

[87]  V. Bagotsky,et al.  Electroreduction of carbon dioxide: Part I. The mechanism and kinetics of electroreduction of CO2 in aqueous solutions on metals with high and moderate hydrogen overvoltages , 1985 .

[88]  K. Scott.  A consideration of circulating bed electrodes for the recovery of metal from dilute solutions , 1988 .

[89]  A. Aramata,et al.  Electrocatalytic activity of CoII TPP-pyridine complex modified carbon electrode for CO2 reduction , 1991 .

[90]  W. Jiyang,et al.  On the evolution of the geothermal regime of the North China Basin , 1985 .

[91]  T. Kuwana,et al.  Copper(II) reduction in the detection and monitoring of carbon monoxide , 1991 .

[92]  W. Lund,et al.  Comparison of five membrane electrode designs and a study of poly(vinyl chloride) membranes with monoaza crown ethers , 1989 .

[93]  M. Kopanica,et al.  Adsorptive stripping voltammetry in trace analysis , 1989 .

[94]  H. Yeager,et al.  Cation and Water Diffusion in Nafion Ion Exchange Membranes: Influence of Polymer Structure , 1981 .

[95]  M. Meyerhoff,et al.  Salicylate-selective membrane electrode based on tin(IV) tetraphenylporphyrin. , 1989, Analytical chemistry.

[96]  Joseph Wang,et al.  Decentralized electrochemical monitoring of trace metals: from disposable strips to remote electrodes. Plenary lecture , 1994 .

[97]  J. Rosamilia,et al.  Differential pulse polarography of germanium(IV), tin(IV), arsenic(V), antimony(V), selenium(IV) and tellurium(VI) at the static mercury drop electrode in catechol—perchlorate media , 1982 .

[98]  A. Bard,et al.  Polarography of Metal-Pyrogallol Complexes. , 1966 .

[99]  Greg M. Swain,et al.  The electrochemical activity of boron-doped polycrystalline diamond thin film electrodes , 1993 .

[100]  T. Matsunaga,et al.  751-Electrochemical sterilization of microbial cells , 1984 .

[101]  J. Tarter.  Gradient elution ion chromatographic determination of inorganic anions using a continuous gradient , 1984 .

[102]  J. Graves,et al.  The reduction of oxygen on titanium oxide electrodes , 1992 .

[103]  Joseph Wang,et al.  Stripping Analysis: Principles, Instrumentation, and Applications , 1985 .

[104]  Dermot Diamond,et al.  All-solid-state sodium-selective electrode based on a calixarene ionophore in a poly(vinyl chloride) membrane with a polypyrrole solid contact , 1992 .

[105]  Yang Bingkun.  Improvement of the performance of porous electrodes using ionic conducting particles: Application to silver recovery , 1990 .

[106]  Christopher W. Bale,et al.  K 2 CO 3 Solid Electrolyte as a CO 2 Probe: Decomposition Measurements of CaCO3 , 1984 .

[107]  A tin oxide semiconductor sensor for oxygen determination in the sub-ppm range , 1993 .

[108]  William R. Heineman,et al.  Polypyrrole electrode as a detector for electroinactive anions by flow injection analysis , 1986 .

[109]  M. Fleischmann,et al.  Application of the trickle tower to problems of pollution control. I. The scavenging of metal ions , 1982 .

[110]  J. Do,et al.  In Situ Oxidative Degradation of Formaldehyde with Electrogenerated Hydrogen Peroxide , 1993 .

[111]  J. Wang,et al.  Electroanalysis at modified carbon-paste electrodes containing natural ionic polysaccharides. , 1991, Talanta.

[112]  L. Toppare,et al.  Conducting polymers of aniline. II: A composite as a gas sensor , 1993 .

[113]  J. Rusling,et al.  Dechlorination of polychlorinated biphenyls by electrochemical catalysis in a bicontinuous microemulsion , 1993 .

[114]  G. Kreysa,et al.  Optimal design of packed bed cells for high conversion , 1982 .

[115]  M. Kaneko,et al.  Electrocatalytic reduction of carbon dioxide in aqueous medium by bis(2,2′: 6′,2″-terpyridine)cobalt(II) complex incorporated into a coated polymer membrane , 1993 .

[116]  K. Kusakabe,et al.  Simultaneous electrochemical removal of copper and chemical oxygen demand using a packed-bed electrode cell , 1986 .

[117]  D. Meisel,et al.  Quenching and quenching reversal of tris(2,2'-bipyridine)ruthenium(II) emission in polyelectrolyte solutions , 1977 .

[118]  John Evans,et al.  Amperometric sensor for carbon dioxide: design, characteristics, and performance , 1989 .

[119]  D. Jagner,et al.  Potentiometric stripping analysis for zinc, cadmium. lead and copper in sea water , 1979 .

[120]  A R Midgley,et al.  Electrochemical performance, biocompatibility, and adhesion of new polymer matrices for solid-state ion sensors. , 1991, Analytical chemistry.

