Experimental study on the effects of hydrogen addition on the emission and heat transfer characteristics of laminar methane diffusion flames with oxygen-enriched air

Abstract The effects of hydrogen addition on the emission and heat transfer characteristics of oxygen-enriched laminar methane diffusion flames were investigated in a laboratory-scale furnace with a co-axial burner. The volume fraction of hydrogen in the methane-hydrogen blend was varied from 0% to 50%, and the oxygen concentration was varied from 25% to 35%. Results showed that the addition of hydrogen led to an increase in the soot-free length and flame temperature while the degree of increase was less at higher oxygen concentrations. Adding hydrogen chemically enhanced the oxidation of CO to CO2, and this chemical effect was stronger when the oxygen concentration increased. NOx emissions increased significantly with the addition of hydrogen, while the rate of this increase decreased with greater oxygen concentrations. The total heat flux increased with the addition of hydrogen, while the rate of this increase was less at higher oxygen concentrations. Although the radiative heat flux increased with higher oxygen concentrations, it did not exceed 6% of the total heat flux at 35% O2. Moreover, adding hydrogen decreased the radiative heat flux; this decrease was significant at higher oxygen concentrations.

[1]  David Scott,et al.  Hydrogen—the case for inevitability , 2004 .

[2]  S. Gollahalli,et al.  Combustion characteristics of hydrogen–hydrocarbon hybrid fuels , 2000 .

[3]  Forman A. Williams,et al.  NOx formation in two-stage methane–air flames , 1999 .

[4]  S. El-Ghafour,et al.  Combustion characteristics of natural gas–hydrogen hybrid fuel turbulent diffusion flame , 2010 .

[5]  R. Schefer,et al.  COMBUSTION OF HYDROGEN-ENRICHED METHANE IN A LEAN PREMIXED SWIRL BURNER , 2001 .

[6]  F. G. Roper The prediction of laminar jet diffusion flame sizes: Part I. Theoretical model , 1977 .

[7]  B. Kroposki,et al.  Renewable hydrogen production , 2008 .

[8]  C. Cheung,et al.  Thermal and emission characteristics of a turbulent swirling inverse diffusion flame , 2010 .

[9]  Yu-Cheng Chang,et al.  High-efficiency combustion of natural gas with 21-30% oxygen-enriched air , 2010 .

[10]  S. Turns An Introduction to Combustion: Concepts and Applications , 2000 .

[11]  Fengshan Liu,et al.  Effect of hydrogen and helium addition to fuel on soot formation in an axisymmetric coflow laminar methane/air diffusion flame , 2014 .

[12]  Bassam B. Dally,et al.  MILD oxy-combustion of gaseous fuels in a laboratory-scale furnace , 2013 .

[13]  Bassam B. Dally,et al.  Mechanisms of NO formation in MILD combustion of CH4/H2 fuel blends , 2014 .

[14]  Jun Li,et al.  Emission and heat transfer characteristics of methane–hydrogen hybrid fuel laminar diffusion flame , 2015 .

[15]  Chung King Law,et al.  Laminar flame speeds of hydrocarbon + air mixtures with hydrogen addition☆ , 1986 .

[16]  I. Yilmaz,et al.  Experimental analysis of the effects of hydrogen addition on methane combustion , 2012 .

[17]  Jun Wang,et al.  Routes of formation and destruction of nitrogen oxides in CH4/H2 jet flames in a hot coflow , 2015 .

[18]  James C. Keck,et al.  Laminar burning velocities in stoichiometric hydrogen and hydrogenhydrocarbon gas mixtures , 1984 .

[19]  Fouad Ammouri,et al.  Soot formation effects of oxygen concentration in the oxidizer stream of laminar coannular nonpremixed methane/air flames , 2000 .

[20]  Charles Baukal,et al.  Oxygen-Enhanced Combustion , 1998 .

[21]  Aldo Coghe,et al.  Behavior of hydrogen-enriched non-premixed swirled natural gas flames , 2006 .

[22]  Alexei V. Saveliev,et al.  Soot and NO formation in methane-oxygen enriched diffusion flames , 2001 .

[23]  Ajay K. Agrawal,et al.  Combustion of hydrogen-enriched methane in a lean premixed swirl-stabilized burner , 2002 .

[24]  Haroun A. K. Shahad,et al.  Investigation of soot formation and temperature field in laminar diffusion flames of LPG–air mixture , 2000 .

[25]  Fengshan Liu,et al.  Experimental and numerical study of the effects of the oxygen index on the radiation characteristics of laminar coflow diffusion flames , 2013 .

[26]  C. Smith,et al.  The prediction of laminar jet diffusion flame sizes: Part II. Experimental verification , 1977 .

[27]  Bassam B. Dally,et al.  Global characteristics of non-premixed jet flames of hydrogen-hydrocarbon blended fuels , 2015 .

[28]  D. Mishra,et al.  Experimental investigation of laminar LPG–H2 jet diffusion flame , 2008 .

[29]  Jinhua Wang,et al.  Numerical study of the effect of hydrogen addition on methane–air mixtures combustion , 2009 .

[30]  Gilles Flamant,et al.  Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy , 2006 .

[31]  Pavel Skryja,et al.  Experimental study on the influence of oxygen content in the combustion air on the combustion characteristics , 2014 .

[32]  Robert W. Schefer,et al.  Hydrogen enrichment for improved lean flame stability , 2003 .

[33]  S. Gollahalli,et al.  Laser induced fluorescence measurements of radical concentrations in hydrogen–hydrocarbon hybrid gas fuel flames , 2000 .

[34]  D. Noh,et al.  The effect of hydrogen addition on the flame behavior of a non-premixed oxy-methane jet in a lab-scale furnace , 2013 .

[35]  George Sidebotham,et al.  Flame temperature, fuel structure, and fuel concentration effects on soot formation in inverse diffusion flames , 1992 .

[36]  Chung King Law,et al.  Soot formation in strained diffusion flames with gaseous additives , 1995 .