Sampling and Smoothing of Spectra

Abstract Anyone working with a spectrometer or similar system should be concerned with using it in the best possible way. This article is concerned with a portion of that problem, viz., the acquisition and treatment of the data. We describe herein what is going on in these various processes and show the dependence of various phenomena on the important parameters. On the basis of the evidence, we then recommend certain procedures and suggest appropriate values for the parameters involved.

[1]  Computer programs for absorption spectrophotometry. , 1969, Applied optics.

[2]  P. Jansson Method for Determining the Response Function of a High-Resolution Infrared Spectrometer* , 1970 .

[3]  Edward B. Magrab,et al.  The measurement of time-varying phenomena : fundamentals and applications , 1971 .

[4]  S. R. Crouch,et al.  Optimization of Electronic Measurements , 1974 .

[5]  R. Bracewell The Fourier Transform and Its Applications , 1966 .

[6]  Gary Horlick,et al.  Practical considerations for digitizing analog signals , 1973 .

[7]  S. Hurlock,et al.  Measuring Line Centers from Digitally Recorded Spectra Using a Minicomputer , 1974 .

[8]  Francis Arthur Jenkins,et al.  Fundamentals of Optics , 1976 .

[9]  S. Chesler,et al.  Effect of peak sensing and random noise on the precision and accuracy of statistical moment analyses from digital chromatographic data , 1971 .

[10]  R. Jones,et al.  The control ot errors in infrared spectrophotometry—I the reduction of finite slit distortion by the method of ``pseudo-deconvolution'' , 1967 .

[11]  Edmund Taylor Whittaker,et al.  The Calculus of Observations , 1969, The Mathematical Gazette.

[12]  A. Savitzky,et al.  Smoothing and Differentiation of Data by Simplified Least Squares Procedures. , 1964 .

[13]  S. Brodersen Noise Filter Effects in Recording Spectroscopes , 1953 .

[14]  R. R. Ernst Sensitivity Enhancement in Magnetic Resonance. I. Analysis of the Method of Time Averaging , 1965 .

[15]  James A. Blackburn,et al.  Spectral analysis : methods and techniques , 1970 .

[16]  H. P. Yule Study of .gamma.-ray spectrum distotion by mathematical smoothing , 1972 .

[17]  P. Jansson,et al.  Resolution Enhancement of Spectra , 1970 .

[18]  Paul D. Willson,et al.  Digital Least Squares Smoothing of Spectra , 1974 .

[19]  H. Gunthard,et al.  Distortion of spectral line shapes by recording instruments. , 1961, Journal of the Optical Society of America.

[20]  James E. Stewart,et al.  Infrared spectroscopy;: Experimental methods and techniques , 1970 .

[21]  W J Potts,et al.  Optimizing the operating parameters of infrared spectrometers. , 1967, Applied optics.