[121]  A. Bard,et al.  Polymer Films on Electrodes. 8. Investigation of Charge-Transport Mechanisms in Nafion Polymer Modified Electrodes , 1982 .

[122]  J. Johnson,et al.  Amperometric membrane electrode for measurement of ozone in water , 1979 .

[123]  F. Walsh,et al.  Reticulated vitreous carbon cathodes for metal ion removal from process streams part II: Removal of copper(II) from acid sulphate media , 1991 .

[124]  T. Matsue,et al.  Oxidation of Alkylbenzenes by Electrogenerated Hydroxyl Radical , 1981 .

[125]  E. Tsuchida,et al.  The interaction of the tris(2,2'-bipyridine)ruthenium(II) ion with poly(p-styrenesulfonate). , 1982 .

[126]  D. Meisel,et al.  Luminescence quenching in the cluster network of perfluorosulfonate membrane , 1980 .

[127]  W. Blaedel,et al.  Study of anodic stripping voltammetry with collection at tubular electrodes , 1977 .

[128]  T. Nieman,et al.  Bipolar pulse conductance measurements with a calcium ion-selective electrode , 1980 .

[129]  T. Matsunaga,et al.  Disinfection of drinking water by using a novel electrochemical reactor employing carbon-cloth electrodes , 1992, Applied and environmental microbiology.

[130]  J. Wang,et al.  Composite electrodes based on carbonized poly(acrylonitrile) foams. , 1990, Analytical chemistry.

[131]  N. Vatistas,et al.  Removal of silver using graphite-felt electrodes , 1993 .

[132]  G. Wallace,et al.  Deposition and electrochemical stripping of mercury ions on polypyrrole based modified electrodes , 1988 .

[133]  J. Newman,et al.  A Flow‐Through Porous Electrode Model: Application to Metal‐Ion Removal from Dilute Streams , 1977 .

[134]  Richard P. Baldwin,et al.  Flow-injection analysis for electroinactive anions at a polyaniline electrode , 1988 .

[135]  A Pareilleux,et al.  Lethal effects of electric current on Escherichia coli. , 1970, Applied microbiology.

[136]  Mark W. Verbrugge,et al.  The Effect of Temperature on the Equilibrium and Transport Properties of Saturated Poly(perfluorosulfonic acid) Membranes , 1992 .

[137]  B. G. Ateya,et al.  Applications of porous flow through electrodes. II. Hydrogen evolution and metal ion removal at packed metal wool electrodes , 1984 .

[138]  K. Stulík,et al.  Electroanalytical measurements in flowing liquids , 1987 .

[139]  P. Dasgupta,et al.  Two-dimensional conductometric detection in ion chromatography: sequential suppressed and single column detection , 1993 .

[140]  F. R. Foulkes,et al.  Anodic oxidation of aniline for waste water treatment , 1985 .

[141]  E. Beinrohr,et al.  Anodic stripping coulometry with collection for absolute trace analysis of lead, using flow-through electrochemical cells with porous working electrodes , 1992 .

[142]  H. Gunasingham,et al.  Electrochemical sensors for monitoring environmental pollutants. , 1992, Talanta.

[143]  K. A. Friedman,et al.  Electrodialytic eluent production and gradient generation in ion chromatography , 1991 .

[144]  M. Madou,et al.  Chemical Sensing With Solid State Devices , 1989 .

[145]  Probstein Rf,et al.  Removal of contaminants from soils by electric fields. , 1993 .

[146]  M. Smyth,et al.  Development of a polypyrrole-based amperometric detector for the determination of certain anions in water samples. , 1993, Talanta.

[147]  B. Tatarchuk,et al.  Metal‐Carbon Composite Electrodes from Fiber Precursors II . Electrochemical Characterization of Stainless Steel‐Carbon Structures , 1990 .

[148]  P. Dasgupta,et al.  Electrodialytic membrane suppressor for ion chromatography , 1989 .

[149]  Luminescence Probe Studies of Pyrene and Two Charged Derivatives in Nafion , 1987 .

[150]  A. Fujishima,et al.  Efficient electrochemical reduction of nitrate to ammonia using conductive diamond film electrodes , 1993 .

[151]  Andrew W. Weisman,et al.  The use of electrokinetics for hazardous waste site remediation. , 1990 .

[152]  J. Sørensen,et al.  The determination of copper and lead in sediments by potentiometric stripping analysis , 1983 .

[153]  J. Osteryoung.  Voltammetry for the Future , 1993 .

[154]  R. Jansson,et al.  Application of the trickle tower to problems of pollution control. II. The direct and indirect oxidation of cyanide , 1982 .

[155]  J. Wang,et al.  Cellulose acetate coated mercury film electrodes for anodic stripping voltammetry. , 1986, Analytical chemistry.

[156]  Peter S. Fedkiw,et al.  In Situ Electrode Formation on a Nafion Membrane by Chemical Platinization , 1992 .